Standard

Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–. / Korenev, V. S.; Abramov, P. A.; Gushchin, A. L. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 64, No. 9, 01.09.2019, p. 1105-1114.

Research output: Contribution to journal › Article › peer-review

Harvard

Korenev, VS, Abramov, PA, Gushchin, AL, Stass, DV, Babaev, VM, Rizvanov, IK & Sokolov, MN 2019, 'Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–', Russian Journal of Inorganic Chemistry, vol. 64, no. 9, pp. 1105-1114. https://doi.org/10.1134/S0036023619090146

APA

Korenev, V. S., Abramov, P. A., Gushchin, A. L., Stass, D. V., Babaev, V. M., Rizvanov, I. K., & Sokolov, M. N. (2019). Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–. Russian Journal of Inorganic Chemistry, 64(9), 1105-1114. https://doi.org/10.1134/S0036023619090146

Vancouver

Korenev VS, Abramov PA, Gushchin AL, Stass DV, Babaev VM, Rizvanov IK et al. Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–. Russian Journal of Inorganic Chemistry. 2019 Sept 1;64(9):1105-1114. doi: 10.1134/S0036023619090146

Author

Korenev, V. S. ; Abramov, P. A. ; Gushchin, A. L. et al. / Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–. In: Russian Journal of Inorganic Chemistry. 2019 ; Vol. 64, No. 9. pp. 1105-1114.

BibTeX

@article{5f77db5afc0d4f7e8171643c79a2468f,
title = "Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–",
abstract = "The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated.",
keywords = "electrochemistry, mass spectrometry, polyoxometalates, uranyl, X-ray luminescence, URANIUM, CAGE, CROWN HETEROPOLYANION, COMPLEXES, P8W48, FLUORESCENCE, NUCLEATION PROCESS, INFRARED SPECTRA, LANTHANIDE, DERIVATIVES",
author = "Korenev, {V. S.} and Abramov, {P. A.} and Gushchin, {A. L.} and Stass, {D. V.} and Babaev, {V. M.} and Rizvanov, {I. Kh} and Sokolov, {M. N.}",
note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd.",
year = "2019",
month = sep,
day = "1",
doi = "10.1134/S0036023619090146",
language = "English",
volume = "64",
pages = "1105--1114",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "9",

}

RIS

TY - JOUR

T1 - Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO2)8P8W48O184]24–

AU - Korenev, V. S.

AU - Abramov, P. A.

AU - Gushchin, A. L.

AU - Stass, D. V.

AU - Babaev, V. M.

AU - Rizvanov, I. Kh

AU - Sokolov, M. N.

N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated.

AB - The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated.

KW - electrochemistry

KW - mass spectrometry

KW - polyoxometalates

KW - uranyl

KW - X-ray luminescence

KW - URANIUM

KW - CAGE

KW - CROWN HETEROPOLYANION

KW - COMPLEXES

KW - P8W48

KW - FLUORESCENCE

KW - NUCLEATION PROCESS

KW - INFRARED SPECTRA

KW - LANTHANIDE

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85073512477&partnerID=8YFLogxK

U2 - 10.1134/S0036023619090146

DO - 10.1134/S0036023619090146

M3 - Article

AN - SCOPUS:85073512477

VL - 64

SP - 1105

EP - 1114

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 9

ER -

ID: 21927466