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Urotropine as a ligand for the efficient synthesis of metal-organic frameworks. / Sapchenko, S. A.; Barsukova, M. O.; Nokhrina, T. V. et al.

In: Russian Chemical Bulletin, Vol. 69, No. 3, 03.2020, p. 461-469.

Research output: Contribution to journal › Article › peer-review

Harvard

Sapchenko, SA, Barsukova, MO, Nokhrina, TV, Kovalenko, KA, Samsonenko, DG, Dybtsev, DN & Fedin, VP 2020, 'Urotropine as a ligand for the efficient synthesis of metal-organic frameworks', Russian Chemical Bulletin, vol. 69, no. 3, pp. 461-469. https://doi.org/10.1007/s11172-020-2785-8

APA

Sapchenko, S. A., Barsukova, M. O., Nokhrina, T. V., Kovalenko, K. A., Samsonenko, D. G., Dybtsev, D. N., & Fedin, V. P. (2020). Urotropine as a ligand for the efficient synthesis of metal-organic frameworks. Russian Chemical Bulletin, 69(3), 461-469. https://doi.org/10.1007/s11172-020-2785-8

Vancouver

Sapchenko SA, Barsukova MO, Nokhrina TV, Kovalenko KA, Samsonenko DG, Dybtsev DN et al. Urotropine as a ligand for the efficient synthesis of metal-organic frameworks. Russian Chemical Bulletin. 2020 Mar;69(3):461-469. doi: 10.1007/s11172-020-2785-8

Author

Sapchenko, S. A. ; Barsukova, M. O. ; Nokhrina, T. V. et al. / Urotropine as a ligand for the efficient synthesis of metal-organic frameworks. In: Russian Chemical Bulletin. 2020 ; Vol. 69, No. 3. pp. 461-469.

BibTeX

@article{e92fad9def8341abaa46956a752178bc,
title = "Urotropine as a ligand for the efficient synthesis of metal-organic frameworks",
abstract = "Urotropine is a cheap and promising ligand for the synthesis of metal-organic frameworks containing uncoordinated nitrogen atoms. The reactions between urotropine, dicarboxylic acids, and zinc(II) or cobalt(II) salts were studied. The optimization of the reaction conditions allows the synthesis of three urotropine-containing metal-organic frameworks, [Zn(ur)(abdc)]• •DMF•H2O (1, ur is urotropine, abdc2− is 4,4´-diazobiphenyldicarboxylate, DMF is N,N-dimethylformamide), (CH3ur)[NaCo(dmf)2(bptc)] (2, CH3ur+ is N-methylhexa methyl enetetrammonium, bptc4− is 2,2´,4,4´-biphenyltetracarboxylate), and [Co4(dmf)(ur)2(ndc)4]•5DMF (3, ndc2− is 2,6-naphthalenedicarboxylate). These compounds were structurally characterized and their thermal and adsorption properties were studied. In the three compounds, urotropine performs diff erent functions, acting as a monodentate ligand (compound 1), a bidentate ligand (compound 3), or a methylammonium counterion (compound 2).",
keywords = "cobalt, metal-organic frameworks, urotropine, zinc, COORDINATION POLYMER, SCANDIUM, HEXAMETHYLENETETRAMINE, CRYSTAL-STRUCTURE, COPPER(II), SITES, ADSORPTION",
author = "Sapchenko, {S. A.} and Barsukova, {M. O.} and Nokhrina, {T. V.} and Kovalenko, {K. A.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",
year = "2020",
month = mar,
doi = "10.1007/s11172-020-2785-8",
language = "English",
volume = "69",
pages = "461--469",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "3",

}

RIS

TY - JOUR

T1 - Urotropine as a ligand for the efficient synthesis of metal-organic frameworks

AU - Sapchenko, S. A.

AU - Barsukova, M. O.

AU - Nokhrina, T. V.

AU - Kovalenko, K. A.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2020/3

Y1 - 2020/3

N2 - Urotropine is a cheap and promising ligand for the synthesis of metal-organic frameworks containing uncoordinated nitrogen atoms. The reactions between urotropine, dicarboxylic acids, and zinc(II) or cobalt(II) salts were studied. The optimization of the reaction conditions allows the synthesis of three urotropine-containing metal-organic frameworks, [Zn(ur)(abdc)]• •DMF•H2O (1, ur is urotropine, abdc2− is 4,4´-diazobiphenyldicarboxylate, DMF is N,N-dimethylformamide), (CH3ur)[NaCo(dmf)2(bptc)] (2, CH3ur+ is N-methylhexa methyl enetetrammonium, bptc4− is 2,2´,4,4´-biphenyltetracarboxylate), and [Co4(dmf)(ur)2(ndc)4]•5DMF (3, ndc2− is 2,6-naphthalenedicarboxylate). These compounds were structurally characterized and their thermal and adsorption properties were studied. In the three compounds, urotropine performs diff erent functions, acting as a monodentate ligand (compound 1), a bidentate ligand (compound 3), or a methylammonium counterion (compound 2).

AB - Urotropine is a cheap and promising ligand for the synthesis of metal-organic frameworks containing uncoordinated nitrogen atoms. The reactions between urotropine, dicarboxylic acids, and zinc(II) or cobalt(II) salts were studied. The optimization of the reaction conditions allows the synthesis of three urotropine-containing metal-organic frameworks, [Zn(ur)(abdc)]• •DMF•H2O (1, ur is urotropine, abdc2− is 4,4´-diazobiphenyldicarboxylate, DMF is N,N-dimethylformamide), (CH3ur)[NaCo(dmf)2(bptc)] (2, CH3ur+ is N-methylhexa methyl enetetrammonium, bptc4− is 2,2´,4,4´-biphenyltetracarboxylate), and [Co4(dmf)(ur)2(ndc)4]•5DMF (3, ndc2− is 2,6-naphthalenedicarboxylate). These compounds were structurally characterized and their thermal and adsorption properties were studied. In the three compounds, urotropine performs diff erent functions, acting as a monodentate ligand (compound 1), a bidentate ligand (compound 3), or a methylammonium counterion (compound 2).

KW - cobalt

KW - metal-organic frameworks

KW - urotropine

KW - zinc

KW - COORDINATION POLYMER

KW - SCANDIUM

KW - HEXAMETHYLENETETRAMINE

KW - CRYSTAL-STRUCTURE

KW - COPPER(II)

KW - SITES

KW - ADSORPTION

UR - http://www.scopus.com/inward/record.url?scp=85083312083&partnerID=8YFLogxK

U2 - 10.1007/s11172-020-2785-8

DO - 10.1007/s11172-020-2785-8

M3 - Article

AN - SCOPUS:85083312083

VL - 69

SP - 461

EP - 469

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 3

ER -

ID: 24076731