Standard

Yttrium 3,5-di-tert-butyl-catecholates supported by 2,6-diisopropylphenyl substituted β-diketiminate. / Klementyeva, Svetlana V.; Smolentsev, Anton I.; Abramov, Pavel A. et al.

In: Inorganic Chemistry Communications, Vol. 86, 01.12.2017, p. 154-158.

Research output: Contribution to journal › Article › peer-review

Harvard

Klementyeva, SV, Smolentsev, AI, Abramov, PA & Konchenko, SN 2017, 'Yttrium 3,5-di-tert-butyl-catecholates supported by 2,6-diisopropylphenyl substituted β-diketiminate', Inorganic Chemistry Communications, vol. 86, pp. 154-158. https://doi.org/10.1016/j.inoche.2017.10.016

APA

Klementyeva, S. V., Smolentsev, A. I., Abramov, P. A., & Konchenko, S. N. (2017). Yttrium 3,5-di-tert-butyl-catecholates supported by 2,6-diisopropylphenyl substituted β-diketiminate. Inorganic Chemistry Communications, 86, 154-158. https://doi.org/10.1016/j.inoche.2017.10.016

Vancouver

Klementyeva SV, Smolentsev AI, Abramov PA, Konchenko SN. Yttrium 3,5-di-tert-butyl-catecholates supported by 2,6-diisopropylphenyl substituted β-diketiminate. Inorganic Chemistry Communications. 2017 Dec 1;86:154-158. doi: 10.1016/j.inoche.2017.10.016

Author

Klementyeva, Svetlana V. ; Smolentsev, Anton I. ; Abramov, Pavel A. et al. / Yttrium 3,5-di-tert-butyl-catecholates supported by 2,6-diisopropylphenyl substituted β-diketiminate. In: Inorganic Chemistry Communications. 2017 ; Vol. 86. pp. 154-158.

BibTeX

@article{be615423e9ce41be96d5617434dbf5c5,
title = "Yttrium 3,5-di-tert-butyl-catecholates supported by 2,6-diisopropylphenyl substituted β-diketiminate",
abstract = "β-Diketiminato yttrium complex [LClY(μ-Cl)3YL(THF)] (L = 2,6-iPr2C6H3-NC(Me)CHC(Me)N-2,6-iPr2C6H3) has been used for the preparation of non-solvated mixed-ligand compound [{LY(μ-3,5-Cat)}2] (1) by the salt metathesis reaction with potassium 3,5-di-tert-butyl-catecholate (3,5-CatK2). The dinuclear yttrium complex [{K(THF)}{LY(μ-3,5-Cat)3Y(THF)}] (2) has been found as an unexpected by-product of side reaction caused by the presence of an admixture of YCl3. Complex 1 has been fully characterized by a set of methods and its solid-state structure, along with that of by-product 2, has been determined by single-crystal X-ray diffraction analysis.",
keywords = "Catecholates, Mixed-ligand complexes, Rare earths, Yttrium, β-Diketiminato ligands, beta-Diketiminato ligands, SEMIQUINONATO COMPLEX, SCANDIUM CHEMISTRY, CRYSTAL-STRUCTURE, STRUCTURAL-CHARACTERIZATION, ORGANOSCANDIUM COMPLEXES, DIALKYLSCANDIUM COMPLEXES, RING-OPENING POLYMERIZATION, EARTH-METAL COMPLEXES, CATALYTIC-ACTIVITY, SEPARATED ION-PAIRS",
author = "Klementyeva, {Svetlana V.} and Smolentsev, {Anton I.} and Abramov, {Pavel A.} and Konchenko, {Sergey N.}",
note = "Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",
year = "2017",
month = dec,
day = "1",
doi = "10.1016/j.inoche.2017.10.016",
language = "English",
volume = "86",
pages = "154--158",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Yttrium 3,5-di-tert-butyl-catecholates supported by 2,6-diisopropylphenyl substituted β-diketiminate

AU - Klementyeva, Svetlana V.

AU - Smolentsev, Anton I.

AU - Abramov, Pavel A.

AU - Konchenko, Sergey N.

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - β-Diketiminato yttrium complex [LClY(μ-Cl)3YL(THF)] (L = 2,6-iPr2C6H3-NC(Me)CHC(Me)N-2,6-iPr2C6H3) has been used for the preparation of non-solvated mixed-ligand compound [{LY(μ-3,5-Cat)}2] (1) by the salt metathesis reaction with potassium 3,5-di-tert-butyl-catecholate (3,5-CatK2). The dinuclear yttrium complex [{K(THF)}{LY(μ-3,5-Cat)3Y(THF)}] (2) has been found as an unexpected by-product of side reaction caused by the presence of an admixture of YCl3. Complex 1 has been fully characterized by a set of methods and its solid-state structure, along with that of by-product 2, has been determined by single-crystal X-ray diffraction analysis.

AB - β-Diketiminato yttrium complex [LClY(μ-Cl)3YL(THF)] (L = 2,6-iPr2C6H3-NC(Me)CHC(Me)N-2,6-iPr2C6H3) has been used for the preparation of non-solvated mixed-ligand compound [{LY(μ-3,5-Cat)}2] (1) by the salt metathesis reaction with potassium 3,5-di-tert-butyl-catecholate (3,5-CatK2). The dinuclear yttrium complex [{K(THF)}{LY(μ-3,5-Cat)3Y(THF)}] (2) has been found as an unexpected by-product of side reaction caused by the presence of an admixture of YCl3. Complex 1 has been fully characterized by a set of methods and its solid-state structure, along with that of by-product 2, has been determined by single-crystal X-ray diffraction analysis.

KW - Catecholates

KW - Mixed-ligand complexes

KW - Rare earths

KW - Yttrium

KW - β-Diketiminato ligands

KW - beta-Diketiminato ligands

KW - SEMIQUINONATO COMPLEX

KW - SCANDIUM CHEMISTRY

KW - CRYSTAL-STRUCTURE

KW - STRUCTURAL-CHARACTERIZATION

KW - ORGANOSCANDIUM COMPLEXES

KW - DIALKYLSCANDIUM COMPLEXES

KW - RING-OPENING POLYMERIZATION

KW - EARTH-METAL COMPLEXES

KW - CATALYTIC-ACTIVITY

KW - SEPARATED ION-PAIRS

UR - http://www.scopus.com/inward/record.url?scp=85032002935&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2017.10.016

DO - 10.1016/j.inoche.2017.10.016

M3 - Article

AN - SCOPUS:85032002935

VL - 86

SP - 154

EP - 158

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 9866203