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The origin of self-sustained reaction-rate oscillations in the oxidation of methane over nickel : An operando XRD and mass spectrometry study. / Saraev, A. A.; Vinokurov, Z. S.; Kaichev, V. V. et al.

In: Catalysis Science and Technology, Vol. 7, No. 8, 21.04.2017, p. 1646-1649.

Research output: Contribution to journal › Article › peer-review

Harvard

Saraev, AA, Vinokurov, ZS, Kaichev, VV, Shmakov, AN & Bukhtiyarov, VI 2017, 'The origin of self-sustained reaction-rate oscillations in the oxidation of methane over nickel: An operando XRD and mass spectrometry study', Catalysis Science and Technology, vol. 7, no. 8, pp. 1646-1649. https://doi.org/10.1039/c6cy02673g

APA

Saraev, A. A., Vinokurov, Z. S., Kaichev, V. V., Shmakov, A. N., & Bukhtiyarov, V. I. (2017). The origin of self-sustained reaction-rate oscillations in the oxidation of methane over nickel: An operando XRD and mass spectrometry study. Catalysis Science and Technology, 7(8), 1646-1649. https://doi.org/10.1039/c6cy02673g

Vancouver

Saraev AA, Vinokurov ZS, Kaichev VV, Shmakov AN, Bukhtiyarov VI. The origin of self-sustained reaction-rate oscillations in the oxidation of methane over nickel: An operando XRD and mass spectrometry study. Catalysis Science and Technology. 2017 Apr 21;7(8):1646-1649. doi: 10.1039/c6cy02673g

Author

Saraev, A. A. ; Vinokurov, Z. S. ; Kaichev, V. V. et al. / The origin of self-sustained reaction-rate oscillations in the oxidation of methane over nickel : An operando XRD and mass spectrometry study. In: Catalysis Science and Technology. 2017 ; Vol. 7, No. 8. pp. 1646-1649.

BibTeX

@article{e3b71f61554c4dfa84c7e94c12432d04,
title = "The origin of self-sustained reaction-rate oscillations in the oxidation of methane over nickel: An operando XRD and mass spectrometry study",
abstract = "The self-sustained kinetic oscillations in the catalytic oxidation of methane over Ni foil have been studied at atmospheric pressure using an X-ray diffraction technique and mass spectrometry. It has been shown that the regular reaction-rate oscillations appear under oxygen-deficient conditions and the period of oscillations varies between approximately 200 and 4000 s. The operando measurements have revealed a higher activity of metallic Ni in the reaction than NiO oxide and have unambiguously showed that the oscillations arise due to the reversible bulk oxidation of Ni to NiO.",
keywords = "CATALYTIC-OXIDATION, BEHAVIOR, PROPANE",
author = "Saraev, {A. A.} and Vinokurov, {Z. S.} and Kaichev, {V. V.} and Shmakov, {A. N.} and Bukhtiyarov, {V. I.}",
year = "2017",
month = apr,
day = "21",
doi = "10.1039/c6cy02673g",
language = "English",
volume = "7",
pages = "1646--1649",
journal = "Catalysis Science and Technology",
issn = "2044-4753",
publisher = "Royal Society of Chemistry",
number = "8",

}

RIS

TY - JOUR

T1 - The origin of self-sustained reaction-rate oscillations in the oxidation of methane over nickel

T2 - An operando XRD and mass spectrometry study

AU - Saraev, A. A.

AU - Vinokurov, Z. S.

AU - Kaichev, V. V.

AU - Shmakov, A. N.

AU - Bukhtiyarov, V. I.

PY - 2017/4/21

Y1 - 2017/4/21

N2 - The self-sustained kinetic oscillations in the catalytic oxidation of methane over Ni foil have been studied at atmospheric pressure using an X-ray diffraction technique and mass spectrometry. It has been shown that the regular reaction-rate oscillations appear under oxygen-deficient conditions and the period of oscillations varies between approximately 200 and 4000 s. The operando measurements have revealed a higher activity of metallic Ni in the reaction than NiO oxide and have unambiguously showed that the oscillations arise due to the reversible bulk oxidation of Ni to NiO.

AB - The self-sustained kinetic oscillations in the catalytic oxidation of methane over Ni foil have been studied at atmospheric pressure using an X-ray diffraction technique and mass spectrometry. It has been shown that the regular reaction-rate oscillations appear under oxygen-deficient conditions and the period of oscillations varies between approximately 200 and 4000 s. The operando measurements have revealed a higher activity of metallic Ni in the reaction than NiO oxide and have unambiguously showed that the oscillations arise due to the reversible bulk oxidation of Ni to NiO.

KW - CATALYTIC-OXIDATION

KW - BEHAVIOR

KW - PROPANE

UR - http://www.scopus.com/inward/record.url?scp=85022098636&partnerID=8YFLogxK

U2 - 10.1039/c6cy02673g

DO - 10.1039/c6cy02673g

M3 - Article

AN - SCOPUS:85022098636

VL - 7

SP - 1646

EP - 1649

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

SN - 2044-4753

IS - 8

ER -

ID: 10093984