Three-dimensional copper(II) carboxylates based on 4,4 ',4 ''-benzene-1,3,5-triyltris(benzoic acid)

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Three-dimensional copper(II) carboxylates based on 4,4 ',4 ''-benzene-1,3,5-triyltris(benzoic acid). / Zavakhina, M. S.; Samsonenko, D. G.; Dybtsev, D. N. et al.

In: Russian Chemical Bulletin, Vol. 67, No. 1, 01.2018, p. 36-44.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{543857ef253549dcb433837f8e612631,

title = "Three-dimensional copper(II) carboxylates based on 4,4 ',4 ''-benzene-1,3,5-triyltris(benzoic acid)",

abstract = "The homochiral coordination polymers [Cu-4(CH3OH)(H2O)(4)(Hbtb)(S-mal)(2)]center dot 4H(2)O and [Cu-4(CH3OH)(H2O)(4)(Hbtb)(R-mal)(2)]center dot 4H(2)O were synthesized by heating S- or R-malic acid (H(3)mal), 4,4',4 ''-benzene-1,3,5-triyltris(benzoic acid) (H(3)btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu-6(C4H8O2)(3)(H2O)(3)(btb)(4)]center dot 4C(4)H(8)O(2)center dot 10H(2)O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.",

keywords = "copper(II) complexes, crystal structure, coordination frameworks, chiral complexes, malic acid, METAL-ORGANIC FRAMEWORKS, COORDINATION POLYMERS, CRYSTAL-STRUCTURE, ENANTIOSELECTIVE SEPARATION, LIGANDS, SURFACE",

author = "Zavakhina, {M. S.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

year = "2018",

month = jan,

language = "English",

volume = "67",

pages = "36--44",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "1",

}

RIS

TY - JOUR

T1 - Three-dimensional copper(II) carboxylates based on 4,4 ',4 ''-benzene-1,3,5-triyltris(benzoic acid)

AU - Zavakhina, M. S.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2018/1

Y1 - 2018/1

N2 - The homochiral coordination polymers [Cu-4(CH3OH)(H2O)(4)(Hbtb)(S-mal)(2)]center dot 4H(2)O and [Cu-4(CH3OH)(H2O)(4)(Hbtb)(R-mal)(2)]center dot 4H(2)O were synthesized by heating S- or R-malic acid (H(3)mal), 4,4',4 ''-benzene-1,3,5-triyltris(benzoic acid) (H(3)btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu-6(C4H8O2)(3)(H2O)(3)(btb)(4)]center dot 4C(4)H(8)O(2)center dot 10H(2)O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.

AB - The homochiral coordination polymers [Cu-4(CH3OH)(H2O)(4)(Hbtb)(S-mal)(2)]center dot 4H(2)O and [Cu-4(CH3OH)(H2O)(4)(Hbtb)(R-mal)(2)]center dot 4H(2)O were synthesized by heating S- or R-malic acid (H(3)mal), 4,4',4 ''-benzene-1,3,5-triyltris(benzoic acid) (H(3)btb), and copper(II) acetate in an aqueous methanolic solution. The reaction with copper(II) nitrate in aqueous dioxane afforded the coordination framework [Cu-6(C4H8O2)(3)(H2O)(3)(btb)(4)]center dot 4C(4)H(8)O(2)center dot 10H(2)O, which does not contain chiral ligands. The compositions and crystal structures of the new compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric and elemental analysis.

KW - copper(II) complexes

KW - crystal structure

KW - coordination frameworks

KW - chiral complexes

KW - malic acid

KW - METAL-ORGANIC FRAMEWORKS

KW - COORDINATION POLYMERS

KW - CRYSTAL-STRUCTURE

KW - ENANTIOSELECTIVE SEPARATION

KW - LIGANDS

KW - SURFACE

M3 - Article

VL - 67

SP - 36

EP - 44

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 1

ER -

ID: 18649456