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X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands. / Mazalov, L. N.; Fedorenko, A. D.; Parygina, G. K. et al.

In: Journal of Structural Chemistry, Vol. 58, No. 8, 01.12.2017, p. 1625-1632.

Research output: Contribution to journal › Article › peer-review

Harvard

Mazalov, LN, Fedorenko, AD, Parygina, GK, Gushchin, AL, Sokolov, MN & Dalmatova, SA 2017, 'X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands', Journal of Structural Chemistry, vol. 58, no. 8, pp. 1625-1632. https://doi.org/10.1134/S0022476617080200

APA

Mazalov, L. N., Fedorenko, A. D., Parygina, G. K., Gushchin, A. L., Sokolov, M. N., & Dalmatova, S. A. (2017). X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands. Journal of Structural Chemistry, 58(8), 1625-1632. https://doi.org/10.1134/S0022476617080200

Vancouver

Mazalov LN, Fedorenko AD, Parygina GK, Gushchin AL, Sokolov MN, Dalmatova SA. X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands. Journal of Structural Chemistry. 2017 Dec 1;58(8):1625-1632. doi: 10.1134/S0022476617080200

Author

Mazalov, L. N. ; Fedorenko, A. D. ; Parygina, G. K. et al. / X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands. In: Journal of Structural Chemistry. 2017 ; Vol. 58, No. 8. pp. 1625-1632.

BibTeX

@article{c1747c4508b04e2f94df9be2773be6ff,
title = "X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands",
abstract = "The electronic structure of binuclear niobium complexes [Nb2S4(acac)4] and K4[Nb2S4(ox)4] is studied by X-ray emission fluorescent spectroscopy and quantum chemistry techniques. Data on the partial atomic composition of highest occupied molecular orbitals of the complexes are obtained. The energy positions of bonding and antibonding frontier molecular orbitals observed in the X-ray emission spectra of binuclear [Nb2((S2)2–)2]4+ clusters are determined by the analysis of overlap populations.",
keywords = "binuclear niobium complexes, bridging disulfide ligands, X-ray emission spectroscopy",
author = "Mazalov, {L. N.} and Fedorenko, {A. D.} and Parygina, {G. K.} and Gushchin, {A. L.} and Sokolov, {M. N.} and Dalmatova, {S. A.}",
year = "2017",
month = dec,
day = "1",
doi = "10.1134/S0022476617080200",
language = "English",
volume = "58",
pages = "1625--1632",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "8",

}

RIS

TY - JOUR

T1 - X-ray emission study of the electronic structure of binuclear niobium complexes with (S2)2–disulfide bridging ligands

AU - Mazalov, L. N.

AU - Fedorenko, A. D.

AU - Parygina, G. K.

AU - Gushchin, A. L.

AU - Sokolov, M. N.

AU - Dalmatova, S. A.

PY - 2017/12/1

Y1 - 2017/12/1

N2 - The electronic structure of binuclear niobium complexes [Nb2S4(acac)4] and K4[Nb2S4(ox)4] is studied by X-ray emission fluorescent spectroscopy and quantum chemistry techniques. Data on the partial atomic composition of highest occupied molecular orbitals of the complexes are obtained. The energy positions of bonding and antibonding frontier molecular orbitals observed in the X-ray emission spectra of binuclear [Nb2((S2)2–)2]4+ clusters are determined by the analysis of overlap populations.

AB - The electronic structure of binuclear niobium complexes [Nb2S4(acac)4] and K4[Nb2S4(ox)4] is studied by X-ray emission fluorescent spectroscopy and quantum chemistry techniques. Data on the partial atomic composition of highest occupied molecular orbitals of the complexes are obtained. The energy positions of bonding and antibonding frontier molecular orbitals observed in the X-ray emission spectra of binuclear [Nb2((S2)2–)2]4+ clusters are determined by the analysis of overlap populations.

KW - binuclear niobium complexes

KW - bridging disulfide ligands

KW - X-ray emission spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85041559260&partnerID=8YFLogxK

U2 - 10.1134/S0022476617080200

DO - 10.1134/S0022476617080200

M3 - Article

AN - SCOPUS:85041559260

VL - 58

SP - 1625

EP - 1632

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 8

ER -

ID: 9640478