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Tri-p-Tolylbismuth Diperchlorate and μ-Oxo-bis[(perchlorato)tri-p-tolylbismuth] : Synthesis and Structure. / Egorova, I. V.; Zhidkov, V. V.; Grinishak, I. P. et al.

In: Russian Journal of Inorganic Chemistry, Vol. 63, No. 7, 01.07.2018, p. 861-866.

Research output: Contribution to journal › Article › peer-review

Harvard

Egorova, IV, Zhidkov, VV, Grinishak, IP, Bagryanskaya, IY, Troshina, RS & Pervukhina, NV 2018, 'Tri-p-Tolylbismuth Diperchlorate and μ-Oxo-bis[(perchlorato)tri-p-tolylbismuth]: Synthesis and Structure', Russian Journal of Inorganic Chemistry, vol. 63, no. 7, pp. 861-866. https://doi.org/10.1134/S0036023618070069

APA

Egorova, I. V., Zhidkov, V. V., Grinishak, I. P., Bagryanskaya, I. Y., Troshina, R. S., & Pervukhina, N. V. (2018). Tri-p-Tolylbismuth Diperchlorate and μ-Oxo-bis[(perchlorato)tri-p-tolylbismuth]: Synthesis and Structure. Russian Journal of Inorganic Chemistry, 63(7), 861-866. https://doi.org/10.1134/S0036023618070069

Vancouver

Egorova IV, Zhidkov VV, Grinishak IP, Bagryanskaya IY, Troshina RS, Pervukhina NV. Tri-p-Tolylbismuth Diperchlorate and μ-Oxo-bis[(perchlorato)tri-p-tolylbismuth]: Synthesis and Structure. Russian Journal of Inorganic Chemistry. 2018 Jul 1;63(7):861-866. doi: 10.1134/S0036023618070069

Author

Egorova, I. V. ; Zhidkov, V. V. ; Grinishak, I. P. et al. / Tri-p-Tolylbismuth Diperchlorate and μ-Oxo-bis[(perchlorato)tri-p-tolylbismuth] : Synthesis and Structure. In: Russian Journal of Inorganic Chemistry. 2018 ; Vol. 63, No. 7. pp. 861-866.

BibTeX

@article{2187de6169114843aa6af2675c2e7f06,
title = "Tri-p-Tolylbismuth Diperchlorate and μ-Oxo-bis[(perchlorato)tri-p-tolylbismuth]: Synthesis and Structure",
abstract = "Tri-p-tolylbismuth perchlorate (1) and μ-oxo-bis[(perchlorato)tri-p-tolylbismuth] (2) have been synthesized by the reaction between tri-p-tolylbismuth dibromide and silver perchlorate and its hydrate. The complexes have been studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Complex 1 is triclinic, space group Pī, Z = 4, a =10.7271(9) {\AA}, b = 13.5585(11) {\AA}, c = 18.1592(13) {\AA}, α = 110.867(3)°, β = 94.944(3)°, γ = 96.888(3)°, V = 2426.3(3) {\AA}3, ρcalcd = 1.865 g/cm3; complex 2 crystallizes in trigonal symmetry, space group R3 ¯ , a = 13.1157(2) {\AA}, c = 22.1959(2) {\AA}, γ = 120°, V = 3306.64(8) {\AA}3, ρcalcd = 1.777 g/cm3. The bismuth atoms in the molecular structure of complex 1 have a distorted trigonal bipyramidal coordination to the apically arranged oxygen atoms of perchlorate ions (Bi–C, 2.180(5)–2.201(5) {\AA}; Bi–O, 2.324(4)–2.355(4) {\AA}; OBiO axial angles, 170.1(1)°, 174.5(1)°). The structure of complex 2 contains binuclear [p-Tol3Bi(ClO4)]2O molecules (Bi–O, 2.371(15), 1.9107(7) {\AA}; OBiO axial angle, 180.0°).",
keywords = "ORGANOBISMUTH COMPOUNDS, MOLECULAR-STRUCTURE, PERCHLORATE, DERIVATIVES, COMPLEXES, CRYSTAL, SOLVENT",
author = "Egorova, {I. V.} and Zhidkov, {V. V.} and Grinishak, {I. P.} and Bagryanskaya, {I. Yu} and Troshina, {R. S.} and Pervukhina, {N. V.}",
year = "2018",
month = jul,
day = "1",
doi = "10.1134/S0036023618070069",
language = "English",
volume = "63",
pages = "861--866",
journal = "Russian Journal of Inorganic Chemistry",
issn = "0036-0236",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "7",

}

RIS

TY - JOUR

T1 - Tri-p-Tolylbismuth Diperchlorate and μ-Oxo-bis[(perchlorato)tri-p-tolylbismuth]

T2 - Synthesis and Structure

AU - Egorova, I. V.

AU - Zhidkov, V. V.

AU - Grinishak, I. P.

AU - Bagryanskaya, I. Yu

AU - Troshina, R. S.

AU - Pervukhina, N. V.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - Tri-p-tolylbismuth perchlorate (1) and μ-oxo-bis[(perchlorato)tri-p-tolylbismuth] (2) have been synthesized by the reaction between tri-p-tolylbismuth dibromide and silver perchlorate and its hydrate. The complexes have been studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Complex 1 is triclinic, space group Pī, Z = 4, a =10.7271(9) Å, b = 13.5585(11) Å, c = 18.1592(13) Å, α = 110.867(3)°, β = 94.944(3)°, γ = 96.888(3)°, V = 2426.3(3) Å3, ρcalcd = 1.865 g/cm3; complex 2 crystallizes in trigonal symmetry, space group R3 ¯ , a = 13.1157(2) Å, c = 22.1959(2) Å, γ = 120°, V = 3306.64(8) Å3, ρcalcd = 1.777 g/cm3. The bismuth atoms in the molecular structure of complex 1 have a distorted trigonal bipyramidal coordination to the apically arranged oxygen atoms of perchlorate ions (Bi–C, 2.180(5)–2.201(5) Å; Bi–O, 2.324(4)–2.355(4) Å; OBiO axial angles, 170.1(1)°, 174.5(1)°). The structure of complex 2 contains binuclear [p-Tol3Bi(ClO4)]2O molecules (Bi–O, 2.371(15), 1.9107(7) Å; OBiO axial angle, 180.0°).

AB - Tri-p-tolylbismuth perchlorate (1) and μ-oxo-bis[(perchlorato)tri-p-tolylbismuth] (2) have been synthesized by the reaction between tri-p-tolylbismuth dibromide and silver perchlorate and its hydrate. The complexes have been studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Complex 1 is triclinic, space group Pī, Z = 4, a =10.7271(9) Å, b = 13.5585(11) Å, c = 18.1592(13) Å, α = 110.867(3)°, β = 94.944(3)°, γ = 96.888(3)°, V = 2426.3(3) Å3, ρcalcd = 1.865 g/cm3; complex 2 crystallizes in trigonal symmetry, space group R3 ¯ , a = 13.1157(2) Å, c = 22.1959(2) Å, γ = 120°, V = 3306.64(8) Å3, ρcalcd = 1.777 g/cm3. The bismuth atoms in the molecular structure of complex 1 have a distorted trigonal bipyramidal coordination to the apically arranged oxygen atoms of perchlorate ions (Bi–C, 2.180(5)–2.201(5) Å; Bi–O, 2.324(4)–2.355(4) Å; OBiO axial angles, 170.1(1)°, 174.5(1)°). The structure of complex 2 contains binuclear [p-Tol3Bi(ClO4)]2O molecules (Bi–O, 2.371(15), 1.9107(7) Å; OBiO axial angle, 180.0°).

KW - ORGANOBISMUTH COMPOUNDS

KW - MOLECULAR-STRUCTURE

KW - PERCHLORATE

KW - DERIVATIVES

KW - COMPLEXES

KW - CRYSTAL

KW - SOLVENT

UR - http://www.scopus.com/inward/record.url?scp=85051144689&partnerID=8YFLogxK

U2 - 10.1134/S0036023618070069

DO - 10.1134/S0036023618070069

M3 - Article

AN - SCOPUS:85051144689

VL - 63

SP - 861

EP - 866

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 7

ER -

ID: 16072267