TY - JOUR

T1 - Catalytic asymmetric oxidations using molecular oxygen

AU - Ottenbacher, Roman V.

AU - Talsi, Evgenii P.

AU - Bryliakov, Konstantin P.

N1 - Publisher Copyright: © 2018 Turpion Ltd. All rights reserved.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new C-O bonds, i.e. Oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance. The bibliography includes 41 references.

AB - Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new C-O bonds, i.e. Oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance. The bibliography includes 41 references.

KW - ENANTIOSELECTIVE ALPHA-HYDROXYLATION

KW - KETOIMINATO MANGANESE(III) COMPLEXES

KW - PHASE-TRANSFER CATALYSTS

KW - AEROBIC EPOXIDATION

KW - UNFUNCTIONALIZED OLEFINS

KW - EFFICIENT CATALYSTS

KW - KETONES

KW - CYCLOBUTANONES

KW - OXINDOLES

KW - SULFIDES

UR - http://www.scopus.com/inward/record.url?scp=85052848680&partnerID=8YFLogxK

U2 - 10.1070/RCR4825

DO - 10.1070/RCR4825

M3 - Article

AN - SCOPUS:85052848680

VL - 87

SP - 821

EP - 830

JO - Russian Chemical Reviews

JF - Russian Chemical Reviews

SN - 0036-021X

IS - 9

ER -