The unique structure of [(C4H9)4N]3[Pb(NO3)5]—one step forward in understanding transport properties in tetra-n-butylammonium-based solid electrolytes

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The unique structure of [(C₄H₉)₄N]₃[Pb(NO₃)₅]—one step forward in understanding transport properties in tetra-n-butylammonium-based solid electrolytes. / Asanbaeva, Nargiz B.; Rychkov, Denis A.; Tyapkin, Pavel Yu et al.

In: Structural Chemistry, Vol. 32, No. 3, 06.2021, p. 1261-1267.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{fb9de93d36cb4c99b6e96e763c6a0cae,

title = "The unique structure of [(C4H9)4N]3[Pb(NO3)5]—one step forward in understanding transport properties in tetra-n-butylammonium-based solid electrolytes",

abstract = "The crystal and molecular structure of tris(tetrabutylammonium) pentanitratoplumbate(II) was determined and characterized by single-crystal and powder X-ray diffraction and IR spectroscopy. The structure is compared to other tetra-n-butylammonium-based metal complexes with inorganic ligands, showing a significant difference in space group and local surroundings. The Pb2+ cation is surrounded by five NO3− groups, forming a stable complex only in the crystal field. Part of (C4H9)4N+ cations are distorted significantly changing geometry from tetrahedra to almost flat (square) at room temperature. Discussion on possible reorientational motion of organic groups at high temperatures and its influence on ion transport processes within the crystal structure of tetra-n-butylammonium-based organic ionic plastic crystals is provided.",

keywords = "Crystal structure, High-temperature conductivity, Organic ionic plastic crystals, Tetra-n-butylammonium, Tris(tetrabutylammonium) pentanitratoplumbate(II)",

author = "Asanbaeva, {Nargiz B.} and Rychkov, {Denis A.} and Tyapkin, {Pavel Yu} and Arkhipov, {Sergey G.} and Uvarov, {Nikolay F.}",

note = "Sergey G. Arkhipov is grateful to a partial financial support from the budget project of Boreskov Institute of Catalysis. Funding Information: This work was supported by the RSF (Russian Science Foundation, http://rscf.ru/en/ ) (project 20-13-00302). Publisher Copyright: {\textcopyright} 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = jun,

doi = "10.1007/s11224-021-01732-y",

language = "English",

volume = "32",

pages = "1261--1267",

journal = "Structural Chemistry",

issn = "1040-0400",

publisher = "Springer New York",

number = "3",

}

RIS

TY - JOUR

T1 - The unique structure of [(C4H9)4N]3[Pb(NO3)5]—one step forward in understanding transport properties in tetra-n-butylammonium-based solid electrolytes

AU - Asanbaeva, Nargiz B.

AU - Rychkov, Denis A.

AU - Tyapkin, Pavel Yu

AU - Arkhipov, Sergey G.

AU - Uvarov, Nikolay F.

N1 - Sergey G. Arkhipov is grateful to a partial financial support from the budget project of Boreskov Institute of Catalysis. Funding Information: This work was supported by the RSF (Russian Science Foundation, http://rscf.ru/en/ ) (project 20-13-00302). Publisher Copyright: © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/6

Y1 - 2021/6

N2 - The crystal and molecular structure of tris(tetrabutylammonium) pentanitratoplumbate(II) was determined and characterized by single-crystal and powder X-ray diffraction and IR spectroscopy. The structure is compared to other tetra-n-butylammonium-based metal complexes with inorganic ligands, showing a significant difference in space group and local surroundings. The Pb2+ cation is surrounded by five NO3− groups, forming a stable complex only in the crystal field. Part of (C4H9)4N+ cations are distorted significantly changing geometry from tetrahedra to almost flat (square) at room temperature. Discussion on possible reorientational motion of organic groups at high temperatures and its influence on ion transport processes within the crystal structure of tetra-n-butylammonium-based organic ionic plastic crystals is provided.

AB - The crystal and molecular structure of tris(tetrabutylammonium) pentanitratoplumbate(II) was determined and characterized by single-crystal and powder X-ray diffraction and IR spectroscopy. The structure is compared to other tetra-n-butylammonium-based metal complexes with inorganic ligands, showing a significant difference in space group and local surroundings. The Pb2+ cation is surrounded by five NO3− groups, forming a stable complex only in the crystal field. Part of (C4H9)4N+ cations are distorted significantly changing geometry from tetrahedra to almost flat (square) at room temperature. Discussion on possible reorientational motion of organic groups at high temperatures and its influence on ion transport processes within the crystal structure of tetra-n-butylammonium-based organic ionic plastic crystals is provided.

KW - Crystal structure

KW - High-temperature conductivity

KW - Organic ionic plastic crystals

KW - Tetra-n-butylammonium

KW - Tris(tetrabutylammonium) pentanitratoplumbate(II)

UR - http://www.scopus.com/inward/record.url?scp=85099930143&partnerID=8YFLogxK

U2 - 10.1007/s11224-021-01732-y

DO - 10.1007/s11224-021-01732-y

M3 - Article

AN - SCOPUS:85099930143

VL - 32

SP - 1261

EP - 1267

JO - Structural Chemistry

JF - Structural Chemistry

SN - 1040-0400

IS - 3

ER -

ID: 27606977