Research output: Contribution to journal › Conference article › peer-review
The synthesis of Ru- and Pd- containing nanoparticles stabilized by the hypercrosslinked polystyrene for the selective hydrogenation of the furfural to the furfuryl alcohol. / Salnikova, Ksenia; Sulman, Mikhail; Larichev, Yury et al.
In: International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM, Vol. 19, No. 4.1, 01.01.2019, p. 547-552.Research output: Contribution to journal › Conference article › peer-review
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TY - JOUR
T1 - The synthesis of Ru- and Pd- containing nanoparticles stabilized by the hypercrosslinked polystyrene for the selective hydrogenation of the furfural to the furfuryl alcohol
AU - Salnikova, Ksenia
AU - Sulman, Mikhail
AU - Larichev, Yury
AU - Kosivtsov, Yury
AU - Matveeva, Valentina
PY - 2019/1/1
Y1 - 2019/1/1
N2 - We report the hydrogenation of furfural (FF) to furfuryl alcohol (FA) with Ru-and Pd-containing catalysts stabilized by hypercrosslinked polystyrene (HPS). Ru-and Pd-containing HPS-based catalysts were synthesized via wet-impregnation method. FF is one of the major ingredients of bio-oil produced by biomass pyrolysis, while FA is a source of value-added chemicals, thus, creating an effective path from biomass to important compounds. Different metal precursors were used for the synthesis of the catalyst. The nature of the metal influences the size of nanoparticles. The TEM data showed that for 3%-Pd/HPS catalyst Pd nanoparticles form monomodal distribution with mean diameter 5.4 ± 1.2 nm. For the sample 3%-Ru/ HPS, we also observed the monomodal particle size distribution with the mean particle sizes up to 1.4 ± 0.3 nm. The comparison with common catalysts showed that Ru-and Pd-catalysts synthesized in this work are the most effective. The excellent catalytic properties of the Ru catalyst are promising for practical applications.
AB - We report the hydrogenation of furfural (FF) to furfuryl alcohol (FA) with Ru-and Pd-containing catalysts stabilized by hypercrosslinked polystyrene (HPS). Ru-and Pd-containing HPS-based catalysts were synthesized via wet-impregnation method. FF is one of the major ingredients of bio-oil produced by biomass pyrolysis, while FA is a source of value-added chemicals, thus, creating an effective path from biomass to important compounds. Different metal precursors were used for the synthesis of the catalyst. The nature of the metal influences the size of nanoparticles. The TEM data showed that for 3%-Pd/HPS catalyst Pd nanoparticles form monomodal distribution with mean diameter 5.4 ± 1.2 nm. For the sample 3%-Ru/ HPS, we also observed the monomodal particle size distribution with the mean particle sizes up to 1.4 ± 0.3 nm. The comparison with common catalysts showed that Ru-and Pd-catalysts synthesized in this work are the most effective. The excellent catalytic properties of the Ru catalyst are promising for practical applications.
KW - Furfural
KW - Furfuryl alcohol
KW - Hydrogenation
KW - Hypercrosslinked polystyrene
KW - Ru-and Pd-containing nanoparticles
UR - http://www.scopus.com/inward/record.url?scp=85071910073&partnerID=8YFLogxK
U2 - 10.5593/sgem2019/4.1/S17.070
DO - 10.5593/sgem2019/4.1/S17.070
M3 - Conference article
AN - SCOPUS:85071910073
VL - 19
SP - 547
EP - 552
JO - International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM
JF - International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM
SN - 1314-2704
IS - 4.1
T2 - 19th International Multidisciplinary Scientific Geoconference, SGEM 2019
Y2 - 30 June 2019 through 6 July 2019
ER -
ID: 21468875