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Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]. / Shamshurin, M. V.; Sukhikh, T. S.; Mikhailov, M. A. et al.

In: Journal of Structural Chemistry, Vol. 61, No. 5, 01.05.2020, p. 727-733.

Research output: Contribution to journal › Article › peer-review

Harvard

Shamshurin, MV, Sukhikh, TS, Mikhailov, MA, Sheven, DG & Sokolov, MN 2020, 'Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]', Journal of Structural Chemistry, vol. 61, no. 5, pp. 727-733. https://doi.org/10.1134/S002247662005008X

APA

Shamshurin, M. V., Sukhikh, T. S., Mikhailov, M. A., Sheven, D. G., & Sokolov, M. N. (2020). Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]. Journal of Structural Chemistry, 61(5), 727-733. https://doi.org/10.1134/S002247662005008X

Vancouver

Shamshurin MV, Sukhikh TS, Mikhailov MA, Sheven DG, Sokolov MN. Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]. Journal of Structural Chemistry. 2020 May 1;61(5):727-733. doi: 10.1134/S002247662005008X

Author

Shamshurin, M. V. ; Sukhikh, T. S. ; Mikhailov, M. A. et al. / Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]. In: Journal of Structural Chemistry. 2020 ; Vol. 61, No. 5. pp. 727-733.

BibTeX

@article{3aae85f7c885445389f5518552245f3a,
title = "Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]",
abstract = "The reaction of Ta6I14 with KNCS in acetonitrile in the presence of 24-dibenzo-crown-8 leads to dissolution of the tantalum iodide cluster to form the [Ta6I12(NCS)6]4− complex. By evaporation of the solution with the subsequent treatment of the precipitate with acetone and PPh4Br, dark green single crystals of the composition [K(C24H32O8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6] CH3COCH3(1) are obtained with a yield of 29%. The product is characterized by elemental analysis, IR, and mass spectra. The crystal structure is determined by the X-ray diffraction analysis.",
keywords = "clusters, crown ethers, iodides, isothiocyanate complex {TaI}, tantalum, X-ray diffraction analysis",
author = "Shamshurin, {M. V.} and Sukhikh, {T. S.} and Mikhailov, {M. A.} and Sheven, {D. G.} and Sokolov, {M. N.}",
year = "2020",
month = may,
day = "1",
doi = "10.1134/S002247662005008X",
language = "English",
volume = "61",
pages = "727--733",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "5",

}

RIS

TY - JOUR

T1 - Thiocyanate Coordination to the {Ta6I12}2+ Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6]

AU - Shamshurin, M. V.

AU - Sukhikh, T. S.

AU - Mikhailov, M. A.

AU - Sheven, D. G.

AU - Sokolov, M. N.

PY - 2020/5/1

Y1 - 2020/5/1

N2 - The reaction of Ta6I14 with KNCS in acetonitrile in the presence of 24-dibenzo-crown-8 leads to dissolution of the tantalum iodide cluster to form the [Ta6I12(NCS)6]4− complex. By evaporation of the solution with the subsequent treatment of the precipitate with acetone and PPh4Br, dark green single crystals of the composition [K(C24H32O8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6] CH3COCH3(1) are obtained with a yield of 29%. The product is characterized by elemental analysis, IR, and mass spectra. The crystal structure is determined by the X-ray diffraction analysis.

AB - The reaction of Ta6I14 with KNCS in acetonitrile in the presence of 24-dibenzo-crown-8 leads to dissolution of the tantalum iodide cluster to form the [Ta6I12(NCS)6]4− complex. By evaporation of the solution with the subsequent treatment of the precipitate with acetone and PPh4Br, dark green single crystals of the composition [K(C24H32O8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6] CH3COCH3(1) are obtained with a yield of 29%. The product is characterized by elemental analysis, IR, and mass spectra. The crystal structure is determined by the X-ray diffraction analysis.

KW - clusters

KW - crown ethers

KW - iodides

KW - isothiocyanate complex {TaI}

KW - tantalum

KW - X-ray diffraction analysis

UR - http://www.scopus.com/inward/record.url?scp=85089236621&partnerID=8YFLogxK

U2 - 10.1134/S002247662005008X

DO - 10.1134/S002247662005008X

M3 - Article

AN - SCOPUS:85089236621

VL - 61

SP - 727

EP - 733

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 24957032