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Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions. / Elsayed Moussa, Mehdi; Peresypkina, Eugenia; Virovets, Alexander V. et al.

In: CrystEngComm, Vol. 20, No. 46, 14.12.2018, p. 7417-7422.

Research output: Contribution to journal › Article › peer-review

Harvard

Elsayed Moussa, M, Peresypkina, E, Virovets, AV, Venus, D, Balázs, G & Scheer, M 2018, 'Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions', CrystEngComm, vol. 20, no. 46, pp. 7417-7422. https://doi.org/10.1039/c8ce01792a

APA

Elsayed Moussa, M., Peresypkina, E., Virovets, A. V., Venus, D., Balázs, G., & Scheer, M. (2018). Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions. CrystEngComm, 20(46), 7417-7422. https://doi.org/10.1039/c8ce01792a

Vancouver

Elsayed Moussa M, Peresypkina E, Virovets AV, Venus D, Balázs G, Scheer M. Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions. CrystEngComm. 2018 Dec 14;20(46):7417-7422. doi: 10.1039/c8ce01792a

Author

Elsayed Moussa, Mehdi ; Peresypkina, Eugenia ; Virovets, Alexander V. et al. / Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions. In: CrystEngComm. 2018 ; Vol. 20, No. 46. pp. 7417-7422.

BibTeX

@article{837cc6047df64d89bcc8d8540eef2d54,
title = "Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions",
abstract = "The reactions of the P2 ligand complex [Cp2Mo2(CO)4(η2-P2)] (Cp = C5H5, 1) with Ag[Al{OC(CF3)3}4] (Ag[TEF]) in the presence of the rigid bipyridyl linkers 1,2-di(pyridin-4-yl)ethyne (3), 4,4′-bis(pyridin-4-ylethynyl)-1,1′-biphenyl (4) and 4,4′-bipyridine (5) possessing various lengths are studied. The reaction with the longer linkers (3 and 4) leads to the formation of the 1D organometallic-organic hybrid polymers [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2{Cp2Mo2(CO)4(μ3,η1:2:2-P2)}2(μ,η1:1-C12H8N2)Ag2]n[TEF]2n (6) and [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2{Cp2Mo2(CO)4(μ3,η1:2:2-P2)}2(μ,η1:1-C26H16N2)Ag2]n[TEF]2n (7) in high selectivity. A similar reaction with the short linker 5 affords a mixture of the 2D hybrid polymers [{Cp2Mo2(CO)4(μ4,η1:2:2:2-P2)}2(μ,η1:1-C13H14N2)Ag2]n[TEF]2n (8) and the 3D hybrid network [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2(μ,η1:1-C10H8N2)Ag]n[TEF]2n (9). However, a selective synthesis of 8 or 9 is possible when the reaction is performed at 0 °C and 60 °C, respectively.",
keywords = "COORDINATION POLYMERS, BUILDING-BLOCKS, DIPHOSPHORUS COMPLEX, CRYSTAL-STRUCTURES, LIGAND COMPLEX, PENTAPHOSPHAFERROCENE, FRAMEWORKS, DESIGN, 2D, SUPRAMOLECULE",
author = "{Elsayed Moussa}, Mehdi and Eugenia Peresypkina and Virovets, {Alexander V.} and Dominik Venus and G{\'a}bor Bal{\'a}zs and Manfred Scheer",
note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",
year = "2018",
month = dec,
day = "14",
doi = "10.1039/c8ce01792a",
language = "English",
volume = "20",
pages = "7417--7422",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "46",

}

RIS

TY - JOUR

T1 - Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp2Mo2(CO)4(η2-P2)], bipyridyl linkers and AgI ions

AU - Elsayed Moussa, Mehdi

AU - Peresypkina, Eugenia

AU - Virovets, Alexander V.

AU - Venus, Dominik

AU - Balázs, Gábor

AU - Scheer, Manfred

N1 - Publisher Copyright: © 2018 The Royal Society of Chemistry.

PY - 2018/12/14

Y1 - 2018/12/14

N2 - The reactions of the P2 ligand complex [Cp2Mo2(CO)4(η2-P2)] (Cp = C5H5, 1) with Ag[Al{OC(CF3)3}4] (Ag[TEF]) in the presence of the rigid bipyridyl linkers 1,2-di(pyridin-4-yl)ethyne (3), 4,4′-bis(pyridin-4-ylethynyl)-1,1′-biphenyl (4) and 4,4′-bipyridine (5) possessing various lengths are studied. The reaction with the longer linkers (3 and 4) leads to the formation of the 1D organometallic-organic hybrid polymers [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2{Cp2Mo2(CO)4(μ3,η1:2:2-P2)}2(μ,η1:1-C12H8N2)Ag2]n[TEF]2n (6) and [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2{Cp2Mo2(CO)4(μ3,η1:2:2-P2)}2(μ,η1:1-C26H16N2)Ag2]n[TEF]2n (7) in high selectivity. A similar reaction with the short linker 5 affords a mixture of the 2D hybrid polymers [{Cp2Mo2(CO)4(μ4,η1:2:2:2-P2)}2(μ,η1:1-C13H14N2)Ag2]n[TEF]2n (8) and the 3D hybrid network [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2(μ,η1:1-C10H8N2)Ag]n[TEF]2n (9). However, a selective synthesis of 8 or 9 is possible when the reaction is performed at 0 °C and 60 °C, respectively.

AB - The reactions of the P2 ligand complex [Cp2Mo2(CO)4(η2-P2)] (Cp = C5H5, 1) with Ag[Al{OC(CF3)3}4] (Ag[TEF]) in the presence of the rigid bipyridyl linkers 1,2-di(pyridin-4-yl)ethyne (3), 4,4′-bis(pyridin-4-ylethynyl)-1,1′-biphenyl (4) and 4,4′-bipyridine (5) possessing various lengths are studied. The reaction with the longer linkers (3 and 4) leads to the formation of the 1D organometallic-organic hybrid polymers [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2{Cp2Mo2(CO)4(μ3,η1:2:2-P2)}2(μ,η1:1-C12H8N2)Ag2]n[TEF]2n (6) and [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2{Cp2Mo2(CO)4(μ3,η1:2:2-P2)}2(μ,η1:1-C26H16N2)Ag2]n[TEF]2n (7) in high selectivity. A similar reaction with the short linker 5 affords a mixture of the 2D hybrid polymers [{Cp2Mo2(CO)4(μ4,η1:2:2:2-P2)}2(μ,η1:1-C13H14N2)Ag2]n[TEF]2n (8) and the 3D hybrid network [{Cp2Mo2(CO)4(μ4,η1:1:2:2-P2)}2(μ,η1:1-C10H8N2)Ag]n[TEF]2n (9). However, a selective synthesis of 8 or 9 is possible when the reaction is performed at 0 °C and 60 °C, respectively.

KW - COORDINATION POLYMERS

KW - BUILDING-BLOCKS

KW - DIPHOSPHORUS COMPLEX

KW - CRYSTAL-STRUCTURES

KW - LIGAND COMPLEX

KW - PENTAPHOSPHAFERROCENE

KW - FRAMEWORKS

KW - DESIGN

KW - 2D

KW - SUPRAMOLECULE

UR - http://www.scopus.com/inward/record.url?scp=85057544797&partnerID=8YFLogxK

U2 - 10.1039/c8ce01792a

DO - 10.1039/c8ce01792a

M3 - Article

AN - SCOPUS:85057544797

VL - 20

SP - 7417

EP - 7422

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 46

ER -

ID: 17669612