Research output: Contribution to journal › Article › peer-review
The study of Nickel product morphology developed during the gaseous reduction of Nickel oxide. / Skrypnik, A. S.; Matvienko, A. A.
In: Materials Today: Proceedings, Vol. 4, No. 11, 2017, p. 11425-11429.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - The study of Nickel product morphology developed during the gaseous reduction of Nickel oxide
AU - Skrypnik, A. S.
AU - Matvienko, A. A.
PY - 2017
Y1 - 2017
N2 - The effects of temperature and hydrogen partial pressure on porous nickel morphology during the low-temperature (T<500°C) reduction of bulk nickel oxide were studied. It was shown that during the reduction process of nickel oxide at 300°C in an atmosphere of pure hydrogen nickel metal thin plates assembled into bundles and separated by cracks were formed. Increasing the reaction temperature up to 500°C led to a significant change in the morphology of the metal and formation of a porous cellular structure with a mesh size of about 0.1-0.2 μm. Decrease of hydrogen partial pressure led to growth of metal mesh cells and transition from the plate-like to the cellular morphology at 300°C. It was shown, that both increasing the surface diffusion of metal atoms and decreasing the surface reaction rate led to a change from the plate-like to the cellular morphology and the growth of the cell size.
AB - The effects of temperature and hydrogen partial pressure on porous nickel morphology during the low-temperature (T<500°C) reduction of bulk nickel oxide were studied. It was shown that during the reduction process of nickel oxide at 300°C in an atmosphere of pure hydrogen nickel metal thin plates assembled into bundles and separated by cracks were formed. Increasing the reaction temperature up to 500°C led to a significant change in the morphology of the metal and formation of a porous cellular structure with a mesh size of about 0.1-0.2 μm. Decrease of hydrogen partial pressure led to growth of metal mesh cells and transition from the plate-like to the cellular morphology at 300°C. It was shown, that both increasing the surface diffusion of metal atoms and decreasing the surface reaction rate led to a change from the plate-like to the cellular morphology and the growth of the cell size.
KW - Nickel oxide
KW - Porous nickel
KW - Reduction process
UR - http://www.scopus.com/inward/record.url?scp=85032031260&partnerID=8YFLogxK
U2 - 10.1016/j.matpr.2017.09.021
DO - 10.1016/j.matpr.2017.09.021
M3 - Article
AN - SCOPUS:85032031260
VL - 4
SP - 11425
EP - 11429
JO - Materials Today: Proceedings
JF - Materials Today: Proceedings
SN - 2214-7853
IS - 11
ER -
ID: 9053681