Standard

Thermodynamic Study of Lithium Tungstate Single Crystals Doped by Molybdenum (Li2W1- xMo xO4, x = 0.1 and 0.15). / Matskevich, Nata I.; Shlegel, Vladimir N.; Semerikova, Anna N. et al.

In: Journal of Chemical and Engineering Data, Vol. 65, No. 4, 09.04.2020, p. 1523-1530.

Research output: Contribution to journal › Article › peer-review

Harvard

Matskevich, NI, Shlegel, VN, Semerikova, AN & Matskevich, MY 2020, 'Thermodynamic Study of Lithium Tungstate Single Crystals Doped by Molybdenum (Li2W1- xMo xO4, x = 0.1 and 0.15)', Journal of Chemical and Engineering Data, vol. 65, no. 4, pp. 1523-1530. https://doi.org/10.1021/acs.jced.9b00941

APA

Matskevich, N. I., Shlegel, V. N., Semerikova, A. N., & Matskevich, M. Y. (2020). Thermodynamic Study of Lithium Tungstate Single Crystals Doped by Molybdenum (Li2W1- xMo xO4, x = 0.1 and 0.15). Journal of Chemical and Engineering Data, 65(4), 1523-1530. https://doi.org/10.1021/acs.jced.9b00941

Vancouver

Matskevich NI, Shlegel VN, Semerikova AN, Matskevich MY. Thermodynamic Study of Lithium Tungstate Single Crystals Doped by Molybdenum (Li2W1- xMo xO4, x = 0.1 and 0.15). Journal of Chemical and Engineering Data. 2020 Apr 9;65(4):1523-1530. doi: 10.1021/acs.jced.9b00941

Author

Matskevich, Nata I. ; Shlegel, Vladimir N. ; Semerikova, Anna N. et al. / Thermodynamic Study of Lithium Tungstate Single Crystals Doped by Molybdenum (Li2W1- xMo xO4, x = 0.1 and 0.15). In: Journal of Chemical and Engineering Data. 2020 ; Vol. 65, No. 4. pp. 1523-1530.

BibTeX

@article{fe71df6402cc479a9b00448b47bdb330,
title = "Thermodynamic Study of Lithium Tungstate Single Crystals Doped by Molybdenum (Li2W1- xMo xO4, x = 0.1 and 0.15)",
abstract = "The single crystals Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4 have been grown by a low-temperature-gradient Czochralski technique as representatives of promising materials for scintillating cryogenic bolometers. Thermodynamic properties and their relationship with structural parameters to improve and extend the device portfolio with special emphasis on formation enthalpies, thermodynamic stability, and lattice enthalpies have been revealed. Solution enthalpies of Li2CO3, MoO3, and Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4 single crystals have been measured in 0.40162 mol kg-1 aqueous KOH. The standard formation enthalpies (ΔfH0 (Li2W0.85Mo0.15O4, s, 298.15 K) = -1590.8 ± 2.0 kJ mol-1 ΔfH0 (Li2W0.9Mo0.1O4, s, 298.15 K) = -1594.1 ± 2.3 kJ mol-1), formation enthalpies from simple oxides, and lattice enthalpies have been determined. As a result, the dependences of formation enthalpies and lattice enthalpies for Li2W1-xMoxO4 on tolerance factors have been found to be linear. It has been discovered that the thermodynamic stability and lattice enthalpies of Li2W1-xMoxO4 are increased when the tolerance factor tends to one. It has been established that single crystals Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4",
keywords = "STANDARD ENTHALPY, HEAT-CAPACITY, MOLYBDATE, THERMOCHEMISTRY, ENERGIES, PROGRESS, LI2MOO4, SYSTEMS, GROWTH, LI2WO4",
author = "Matskevich, {Nata I.} and Shlegel, {Vladimir N.} and Semerikova, {Anna N.} and Matskevich, {Mariya Yu}",
year = "2020",
month = apr,
day = "9",
doi = "10.1021/acs.jced.9b00941",
language = "English",
volume = "65",
pages = "1523--1530",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Thermodynamic Study of Lithium Tungstate Single Crystals Doped by Molybdenum (Li2W1- xMo xO4, x = 0.1 and 0.15)

AU - Matskevich, Nata I.

AU - Shlegel, Vladimir N.

AU - Semerikova, Anna N.

AU - Matskevich, Mariya Yu

PY - 2020/4/9

Y1 - 2020/4/9

N2 - The single crystals Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4 have been grown by a low-temperature-gradient Czochralski technique as representatives of promising materials for scintillating cryogenic bolometers. Thermodynamic properties and their relationship with structural parameters to improve and extend the device portfolio with special emphasis on formation enthalpies, thermodynamic stability, and lattice enthalpies have been revealed. Solution enthalpies of Li2CO3, MoO3, and Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4 single crystals have been measured in 0.40162 mol kg-1 aqueous KOH. The standard formation enthalpies (ΔfH0 (Li2W0.85Mo0.15O4, s, 298.15 K) = -1590.8 ± 2.0 kJ mol-1 ΔfH0 (Li2W0.9Mo0.1O4, s, 298.15 K) = -1594.1 ± 2.3 kJ mol-1), formation enthalpies from simple oxides, and lattice enthalpies have been determined. As a result, the dependences of formation enthalpies and lattice enthalpies for Li2W1-xMoxO4 on tolerance factors have been found to be linear. It has been discovered that the thermodynamic stability and lattice enthalpies of Li2W1-xMoxO4 are increased when the tolerance factor tends to one. It has been established that single crystals Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4

AB - The single crystals Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4 have been grown by a low-temperature-gradient Czochralski technique as representatives of promising materials for scintillating cryogenic bolometers. Thermodynamic properties and their relationship with structural parameters to improve and extend the device portfolio with special emphasis on formation enthalpies, thermodynamic stability, and lattice enthalpies have been revealed. Solution enthalpies of Li2CO3, MoO3, and Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4 single crystals have been measured in 0.40162 mol kg-1 aqueous KOH. The standard formation enthalpies (ΔfH0 (Li2W0.85Mo0.15O4, s, 298.15 K) = -1590.8 ± 2.0 kJ mol-1 ΔfH0 (Li2W0.9Mo0.1O4, s, 298.15 K) = -1594.1 ± 2.3 kJ mol-1), formation enthalpies from simple oxides, and lattice enthalpies have been determined. As a result, the dependences of formation enthalpies and lattice enthalpies for Li2W1-xMoxO4 on tolerance factors have been found to be linear. It has been discovered that the thermodynamic stability and lattice enthalpies of Li2W1-xMoxO4 are increased when the tolerance factor tends to one. It has been established that single crystals Li2W0.85Mo0.15O4 and Li2W0.9Mo0.1O4

KW - STANDARD ENTHALPY

KW - HEAT-CAPACITY

KW - MOLYBDATE

KW - THERMOCHEMISTRY

KW - ENERGIES

KW - PROGRESS

KW - LI2MOO4

KW - SYSTEMS

KW - GROWTH

KW - LI2WO4

UR - http://www.scopus.com/inward/record.url?scp=85081247713&partnerID=8YFLogxK

U2 - 10.1021/acs.jced.9b00941

DO - 10.1021/acs.jced.9b00941

M3 - Article

AN - SCOPUS:85081247713

VL - 65

SP - 1523

EP - 1530

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 4

ER -

ID: 23792929