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Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex. / Vorobyev, Vasily; Kostin, Gennadiy A.; Kuratieva, Natalia V. et al.

In: Inorganic Chemistry, Vol. 55, No. 18, 19.09.2016, p. 9158-9161.

Research output: Contribution to journal › Article › peer-review

Harvard

Vorobyev, V, Kostin, GA, Kuratieva, NV & Emelyanov, VA 2016, 'Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex', Inorganic Chemistry, vol. 55, no. 18, pp. 9158-9161. https://doi.org/10.1021/acs.inorgchem.6b01818

APA

Vorobyev, V., Kostin, G. A., Kuratieva, N. V., & Emelyanov, V. A. (2016). Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex. Inorganic Chemistry, 55(18), 9158-9161. https://doi.org/10.1021/acs.inorgchem.6b01818

Vancouver

Vorobyev V, Kostin GA, Kuratieva NV, Emelyanov VA. Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex. Inorganic Chemistry. 2016 Sept 19;55(18):9158-9161. doi: 10.1021/acs.inorgchem.6b01818

Author

Vorobyev, Vasily ; Kostin, Gennadiy A. ; Kuratieva, Natalia V. et al. / Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex. In: Inorganic Chemistry. 2016 ; Vol. 55, No. 18. pp. 9158-9161.

BibTeX

@article{0ce6381b32ca48df84c6513dfb625d45,
title = "Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex",
abstract = "The properties of Ru-ON states were studied in cis-[RuNO(NH3)2(NO2)2OH] under illumination. The structure contains two nonequivalent complexes, and the metastable state was generated for both molecules with 19(1) and 31(1)% populations. The MS1 thermal decay occurs as a one-step process at about 240 K according to differential scanning calorimetry (DSC). For the first-order reaction, the frequency factor and activation energy for the decay process were determined as 2.0(2) × 1013 s-1 and 68.3(4) kJ mol-1, respectively. Also, the simultaneous metastable state decay observed via DSC was in agreement with IR spectroscopy.",
author = "Vasily Vorobyev and Kostin, {Gennadiy A.} and Kuratieva, {Natalia V.} and Emelyanov, {Vyacheslav A.}",
year = "2016",
month = sep,
day = "19",
doi = "10.1021/acs.inorgchem.6b01818",
language = "English",
volume = "55",
pages = "9158--9161",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "18",

}

RIS

TY - JOUR

T1 - Two oxygen-coordinated metastable Ru-ON states for ruthenium mononitrosyl complex

AU - Vorobyev, Vasily

AU - Kostin, Gennadiy A.

AU - Kuratieva, Natalia V.

AU - Emelyanov, Vyacheslav A.

PY - 2016/9/19

Y1 - 2016/9/19

N2 - The properties of Ru-ON states were studied in cis-[RuNO(NH3)2(NO2)2OH] under illumination. The structure contains two nonequivalent complexes, and the metastable state was generated for both molecules with 19(1) and 31(1)% populations. The MS1 thermal decay occurs as a one-step process at about 240 K according to differential scanning calorimetry (DSC). For the first-order reaction, the frequency factor and activation energy for the decay process were determined as 2.0(2) × 1013 s-1 and 68.3(4) kJ mol-1, respectively. Also, the simultaneous metastable state decay observed via DSC was in agreement with IR spectroscopy.

AB - The properties of Ru-ON states were studied in cis-[RuNO(NH3)2(NO2)2OH] under illumination. The structure contains two nonequivalent complexes, and the metastable state was generated for both molecules with 19(1) and 31(1)% populations. The MS1 thermal decay occurs as a one-step process at about 240 K according to differential scanning calorimetry (DSC). For the first-order reaction, the frequency factor and activation energy for the decay process were determined as 2.0(2) × 1013 s-1 and 68.3(4) kJ mol-1, respectively. Also, the simultaneous metastable state decay observed via DSC was in agreement with IR spectroscopy.

UR - http://www.scopus.com/inward/record.url?scp=84988410057&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.6b01818

DO - 10.1021/acs.inorgchem.6b01818

M3 - Article

AN - SCOPUS:84988410057

VL - 55

SP - 9158

EP - 9161

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 18

ER -

ID: 25403640