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Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia : An optical spectroscopy study. / Basova, Tamara V.; Mikhaleva, Natalia S.; Hassan, Aseel K. et al.

In: Sensors and Actuators, B: Chemical, Vol. 227, 01.05.2016, p. 634-642.

Research output: Contribution to journal › Article › peer-review

Harvard

Basova, TV, Mikhaleva, NS, Hassan, AK & Kiselev, VG 2016, 'Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia: An optical spectroscopy study', Sensors and Actuators, B: Chemical, vol. 227, pp. 634-642. https://doi.org/10.1016/j.snb.2015.12.079

APA

Basova, T. V., Mikhaleva, N. S., Hassan, A. K., & Kiselev, V. G. (2016). Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia: An optical spectroscopy study. Sensors and Actuators, B: Chemical, 227, 634-642. https://doi.org/10.1016/j.snb.2015.12.079

Vancouver

Basova TV, Mikhaleva NS, Hassan AK, Kiselev VG. Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia: An optical spectroscopy study. Sensors and Actuators, B: Chemical. 2016 May 1;227:634-642. doi: 10.1016/j.snb.2015.12.079

Author

Basova, Tamara V. ; Mikhaleva, Natalia S. ; Hassan, Aseel K. et al. / Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia : An optical spectroscopy study. In: Sensors and Actuators, B: Chemical. 2016 ; Vol. 227. pp. 634-642.

BibTeX

@article{c476175d14cb4a38af3978eb87079902,
title = "Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia: An optical spectroscopy study",
abstract = "A comparative study of the sensor response toward gaseous ammonia of hexadecafluorinated 3d-metal phthalocyanine (MPcF16, M=Cu(II), Co(II), Zn(II), Ni(II)) thin films was performed using complementary experimental (viz., surface plasmon resonance, SPR, and IR absorption spectroscopy) along with theoretical (density functional theory calculations, DFT) techniques. SPR measurements revealed changes of both thickness and optical parameters (refraction indices and extinction coefficients) of the MPcF16 films caused by adsorption of NH3. The MPcF16 species studied exhibited the following order of sensor response: ZnPcF16 > CoPcF16 ≥ CuPcF16 > NiPcF16. A good correlation was found between the DFT calculated (B3LYP/6-311++G(2df,p)) binding energies, experimentally measured shift of the selected IR bands, and the optical sensor response. Apart from this, we performed a detailed assignment of all intense bands in the vibrational spectra (IR and Raman) of fluorinated 3d-metal phthalocyanines studied.",
keywords = "Ammonia detection, DFT, Hexadecafluorinated phthalocyanines, Optical sensors, SPR, Vibrational Spectra",
author = "Basova, {Tamara V.} and Mikhaleva, {Natalia S.} and Hassan, {Aseel K.} and Kiselev, {Vitaly G.}",
year = "2016",
month = may,
day = "1",
doi = "10.1016/j.snb.2015.12.079",
language = "English",
volume = "227",
pages = "634--642",
journal = "Sensors and Actuators, B: Chemical",
issn = "0925-4005",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia

T2 - An optical spectroscopy study

AU - Basova, Tamara V.

AU - Mikhaleva, Natalia S.

AU - Hassan, Aseel K.

AU - Kiselev, Vitaly G.

PY - 2016/5/1

Y1 - 2016/5/1

N2 - A comparative study of the sensor response toward gaseous ammonia of hexadecafluorinated 3d-metal phthalocyanine (MPcF16, M=Cu(II), Co(II), Zn(II), Ni(II)) thin films was performed using complementary experimental (viz., surface plasmon resonance, SPR, and IR absorption spectroscopy) along with theoretical (density functional theory calculations, DFT) techniques. SPR measurements revealed changes of both thickness and optical parameters (refraction indices and extinction coefficients) of the MPcF16 films caused by adsorption of NH3. The MPcF16 species studied exhibited the following order of sensor response: ZnPcF16 > CoPcF16 ≥ CuPcF16 > NiPcF16. A good correlation was found between the DFT calculated (B3LYP/6-311++G(2df,p)) binding energies, experimentally measured shift of the selected IR bands, and the optical sensor response. Apart from this, we performed a detailed assignment of all intense bands in the vibrational spectra (IR and Raman) of fluorinated 3d-metal phthalocyanines studied.

AB - A comparative study of the sensor response toward gaseous ammonia of hexadecafluorinated 3d-metal phthalocyanine (MPcF16, M=Cu(II), Co(II), Zn(II), Ni(II)) thin films was performed using complementary experimental (viz., surface plasmon resonance, SPR, and IR absorption spectroscopy) along with theoretical (density functional theory calculations, DFT) techniques. SPR measurements revealed changes of both thickness and optical parameters (refraction indices and extinction coefficients) of the MPcF16 films caused by adsorption of NH3. The MPcF16 species studied exhibited the following order of sensor response: ZnPcF16 > CoPcF16 ≥ CuPcF16 > NiPcF16. A good correlation was found between the DFT calculated (B3LYP/6-311++G(2df,p)) binding energies, experimentally measured shift of the selected IR bands, and the optical sensor response. Apart from this, we performed a detailed assignment of all intense bands in the vibrational spectra (IR and Raman) of fluorinated 3d-metal phthalocyanines studied.

KW - Ammonia detection

KW - DFT

KW - Hexadecafluorinated phthalocyanines

KW - Optical sensors

KW - SPR

KW - Vibrational Spectra

UR - http://www.scopus.com/inward/record.url?scp=84954348214&partnerID=8YFLogxK

U2 - 10.1016/j.snb.2015.12.079

DO - 10.1016/j.snb.2015.12.079

M3 - Article

AN - SCOPUS:84954348214

VL - 227

SP - 634

EP - 642

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

SN - 0925-4005

ER -

ID: 25437144