The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series

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The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series. / Zaytseva, Elena V.; Gatilov, Yury V.; Mazhukin, Dmitrii G.

In: Arkivoc, Vol. 2018, No. 5, 04.08.2018, p. 359-374.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{50ea869332df4a908dc6e1fa6648ba89,

title = "The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series",

abstract = "New non-conjugated functionalized 2,5-dihydroimidazole-type bi- and trinitroxyl radicals are described. The synthesis of which was based on a nucleophilic substitution reaction between 2,4,6-trichloro-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine and spiro-fused 2,5-dihydroimidazole-type monoradicals bearing both a p-hydroxyaryl moiety at the C-4 atom of the heterocycle and a residue at the fourth position of the cyclohexane ring. The model tris-nitroxide with an unsubstituted cyclohexane unit was structurally characterized in the solid state.",

keywords = "1,3,5-triazine-based nitroxides, 2,5-dihydroimidazoles, Biradicals, Organic free radicals, Triradicals, triradicals, 1,3,5-Triazine-based nitroxides, biradicals, SUBSTITUENT, PHASE, organic free radicals, LIQUID-CRYSTALS, RADICALS, DERIVATIVES, S-TRIAZINE",

author = "Zaytseva, {Elena V.} and Gatilov, {Yury V.} and Mazhukin, {Dmitrii G.}",

year = "2018",

month = aug,

day = "4",

doi = "10.24820/ark.5550190.p010.614",

language = "English",

volume = "2018",

pages = "359--374",

journal = "Arkivoc",

issn = "1551-7004",

publisher = "Arkat USA",

number = "5",

}

RIS

TY - JOUR

T1 - The synthesis of new functionalized 1,3,5-triazine-based stable bi- and trinitroxides of the 2,5-dihydroimidazole series

AU - Zaytseva, Elena V.

AU - Gatilov, Yury V.

AU - Mazhukin, Dmitrii G.

PY - 2018/8/4

Y1 - 2018/8/4

N2 - New non-conjugated functionalized 2,5-dihydroimidazole-type bi- and trinitroxyl radicals are described. The synthesis of which was based on a nucleophilic substitution reaction between 2,4,6-trichloro-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine and spiro-fused 2,5-dihydroimidazole-type monoradicals bearing both a p-hydroxyaryl moiety at the C-4 atom of the heterocycle and a residue at the fourth position of the cyclohexane ring. The model tris-nitroxide with an unsubstituted cyclohexane unit was structurally characterized in the solid state.

AB - New non-conjugated functionalized 2,5-dihydroimidazole-type bi- and trinitroxyl radicals are described. The synthesis of which was based on a nucleophilic substitution reaction between 2,4,6-trichloro-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine and spiro-fused 2,5-dihydroimidazole-type monoradicals bearing both a p-hydroxyaryl moiety at the C-4 atom of the heterocycle and a residue at the fourth position of the cyclohexane ring. The model tris-nitroxide with an unsubstituted cyclohexane unit was structurally characterized in the solid state.

KW - 1,3,5-triazine-based nitroxides

KW - 2,5-dihydroimidazoles

KW - Biradicals

KW - Organic free radicals

KW - Triradicals

KW - triradicals

KW - 1,3,5-Triazine-based nitroxides

KW - biradicals

KW - SUBSTITUENT

KW - PHASE

KW - organic free radicals

KW - LIQUID-CRYSTALS

KW - RADICALS

KW - DERIVATIVES

KW - S-TRIAZINE

UR - http://www.scopus.com/inward/record.url?scp=85054570320&partnerID=8YFLogxK

U2 - 10.24820/ark.5550190.p010.614

DO - 10.24820/ark.5550190.p010.614

M3 - Article

AN - SCOPUS:85054570320

VL - 2018

SP - 359

EP - 374

JO - Arkivoc

JF - Arkivoc

SN - 1551-7004

IS - 5

ER -

ID: 17035279