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The Ni–Ni2P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks. / Litasov, Konstantin D.; Shatskiy, Anton F.; Minin, Daniil A. et al.

In: High Pressure Research, Vol. 39, No. 4, 02.10.2019, p. 561-578.

Research output: Contribution to journal › Article › peer-review

Harvard

Litasov, KD, Shatskiy, AF, Minin, DA, Kuper, KE & Ohfuji, H 2019, 'The Ni–Ni2P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks', High Pressure Research, vol. 39, no. 4, pp. 561-578. https://doi.org/10.1080/08957959.2019.1672677

APA

Litasov, K. D., Shatskiy, A. F., Minin, D. A., Kuper, K. E., & Ohfuji, H. (2019). The Ni–Ni2P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks. High Pressure Research, 39(4), 561-578. https://doi.org/10.1080/08957959.2019.1672677

Vancouver

Litasov KD, Shatskiy AF, Minin DA, Kuper KE, Ohfuji H. The Ni–Ni2P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks. High Pressure Research. 2019 Oct 2;39(4):561-578. doi: 10.1080/08957959.2019.1672677

Author

Litasov, Konstantin D. ; Shatskiy, Anton F. ; Minin, Daniil A. et al. / The Ni–Ni2P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks. In: High Pressure Research. 2019 ; Vol. 39, No. 4. pp. 561-578.

BibTeX

@article{2d65bf55318543fcb1ab08d9161e72e8,
title = "The Ni–Ni2P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks",
abstract = "We present experimental results on melting and subsolidus phase relations in the Ni–Ni2P system at 6 GPa and 900–1600°C. The system has four stable phosphides: Ni3P nickelphosphide, Ni8P3/Ni5P2, Ni12P5 and Ni2P transjordanite. The Ni12P5 phase becomes unstable at 900°C and decomposes into Ni5P2 and Ni2P. The eutectic Ni–Ni3P locates at 950°C and 20 mol% P. Ni3P melts incongruently at 1075°C to Ni5P2 and liquid containing 23 mol% P. Ni8P3 and Ni5P2 form a homogeneity range with crystal structure close to Ni5P2. The Ni5P2–Ni2P eutectic locates at 1175°C and 29 mol%. Ni2P melts congruently at 1250°C. The quenched products of nickelphosphide liquid correspond to the eutectics composition and can serve as indicators for reconstructing the P–T–X conditions recorded in meteoritic and terrestrial Fe–Ni–P assemblages. The Ni–P stoichiometries, which were not observed in the equilibrium phase diagrams, including Ni4P and Ni5P, remain enigmatic.",
keywords = "high pressure, meteorites, Nickel, nickelphosphide, phase diagram, phosphorus, super-reduced rocks, transjordanite, PHOSPHORUS, THERMODYNAMIC PROPERTIES, CRYSTAL-STRUCTURE, NATIVE IRON, P SYSTEM, PERRYITE, EQUILIBRIA",
author = "Litasov, {Konstantin D.} and Shatskiy, {Anton F.} and Minin, {Daniil A.} and Kuper, {Konstantin E.} and Hiroaki Ohfuji",
note = "Publisher Copyright: {\textcopyright} 2019, {\textcopyright} 2019 Informa UK Limited, trading as Taylor & Francis Group.",
year = "2019",
month = oct,
day = "2",
doi = "10.1080/08957959.2019.1672677",
language = "English",
volume = "39",
pages = "561--578",
journal = "High Pressure Research",
issn = "0895-7959",
publisher = "Taylor and Francis Ltd.",
number = "4",

}

RIS

TY - JOUR

T1 - The Ni–Ni2P phase diagram at 6 GPa with implication to meteorites and super-reduced terrestrial rocks

AU - Litasov, Konstantin D.

AU - Shatskiy, Anton F.

AU - Minin, Daniil A.

AU - Kuper, Konstantin E.

AU - Ohfuji, Hiroaki

N1 - Publisher Copyright: © 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group.

PY - 2019/10/2

Y1 - 2019/10/2

N2 - We present experimental results on melting and subsolidus phase relations in the Ni–Ni2P system at 6 GPa and 900–1600°C. The system has four stable phosphides: Ni3P nickelphosphide, Ni8P3/Ni5P2, Ni12P5 and Ni2P transjordanite. The Ni12P5 phase becomes unstable at 900°C and decomposes into Ni5P2 and Ni2P. The eutectic Ni–Ni3P locates at 950°C and 20 mol% P. Ni3P melts incongruently at 1075°C to Ni5P2 and liquid containing 23 mol% P. Ni8P3 and Ni5P2 form a homogeneity range with crystal structure close to Ni5P2. The Ni5P2–Ni2P eutectic locates at 1175°C and 29 mol%. Ni2P melts congruently at 1250°C. The quenched products of nickelphosphide liquid correspond to the eutectics composition and can serve as indicators for reconstructing the P–T–X conditions recorded in meteoritic and terrestrial Fe–Ni–P assemblages. The Ni–P stoichiometries, which were not observed in the equilibrium phase diagrams, including Ni4P and Ni5P, remain enigmatic.

AB - We present experimental results on melting and subsolidus phase relations in the Ni–Ni2P system at 6 GPa and 900–1600°C. The system has four stable phosphides: Ni3P nickelphosphide, Ni8P3/Ni5P2, Ni12P5 and Ni2P transjordanite. The Ni12P5 phase becomes unstable at 900°C and decomposes into Ni5P2 and Ni2P. The eutectic Ni–Ni3P locates at 950°C and 20 mol% P. Ni3P melts incongruently at 1075°C to Ni5P2 and liquid containing 23 mol% P. Ni8P3 and Ni5P2 form a homogeneity range with crystal structure close to Ni5P2. The Ni5P2–Ni2P eutectic locates at 1175°C and 29 mol%. Ni2P melts congruently at 1250°C. The quenched products of nickelphosphide liquid correspond to the eutectics composition and can serve as indicators for reconstructing the P–T–X conditions recorded in meteoritic and terrestrial Fe–Ni–P assemblages. The Ni–P stoichiometries, which were not observed in the equilibrium phase diagrams, including Ni4P and Ni5P, remain enigmatic.

KW - high pressure

KW - meteorites

KW - Nickel

KW - nickelphosphide

KW - phase diagram

KW - phosphorus

KW - super-reduced rocks

KW - transjordanite

KW - PHOSPHORUS

KW - THERMODYNAMIC PROPERTIES

KW - CRYSTAL-STRUCTURE

KW - NATIVE IRON

KW - P SYSTEM

KW - PERRYITE

KW - EQUILIBRIA

UR - http://www.scopus.com/inward/record.url?scp=85074048814&partnerID=8YFLogxK

U2 - 10.1080/08957959.2019.1672677

DO - 10.1080/08957959.2019.1672677

M3 - Article

AN - SCOPUS:85074048814

VL - 39

SP - 561

EP - 578

JO - High Pressure Research

JF - High Pressure Research

SN - 0895-7959

IS - 4

ER -

ID: 21997036