TY - JOUR

T1 - Towards composition of carbonatite melts in peridotitic mantle

AU - Shatskiy, Anton

AU - Bekhtenova, Altyna

AU - Podborodnikov, Ivan V.

AU - Arefiev, Anton V.

AU - Litasov, Konstantin D.

N1 - Funding Information: This work is financially supported by Russian Science Foundation (project No. 21-77-10057). We are grateful to J. Badro for editorial handling and important comments; O. Navon and anonymous reviewer for constructive reviews; V.S. Shatsky and A.L. Ragozin for providing natural peridotite and discussion. The SEM and EDS studies of experimental samples were performed in the Analytical Center for multi-elemental and isotope research SB RAS. We thank N.S. Karmanov, A.T. Titov, and M.V. Khlestov for their assistance in the analytical works. Publisher Copyright: © 2022 Elsevier B.V.

PY - 2022/3/1

Y1 - 2022/3/1

N2 - It is generally accepted that carbonatite metasomatism in the subcontinental lithospheric mantle (SCLM) inevitably causes wehrlitization of the primary lherzolite substrate. However, the K-rich carbonatite inclusions in kimberlitic diamonds containing orthopyroxene indicate that this is not always the case. In the present study, we equilibrated natural garnet lherzolite with carbonate melts containing 33–38 wt% K2O with various Ca# = 10, 20, 30, and 40 at 6 GPa and 1200–1500 °C, where Ca# = 100⋅Ca/(Ca+Mg+Fe). The original ratio of peridotite to carbonate was 58 to 42 by weight. In the studied temperature range, the melt retains essentially carbonate composition with silica content increasing from 1 to 11–12 wt%. The melt with Ca# 10 alters lherzolite to harzburgite, replacing clinopyroxene by orthopyroxene and decreasing CaO content in garnet below 4 wt%. The melts with Ca# 20-30 also consume clinopyroxene; although CaO content in garnet remains in the range of lherzolitic compositions. The melt with Ca# 40 yields wehrlitization, consuming orthopyroxene, increasing clinopyroxene fraction, and increasing CaO content in garnet above 6 wt%. After the interaction, the Ca# of the melt changes as follows 10 → 16–28, 20 → 20–33, 30 → 27–34, and 40 → 30–34. The olivine + orthopyroxene + clinopyroxene + garnet assemblage was found in equilibrium with carbonatite melt with Ca# 34 at 1200 °C and Ca# 30 at 1400 °C. Thus, K-rich (26–35 wt% K2O) carbonatite melts with Ca# = 30-34 can appear in equilibrium with garnet lherzolite, while the melts with Ca# < 30 and > 34 can be in equilibrium with harzburgite and wehrlite, respectively, at 6 GPa and 1200–1400 °C. Considering that Ca-Mg-Fe carbonates do not melt at the geothermal conditions of the SCLM, while sodic, dolomitic melt causes wehrlitization, high-Mg (Ca# < 35) K-rich dolomitic melt is the only possible carbonatite fluids that are thermodynamically stable in equilibrium with garnet harzburgites and lherzolites in the SCLM at a depth of about 200 km. At higher temperatures corresponding to the underlying asthenosphere, the high alkalinity ceases to be a requirement for the stability of the carbonate melt. Nevertheless, the regularities established here for the K-rich melts remain valid for less alkaline (4–15 wt% Na2O+K2O) primary kimberlite (i.e., mantle carbonatite) melts in the sublithospheric mantle.

AB - It is generally accepted that carbonatite metasomatism in the subcontinental lithospheric mantle (SCLM) inevitably causes wehrlitization of the primary lherzolite substrate. However, the K-rich carbonatite inclusions in kimberlitic diamonds containing orthopyroxene indicate that this is not always the case. In the present study, we equilibrated natural garnet lherzolite with carbonate melts containing 33–38 wt% K2O with various Ca# = 10, 20, 30, and 40 at 6 GPa and 1200–1500 °C, where Ca# = 100⋅Ca/(Ca+Mg+Fe). The original ratio of peridotite to carbonate was 58 to 42 by weight. In the studied temperature range, the melt retains essentially carbonate composition with silica content increasing from 1 to 11–12 wt%. The melt with Ca# 10 alters lherzolite to harzburgite, replacing clinopyroxene by orthopyroxene and decreasing CaO content in garnet below 4 wt%. The melts with Ca# 20-30 also consume clinopyroxene; although CaO content in garnet remains in the range of lherzolitic compositions. The melt with Ca# 40 yields wehrlitization, consuming orthopyroxene, increasing clinopyroxene fraction, and increasing CaO content in garnet above 6 wt%. After the interaction, the Ca# of the melt changes as follows 10 → 16–28, 20 → 20–33, 30 → 27–34, and 40 → 30–34. The olivine + orthopyroxene + clinopyroxene + garnet assemblage was found in equilibrium with carbonatite melt with Ca# 34 at 1200 °C and Ca# 30 at 1400 °C. Thus, K-rich (26–35 wt% K2O) carbonatite melts with Ca# = 30-34 can appear in equilibrium with garnet lherzolite, while the melts with Ca# < 30 and > 34 can be in equilibrium with harzburgite and wehrlite, respectively, at 6 GPa and 1200–1400 °C. Considering that Ca-Mg-Fe carbonates do not melt at the geothermal conditions of the SCLM, while sodic, dolomitic melt causes wehrlitization, high-Mg (Ca# < 35) K-rich dolomitic melt is the only possible carbonatite fluids that are thermodynamically stable in equilibrium with garnet harzburgites and lherzolites in the SCLM at a depth of about 200 km. At higher temperatures corresponding to the underlying asthenosphere, the high alkalinity ceases to be a requirement for the stability of the carbonate melt. Nevertheless, the regularities established here for the K-rich melts remain valid for less alkaline (4–15 wt% Na2O+K2O) primary kimberlite (i.e., mantle carbonatite) melts in the sublithospheric mantle.

KW - carbonatite melt

KW - Earth's mantle

KW - high-pressure experiment

KW - lherzolite

KW - mantle metasomatism

KW - wehrlitization

UR - http://www.scopus.com/inward/record.url?scp=85124202228&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/fed6f48f-17a5-3985-b3f5-9e9a15076998/

U2 - 10.1016/j.epsl.2022.117395

DO - 10.1016/j.epsl.2022.117395

M3 - Article

AN - SCOPUS:85124202228

VL - 581

JO - Earth and Planetary Science Letters

JF - Earth and Planetary Science Letters

SN - 0012-821X

M1 - 117395

ER -