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Through-bond and through-space radiofrequency amplification by stimulated emission of radiation. / Trofimov, Ivan A.; Salnikov, Oleg G.; Pravdivtsev, Andrey N. et al.

In: Communications Chemistry, Vol. 7, No. 1, 235, 23.10.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Trofimov, IA, Salnikov, OG, Pravdivtsev, AN, de Maissin, H, Yi, AP, Chekmenev, EY, Hövener, JB, Schmidt, AB & Koptyug, IV 2024, 'Through-bond and through-space radiofrequency amplification by stimulated emission of radiation', Communications Chemistry, vol. 7, no. 1, 235. https://doi.org/10.1038/s42004-024-01313-0

APA

Trofimov, I. A., Salnikov, O. G., Pravdivtsev, A. N., de Maissin, H., Yi, A. P., Chekmenev, E. Y., Hövener, J. B., Schmidt, A. B., & Koptyug, I. V. (2024). Through-bond and through-space radiofrequency amplification by stimulated emission of radiation. Communications Chemistry, 7(1), [235]. https://doi.org/10.1038/s42004-024-01313-0

Vancouver

Trofimov IA, Salnikov OG, Pravdivtsev AN, de Maissin H, Yi AP, Chekmenev EY et al. Through-bond and through-space radiofrequency amplification by stimulated emission of radiation. Communications Chemistry. 2024 Oct 23;7(1):235. doi: 10.1038/s42004-024-01313-0

Author

Trofimov, Ivan A. ; Salnikov, Oleg G. ; Pravdivtsev, Andrey N. et al. / Through-bond and through-space radiofrequency amplification by stimulated emission of radiation. In: Communications Chemistry. 2024 ; Vol. 7, No. 1.

BibTeX

@article{4b522c3aa80c49a3af34f86c6b318550,
title = "Through-bond and through-space radiofrequency amplification by stimulated emission of radiation",
abstract = "Radio Amplification by Stimulated Emission of Radiation (RASER) is a phenomenon observed during nuclear magnetic resonance (NMR) experiments with strongly negatively polarized systems. This phenomenon may be utilized for the production of very narrow NMR lines, background-free NMR spectroscopy, and excitation-free sensing of chemical transformations. Recently, novel methods of producing RASER by ParaHydrogen-Induced Polarization (PHIP) were introduced. Here, we show that pairwise addition of parahydrogen to various propargylic compounds induces RASER activity of other protons beyond those chemically introduced in the reaction. In high-field PHIP, negative polarization initiating RASER is transferred via intramolecular cross-relaxation. When parahydrogen is added in Earth{\textquoteright}s field followed by adiabatic transfer to a high field, RASER activity of other protons is induced via both J-couplings and cross-relaxation. This through-bond and through-space induction of RASER holds potential for the ongoing development and expansion of RASER applications and can potentially enhance spectral resolution in two-dimensional NMR spectroscopy techniques.",
author = "Trofimov, {Ivan A.} and Salnikov, {Oleg G.} and Pravdivtsev, {Andrey N.} and {de Maissin}, Henri and Yi, {Anna P.} and Chekmenev, {Eduard Y.} and H{\"o}vener, {Jan Bernd} and Schmidt, {Andreas B.} and Koptyug, {Igor V.}",
year = "2024",
month = oct,
day = "23",
doi = "10.1038/s42004-024-01313-0",
language = "English",
volume = "7",
journal = "Communications Chemistry",
issn = "2399-3669",
publisher = "Springer Nature",
number = "1",

}

RIS

TY - JOUR

T1 - Through-bond and through-space radiofrequency amplification by stimulated emission of radiation

AU - Trofimov, Ivan A.

AU - Salnikov, Oleg G.

AU - Pravdivtsev, Andrey N.

AU - de Maissin, Henri

AU - Yi, Anna P.

AU - Chekmenev, Eduard Y.

AU - Hövener, Jan Bernd

AU - Schmidt, Andreas B.

AU - Koptyug, Igor V.

PY - 2024/10/23

Y1 - 2024/10/23

N2 - Radio Amplification by Stimulated Emission of Radiation (RASER) is a phenomenon observed during nuclear magnetic resonance (NMR) experiments with strongly negatively polarized systems. This phenomenon may be utilized for the production of very narrow NMR lines, background-free NMR spectroscopy, and excitation-free sensing of chemical transformations. Recently, novel methods of producing RASER by ParaHydrogen-Induced Polarization (PHIP) were introduced. Here, we show that pairwise addition of parahydrogen to various propargylic compounds induces RASER activity of other protons beyond those chemically introduced in the reaction. In high-field PHIP, negative polarization initiating RASER is transferred via intramolecular cross-relaxation. When parahydrogen is added in Earth’s field followed by adiabatic transfer to a high field, RASER activity of other protons is induced via both J-couplings and cross-relaxation. This through-bond and through-space induction of RASER holds potential for the ongoing development and expansion of RASER applications and can potentially enhance spectral resolution in two-dimensional NMR spectroscopy techniques.

AB - Radio Amplification by Stimulated Emission of Radiation (RASER) is a phenomenon observed during nuclear magnetic resonance (NMR) experiments with strongly negatively polarized systems. This phenomenon may be utilized for the production of very narrow NMR lines, background-free NMR spectroscopy, and excitation-free sensing of chemical transformations. Recently, novel methods of producing RASER by ParaHydrogen-Induced Polarization (PHIP) were introduced. Here, we show that pairwise addition of parahydrogen to various propargylic compounds induces RASER activity of other protons beyond those chemically introduced in the reaction. In high-field PHIP, negative polarization initiating RASER is transferred via intramolecular cross-relaxation. When parahydrogen is added in Earth’s field followed by adiabatic transfer to a high field, RASER activity of other protons is induced via both J-couplings and cross-relaxation. This through-bond and through-space induction of RASER holds potential for the ongoing development and expansion of RASER applications and can potentially enhance spectral resolution in two-dimensional NMR spectroscopy techniques.

UR - https://www.webofscience.com/wos/woscc/full-record/WOS:001333847100001

UR - https://www.mendeley.com/catalogue/71df6c78-32b3-3c4e-9287-2b3d3def6ffa/

U2 - 10.1038/s42004-024-01313-0

DO - 10.1038/s42004-024-01313-0

M3 - Article

C2 - 39414912

VL - 7

JO - Communications Chemistry

JF - Communications Chemistry

SN - 2399-3669

IS - 1

M1 - 235

ER -

ID: 61254438