Research output: Contribution to journal › Article › peer-review
Catalytic asymmetric oxidations using molecular oxygen. / Ottenbacher, Roman V.; Talsi, Evgenii P.; Bryliakov, Konstantin P.
In: Russian Chemical Reviews, Vol. 87, No. 9, 01.01.2018, p. 821-830.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Catalytic asymmetric oxidations using molecular oxygen
AU - Ottenbacher, Roman V.
AU - Talsi, Evgenii P.
AU - Bryliakov, Konstantin P.
N1 - Publisher Copyright: © 2018 Turpion Ltd. All rights reserved.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new C-O bonds, i.e. Oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance. The bibliography includes 41 references.
AB - Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new C-O bonds, i.e. Oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance. The bibliography includes 41 references.
KW - ENANTIOSELECTIVE ALPHA-HYDROXYLATION
KW - KETOIMINATO MANGANESE(III) COMPLEXES
KW - PHASE-TRANSFER CATALYSTS
KW - AEROBIC EPOXIDATION
KW - UNFUNCTIONALIZED OLEFINS
KW - EFFICIENT CATALYSTS
KW - KETONES
KW - CYCLOBUTANONES
KW - OXINDOLES
KW - SULFIDES
UR - http://www.scopus.com/inward/record.url?scp=85052848680&partnerID=8YFLogxK
U2 - 10.1070/RCR4825
DO - 10.1070/RCR4825
M3 - Article
AN - SCOPUS:85052848680
VL - 87
SP - 821
EP - 830
JO - Russian Chemical Reviews
JF - Russian Chemical Reviews
SN - 0036-021X
IS - 9
ER -
ID: 16483310