Research output: Contribution to journal › Article › peer-review
Yttrium complexes with 3,6-bis(tert-butylcatecholate). / Petrov, P. A.; Samsonenko, D. G.
In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 43, No. 8, 01.08.2017, p. 500-504.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Yttrium complexes with 3,6-bis(tert-butylcatecholate)
AU - Petrov, P. A.
AU - Samsonenko, D. G.
PY - 2017/8/1
Y1 - 2017/8/1
N2 - Heterometallic complex [K3Y(Cat36)3(Dme)4] (I) or binuclear complex [Y2(Cat36)3(Dme)3] · Dme (II · Dme) is synthesized, depending on the reactant ratio, by the reaction of YCl3 with 3,6-bis(tertbutylcatecholate) potassium salt (K2Cat36) in 1,2-dimethoxyethane (Dme). Both complexes are characterized by single-crystal X-ray diffraction analysis (CIF files CCDC nos. 1527929 (I) and 1527930 (II)) and 1H and 13C NMR spectroscopy.
AB - Heterometallic complex [K3Y(Cat36)3(Dme)4] (I) or binuclear complex [Y2(Cat36)3(Dme)3] · Dme (II · Dme) is synthesized, depending on the reactant ratio, by the reaction of YCl3 with 3,6-bis(tertbutylcatecholate) potassium salt (K2Cat36) in 1,2-dimethoxyethane (Dme). Both complexes are characterized by single-crystal X-ray diffraction analysis (CIF files CCDC nos. 1527929 (I) and 1527930 (II)) and 1H and 13C NMR spectroscopy.
KW - quinones
KW - rare-earth elements
KW - X-ray diffraction analysis
KW - yttrium
KW - CATECHOLATE
KW - GADOLINIUM
KW - TRANSITION-METAL-COMPLEXES
KW - SEMIQUINONATO COMPLEX
KW - FIELD
KW - CRYSTAL
KW - ELECTRON-TRANSFER
KW - LIGANDS
KW - CHEMISTRY
KW - MAGNETIC-PROPERTIES
UR - http://www.scopus.com/inward/record.url?scp=85027881081&partnerID=8YFLogxK
U2 - 10.1134/S1070328417080048
DO - 10.1134/S1070328417080048
M3 - Article
AN - SCOPUS:85027881081
VL - 43
SP - 500
EP - 504
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 8
ER -
ID: 9963572