Three-dimensional copper(II) carboxylates based on 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid)

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Three-dimensional copper(II) carboxylates based on 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid). / Zavakhina, M. S.; Samsonenko, D. G.; Dybtsev, D. N. et al.

In: Russian Chemical Bulletin, Vol. 67, No. 1, 01.01.2018, p. 36-44.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{e37f8d1f92164bd1bde08ed8dd2e3b15,

title = "Three-dimensional copper(II) carboxylates based on 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid)",

abstract = "The homochiral coordination polymers [Cu4(CH3OH)(H2O)4(Hbtb)(S-mal)2]•4H2O and [Cu4(CH3OH)(H2O)4(Hbtb)(R-mal)2]•4H2O were synthesized by heating S- or R-malic acid (H3mal), 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid) (H3btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu6(C4H8O2)3(H2O)3(btb)4]•4C4H8O2•10H2O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.",

keywords = "chiral complexes, coordination frameworks, copper(II) complexes, crystal structure, malic acid",

author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

year = "2018",

month = jan,

day = "1",

doi = "10.1007/s11172-018-2034-6",

language = "English",

volume = "67",

pages = "36--44",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "1",

}

RIS

TY - JOUR

T1 - Three-dimensional copper(II) carboxylates based on 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid)

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The homochiral coordination polymers [Cu4(CH3OH)(H2O)4(Hbtb)(S-mal)2]•4H2O and [Cu4(CH3OH)(H2O)4(Hbtb)(R-mal)2]•4H2O were synthesized by heating S- or R-malic acid (H3mal), 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid) (H3btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu6(C4H8O2)3(H2O)3(btb)4]•4C4H8O2•10H2O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.

AB - The homochiral coordination polymers [Cu4(CH3OH)(H2O)4(Hbtb)(S-mal)2]•4H2O and [Cu4(CH3OH)(H2O)4(Hbtb)(R-mal)2]•4H2O were synthesized by heating S- or R-malic acid (H3mal), 4,4′,4″-benzene-1,3,5-triyltris(benzoic acid) (H3btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu6(C4H8O2)3(H2O)3(btb)4]•4C4H8O2•10H2O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.

KW - chiral complexes

KW - coordination frameworks

KW - copper(II) complexes

KW - crystal structure

KW - malic acid

UR - http://www.scopus.com/inward/record.url?scp=85045842479&partnerID=8YFLogxK

U2 - 10.1007/s11172-018-2034-6

DO - 10.1007/s11172-018-2034-6

M3 - Article

AN - SCOPUS:85045842479

VL - 67

SP - 36

EP - 44

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 1

ER -

ID: 12799174