Research output: Contribution to journal › Article › peer-review
Visible and “invisible” forms of gold and silver in the crystallization products of melts in the Fe–S–Ag–Au system : experimental data. / Palyanova, G. A.; Mikhlin, Yu L.; Karmanov, N. S. et al.
In: Doklady Earth Sciences, Vol. 474, No. 2, 01.06.2017, p. 636-640.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Visible and “invisible” forms of gold and silver in the crystallization products of melts in the Fe–S–Ag–Au system
T2 - experimental data
AU - Palyanova, G. A.
AU - Mikhlin, Yu L.
AU - Karmanov, N. S.
AU - Kokh, K. A.
AU - Seryotkin, Yu V.
PY - 2017/6/1
Y1 - 2017/6/1
N2 - The forms of Au and Ag occurrence in the crystallization products of melts in the Fe–S–Ag–Au system depending on the proportions of Fe/S and Ag/Au have been studied at (Fe + S)/(Ag + Au) = 0.1. It is shown that the S-rich systems with S/Fe = 2 contain Au–Ag sulfides and Au–Ag alloys. The systems depleted in S with S/Fe = 1 contain only Au–Ag alloys. The results of XPS provide evidence for the sulfide and metallic components of Au and Ag among the crystallization products of melts in the system studied at S/Fe = 2 and a metallic component with S/Fe = 1. According to the data of electron microprobe analysis, the content of “invisible” forms of noble metals in pyrite and pyrrhotite is < 0.024 wt % for Au and <0.030 wt % for Ag; the contents of “invisible” Au and Ag in troilites are 0.040 ± 0.013 wt % Au and 0.079 ± 0.016 wt % Ag.
AB - The forms of Au and Ag occurrence in the crystallization products of melts in the Fe–S–Ag–Au system depending on the proportions of Fe/S and Ag/Au have been studied at (Fe + S)/(Ag + Au) = 0.1. It is shown that the S-rich systems with S/Fe = 2 contain Au–Ag sulfides and Au–Ag alloys. The systems depleted in S with S/Fe = 1 contain only Au–Ag alloys. The results of XPS provide evidence for the sulfide and metallic components of Au and Ag among the crystallization products of melts in the system studied at S/Fe = 2 and a metallic component with S/Fe = 1. According to the data of electron microprobe analysis, the content of “invisible” forms of noble metals in pyrite and pyrrhotite is < 0.024 wt % for Au and <0.030 wt % for Ag; the contents of “invisible” Au and Ag in troilites are 0.040 ± 0.013 wt % Au and 0.079 ± 0.016 wt % Ag.
UR - http://www.scopus.com/inward/record.url?scp=85024090634&partnerID=8YFLogxK
U2 - 10.1134/S1028334X1706006X
DO - 10.1134/S1028334X1706006X
M3 - Article
AN - SCOPUS:85024090634
VL - 474
SP - 636
EP - 640
JO - Doklady Earth Sciences
JF - Doklady Earth Sciences
SN - 1028-334X
IS - 2
ER -
ID: 10092083