Research output: Contribution to journal › Article › peer-review
Zinc and Cobalt Aqua Complexes with Cucurbit[6]uril : Syntheses and Crystal Structures. / Andrienko, I. V.; Kovalenko, E. A.; Karmadonova, I. E. et al.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 6, 01.06.2019, p. 433-438.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Zinc and Cobalt Aqua Complexes with Cucurbit[6]uril
T2 - Syntheses and Crystal Structures
AU - Andrienko, I. V.
AU - Kovalenko, E. A.
AU - Karmadonova, I. E.
AU - Plyusnin, P. E.
AU - Samsonenko, D. G.
AU - Fedin, V. P.
PY - 2019/6/1
Y1 - 2019/6/1
N2 - Abstract: Supramolecular complexes [Zn(H2O)4(C36H36N24O12)](NO3)2 · 6.5H2O (I), [Zn(H2O)4-(C36H36N24O12)](NO3)2 · 7H2O (II), and [Co(H2O)4(C36H36N24O12)](NO3)2 · 7H2O (III) are synthesized by the slow (for I and III) and fast (for II) cooling (after reflux) of aqueous solutions of a mixture of salts of the corresponding metals and cucurbit[6]uril. According to the X-ray diffraction data (СIF files CCDC nos. 1862494 (I), 1862495 (II), and 1862496 (III)), the supramolecular complexes are the first examples of the direct coordination of the zinc and cobalt atoms to the cucurbit[6]uril molecule. Compounds I–III are characterized by X-ray diffraction analysis, thermogravimetry, IR spectroscopy, and elemental analysis.
AB - Abstract: Supramolecular complexes [Zn(H2O)4(C36H36N24O12)](NO3)2 · 6.5H2O (I), [Zn(H2O)4-(C36H36N24O12)](NO3)2 · 7H2O (II), and [Co(H2O)4(C36H36N24O12)](NO3)2 · 7H2O (III) are synthesized by the slow (for I and III) and fast (for II) cooling (after reflux) of aqueous solutions of a mixture of salts of the corresponding metals and cucurbit[6]uril. According to the X-ray diffraction data (СIF files CCDC nos. 1862494 (I), 1862495 (II), and 1862496 (III)), the supramolecular complexes are the first examples of the direct coordination of the zinc and cobalt atoms to the cucurbit[6]uril molecule. Compounds I–III are characterized by X-ray diffraction analysis, thermogravimetry, IR spectroscopy, and elemental analysis.
KW - cobalt complexes
KW - crystal structure
KW - cucurbit[6]uril
KW - supramolecular chemistry
KW - X-ray diffraction analysis
KW - zinc complexes
KW - INCLUSION-COMPOUNDS
KW - COORDINATION
KW - CUCURBITURIL
KW - POTENTIAL APPLICATIONS
KW - LANTHANIDE CATIONS
KW - SUPRAMOLECULAR ASSEMBLIES
KW - METAL-IONS
UR - http://www.scopus.com/inward/record.url?scp=85067865496&partnerID=8YFLogxK
U2 - 10.1134/S1070328419060010
DO - 10.1134/S1070328419060010
M3 - Article
AN - SCOPUS:85067865496
VL - 45
SP - 433
EP - 438
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 6
ER -
ID: 20707340