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Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules. / Kozlova, Svetlana G.; Gabuda, Svyatoslav P.

In: Scientific Reports, Vol. 7, No. 1, 11505, 14.09.2017, p. 11505.

Research output: Contribution to journal › Article › peer-review

Harvard

Kozlova, SG & Gabuda, SP 2017, 'Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules', Scientific Reports, vol. 7, no. 1, 11505, pp. 11505. https://doi.org/10.1038/s41598-017-11326-6

APA

Kozlova, S. G., & Gabuda, S. P. (2017). Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules. Scientific Reports, 7(1), 11505. [11505]. https://doi.org/10.1038/s41598-017-11326-6

Vancouver

Kozlova SG, Gabuda SP. Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules. Scientific Reports. 2017 Sept 14;7(1):11505. 11505. doi: 10.1038/s41598-017-11326-6

Author

Kozlova, Svetlana G. ; Gabuda, Svyatoslav P. / Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules. In: Scientific Reports. 2017 ; Vol. 7, No. 1. pp. 11505.

BibTeX

@article{ae2381d9f0e74bd28488e622aab66090,
title = "Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules",
abstract = "Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound at 8-300 K suggest the possibility of subbarrier tunnelling transitions between left-twisted (S) and right-twisted (R) forms of C6H12N2 dabco molecules with D3 point symmetry. The data agree with those obtained for the temperature behavior of nuclear spin-lattice relaxation times. It is shown that there is a temperature range where the transitions are stopped. Therefore, Zn2(C8H4O4)2•C6H12N2 and related compounds are interesting objects to study the effect of spontaneous mirror-symmetry breaking and stabilization of chiral isomeric molecules in solids at low temperatures.",
keywords = "BEHAVIOR, CRYSTALS, DYNAMICS, HEAT-CAPACITY, NMR, PHASE-TRANSITIONS, RELAXATION",
author = "Kozlova, {Svetlana G.} and Gabuda, {Svyatoslav P.}",
note = "Publisher Copyright: {\textcopyright} 2017 The Author(s).",
year = "2017",
month = sep,
day = "14",
doi = "10.1038/s41598-017-11326-6",
language = "English",
volume = "7",
pages = "11505",
journal = "Scientific Reports",
issn = "2045-2322",
publisher = "Nature Publishing Group",
number = "1",

}

RIS

TY - JOUR

T1 - Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound and mirror symmetry violation of dabco molecules

AU - Kozlova, Svetlana G.

AU - Gabuda, Svyatoslav P.

N1 - Publisher Copyright: © 2017 The Author(s).

PY - 2017/9/14

Y1 - 2017/9/14

N2 - Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound at 8-300 K suggest the possibility of subbarrier tunnelling transitions between left-twisted (S) and right-twisted (R) forms of C6H12N2 dabco molecules with D3 point symmetry. The data agree with those obtained for the temperature behavior of nuclear spin-lattice relaxation times. It is shown that there is a temperature range where the transitions are stopped. Therefore, Zn2(C8H4O4)2•C6H12N2 and related compounds are interesting objects to study the effect of spontaneous mirror-symmetry breaking and stabilization of chiral isomeric molecules in solids at low temperatures.

AB - Thermal properties of Zn2(C8H4O4)2•C6H12N2 metal-organic framework compound at 8-300 K suggest the possibility of subbarrier tunnelling transitions between left-twisted (S) and right-twisted (R) forms of C6H12N2 dabco molecules with D3 point symmetry. The data agree with those obtained for the temperature behavior of nuclear spin-lattice relaxation times. It is shown that there is a temperature range where the transitions are stopped. Therefore, Zn2(C8H4O4)2•C6H12N2 and related compounds are interesting objects to study the effect of spontaneous mirror-symmetry breaking and stabilization of chiral isomeric molecules in solids at low temperatures.

KW - BEHAVIOR

KW - CRYSTALS

KW - DYNAMICS

KW - HEAT-CAPACITY

KW - NMR

KW - PHASE-TRANSITIONS

KW - RELAXATION

UR - http://www.scopus.com/inward/record.url?scp=85029521690&partnerID=8YFLogxK

U2 - 10.1038/s41598-017-11326-6

DO - 10.1038/s41598-017-11326-6

M3 - Article

C2 - 28912483

AN - SCOPUS:85029521690

VL - 7

SP - 11505

JO - Scientific Reports

JF - Scientific Reports

SN - 2045-2322

IS - 1

M1 - 11505

ER -

ID: 9520751