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The Reaction of Re3Br9 with P(CH2OH)3 : Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters. / Anyushin, A. V.; Abramov, P. A.; Sokolov, M. N.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 45, No. 8, 01.08.2019, p. 548-554.

Research output: Contribution to journal › Article › peer-review

Harvard

Anyushin, AV, Abramov, PA & Sokolov, MN 2019, 'The Reaction of Re3Br9 with P(CH2OH)3: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 45, no. 8, pp. 548-554. https://doi.org/10.1134/S1070328419080013

APA

Anyushin, A. V., Abramov, P. A., & Sokolov, M. N. (2019). The Reaction of Re3Br9 with P(CH2OH)3: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 45(8), 548-554. https://doi.org/10.1134/S1070328419080013

Vancouver

Anyushin AV, Abramov PA, Sokolov MN. The Reaction of Re3Br9 with P(CH2OH)3: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 Aug 1;45(8):548-554. doi: 10.1134/S1070328419080013

Author

Anyushin, A. V. ; Abramov, P. A. ; Sokolov, M. N. / The Reaction of Re3Br9 with P(CH2OH)3 : Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2019 ; Vol. 45, No. 8. pp. 548-554.

BibTeX

@article{85a64b28052240d884aba04cee26c93e,
title = "The Reaction of Re3Br9 with P(CH2OH)3: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters",
abstract = "Abstract: The reaction of Re3Br9 with P(CH2OH)3 (THP) in methanol under inert atmosphere gives a new cluster complex, [Re3(µ2‑Br)3Br3(µ3-P,O,O-P(CH2OH)(CH2O)2)2H] ∙ 0.8H2O · 1.6MeOH (I). With access of air, the reaction produces a different product, [{Re3(µ2-Br)3Br2(OCH2)2PCH2-OP(CH2OH)2}2-{(P(CH2OH)(CH2O)2)}2] (II), in which two triangular clusters are linked by deprotonated THP molecules as bridging ligands. In addition, each cluster is coordinated in a tetradentate fashion by the phosphine-phosphinite ligand, resulting from the oxidative condensation of two THP molecules (CIF files CCDC 1829565 (I) and 1829566 (II)).",
keywords = "clusters, crystal structure, hydrophilic ligands, phosphine complexes, rhenium, HYDROGENATION, CRYSTAL-STRUCTURE, COMPLEXES, ISOMERIZATION, TRIS(HYDROXYMETHYL)PHOSPHINE, CATALYTIC CYCLOOLIGOMERIZATION, SUBSTITUTION-REACTIONS, AQUEOUS SPECIATION, KINETICS, LIGAND",
author = "Anyushin, {A. V.} and Abramov, {P. A.} and Sokolov, {M. N.}",
year = "2019",
month = aug,
day = "1",
doi = "10.1134/S1070328419080013",
language = "English",
volume = "45",
pages = "548--554",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "8",

}

RIS

TY - JOUR

T1 - The Reaction of Re3Br9 with P(CH2OH)3

T2 - Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters

AU - Anyushin, A. V.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - Abstract: The reaction of Re3Br9 with P(CH2OH)3 (THP) in methanol under inert atmosphere gives a new cluster complex, [Re3(µ2‑Br)3Br3(µ3-P,O,O-P(CH2OH)(CH2O)2)2H] ∙ 0.8H2O · 1.6MeOH (I). With access of air, the reaction produces a different product, [{Re3(µ2-Br)3Br2(OCH2)2PCH2-OP(CH2OH)2}2-{(P(CH2OH)(CH2O)2)}2] (II), in which two triangular clusters are linked by deprotonated THP molecules as bridging ligands. In addition, each cluster is coordinated in a tetradentate fashion by the phosphine-phosphinite ligand, resulting from the oxidative condensation of two THP molecules (CIF files CCDC 1829565 (I) and 1829566 (II)).

AB - Abstract: The reaction of Re3Br9 with P(CH2OH)3 (THP) in methanol under inert atmosphere gives a new cluster complex, [Re3(µ2‑Br)3Br3(µ3-P,O,O-P(CH2OH)(CH2O)2)2H] ∙ 0.8H2O · 1.6MeOH (I). With access of air, the reaction produces a different product, [{Re3(µ2-Br)3Br2(OCH2)2PCH2-OP(CH2OH)2}2-{(P(CH2OH)(CH2O)2)}2] (II), in which two triangular clusters are linked by deprotonated THP molecules as bridging ligands. In addition, each cluster is coordinated in a tetradentate fashion by the phosphine-phosphinite ligand, resulting from the oxidative condensation of two THP molecules (CIF files CCDC 1829565 (I) and 1829566 (II)).

KW - clusters

KW - crystal structure

KW - hydrophilic ligands

KW - phosphine complexes

KW - rhenium

KW - HYDROGENATION

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - ISOMERIZATION

KW - TRIS(HYDROXYMETHYL)PHOSPHINE

KW - CATALYTIC CYCLOOLIGOMERIZATION

KW - SUBSTITUTION-REACTIONS

KW - AQUEOUS SPECIATION

KW - KINETICS

KW - LIGAND

UR - http://www.scopus.com/inward/record.url?scp=85070477129&partnerID=8YFLogxK

U2 - 10.1134/S1070328419080013

DO - 10.1134/S1070328419080013

M3 - Article

AN - SCOPUS:85070477129

VL - 45

SP - 548

EP - 554

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 8

ER -

ID: 21237706