Standard

The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol. / Salnikova, Ksenia E.; Matveeva, Valentina G.; Larichev, Yurii V. et al.

In: Catalysis Today, Vol. 329, 01.06.2019, p. 142-148.

Research output: Contribution to journal › Article › peer-review

Harvard

Salnikova, KE, Matveeva, VG, Larichev, YV, Bykov, AV, Demidenko, GN, Shkileva, IP & Sulman, MG 2019, 'The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol', Catalysis Today, vol. 329, pp. 142-148. https://doi.org/10.1016/j.cattod.2018.12.036

APA

Salnikova, K. E., Matveeva, V. G., Larichev, Y. V., Bykov, A. V., Demidenko, G. N., Shkileva, I. P., & Sulman, M. G. (2019). The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol. Catalysis Today, 329, 142-148. https://doi.org/10.1016/j.cattod.2018.12.036

Vancouver

Salnikova KE, Matveeva VG, Larichev YV, Bykov AV, Demidenko GN, Shkileva IP et al. The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol. Catalysis Today. 2019 Jun 1;329:142-148. doi: 10.1016/j.cattod.2018.12.036

Author

Salnikova, Ksenia E. ; Matveeva, Valentina G. ; Larichev, Yurii V. et al. / The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol. In: Catalysis Today. 2019 ; Vol. 329. pp. 142-148.

BibTeX

@article{dabc0c928eb642258c476670043f1857,
title = "The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol",
abstract = "We report the hydrogenation of furfural (FF) to furfuryl alcohol (FA) with Pd-containing catalysts stabilized by hypercrosslinked polystyrene (HPS). FF is one of the major ingredients of biooil produced by biomass pyrolysis, while FA is a source of value-added chemicals, thus, creating an effective path from biomass to important compounds. Different palladium precursors (PdCl2(CH3CN)2, Pd(CH3COO)2) were used for the catalysts synthesis. The nature of the precursor influences the size of palladium nanoparticles. The TEM and SAXS data showed that when using PdCl2(CH3CN)2, a monomodal distribution of particles size with mean diameter 5.4 ± 1.2 nm was observed, whereas for Pd(CH3COO)2, multimodal particle size distribution with the mean particle sizes up to 13.8 ± 5.4 nm was observed. The comparison of the catalytic activities of Pd-containing catalysts indicated that the more disperse sample of palladium showed higher values of FF conversion and selectivity to FA because of small particles.",
keywords = "Furfural, Furfuryl alcohol, Hydrogenation, Hypercrosslinked polystyrene, Palladium catalyst",
author = "Salnikova, {Ksenia E.} and Matveeva, {Valentina G.} and Larichev, {Yurii V.} and Bykov, {Alexey V.} and Demidenko, {Galina N.} and Shkileva, {Irina P.} and Sulman, {Mikhail G.}",
year = "2019",
month = jun,
day = "1",
doi = "10.1016/j.cattod.2018.12.036",
language = "English",
volume = "329",
pages = "142--148",
journal = "Catalysis Today",
issn = "0920-5861",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - The liquid phase catalytic hydrogenation of furfural to furfuryl alcohol

AU - Salnikova, Ksenia E.

AU - Matveeva, Valentina G.

AU - Larichev, Yurii V.

AU - Bykov, Alexey V.

AU - Demidenko, Galina N.

AU - Shkileva, Irina P.

AU - Sulman, Mikhail G.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - We report the hydrogenation of furfural (FF) to furfuryl alcohol (FA) with Pd-containing catalysts stabilized by hypercrosslinked polystyrene (HPS). FF is one of the major ingredients of biooil produced by biomass pyrolysis, while FA is a source of value-added chemicals, thus, creating an effective path from biomass to important compounds. Different palladium precursors (PdCl2(CH3CN)2, Pd(CH3COO)2) were used for the catalysts synthesis. The nature of the precursor influences the size of palladium nanoparticles. The TEM and SAXS data showed that when using PdCl2(CH3CN)2, a monomodal distribution of particles size with mean diameter 5.4 ± 1.2 nm was observed, whereas for Pd(CH3COO)2, multimodal particle size distribution with the mean particle sizes up to 13.8 ± 5.4 nm was observed. The comparison of the catalytic activities of Pd-containing catalysts indicated that the more disperse sample of palladium showed higher values of FF conversion and selectivity to FA because of small particles.

AB - We report the hydrogenation of furfural (FF) to furfuryl alcohol (FA) with Pd-containing catalysts stabilized by hypercrosslinked polystyrene (HPS). FF is one of the major ingredients of biooil produced by biomass pyrolysis, while FA is a source of value-added chemicals, thus, creating an effective path from biomass to important compounds. Different palladium precursors (PdCl2(CH3CN)2, Pd(CH3COO)2) were used for the catalysts synthesis. The nature of the precursor influences the size of palladium nanoparticles. The TEM and SAXS data showed that when using PdCl2(CH3CN)2, a monomodal distribution of particles size with mean diameter 5.4 ± 1.2 nm was observed, whereas for Pd(CH3COO)2, multimodal particle size distribution with the mean particle sizes up to 13.8 ± 5.4 nm was observed. The comparison of the catalytic activities of Pd-containing catalysts indicated that the more disperse sample of palladium showed higher values of FF conversion and selectivity to FA because of small particles.

KW - Furfural

KW - Furfuryl alcohol

KW - Hydrogenation

KW - Hypercrosslinked polystyrene

KW - Palladium catalyst

UR - http://www.scopus.com/inward/record.url?scp=85059675979&partnerID=8YFLogxK

U2 - 10.1016/j.cattod.2018.12.036

DO - 10.1016/j.cattod.2018.12.036

M3 - Article

AN - SCOPUS:85059675979

VL - 329

SP - 142

EP - 148

JO - Catalysis Today

JF - Catalysis Today

SN - 0920-5861

ER -

ID: 18068234