TY - JOUR

T1 - The Influence of Cu and Al Additives on Reduction of Iron(III) Oxide

T2 - In Situ XRD and XANES Study

AU - Bulavchenko, Olga A.

AU - Vinokurov, Zakhar S.

AU - Saraev, Andrey A.

AU - Tsapina, Anna M.

AU - Trigub, Alexander L.

AU - Gerasimov, Evgeny Yu

AU - Gladky, Alexey Yu

AU - Fedorov, Alexander V.

AU - Yakovlev, Vadim A.

AU - Kaichev, Vasily V.

PY - 2019/4/15

Y1 - 2019/4/15

N2 - The reduction of Fe-based nanocomposite catalysts doped with Al and Cu has been studied using in situ X-ray diffraction (XRD), in situ X-ray absorption near-edge structure (XANES), and temperature-programmed reduction (TPR) techniques. The catalysts have been synthesized by melting of iron, aluminum, and copper salts. According to XRD, the catalysts consist mainly of Fe 2 O 3 and Al 2 O 3 phases. Alumina is in an amorphous state, whereas iron oxide forms nanoparticles with the protohematite structure. The Al 3+ cations are partially dissolved in the Fe 2 O 3 lattice. Due to strong alumina-iron oxide interaction, the specific surface area of the catalysts increases significantly. TPR and XANES data indicate that copper forms highly dispersed surface CuO nanoparticles and partially dissolves in iron oxide. It has been shown that the reduction of iron(III) oxide by CO proceeds via two routes: a direct two-stage reduction of iron(III) oxide to metal (Fe 2 O 3 → Fe 3 O 4 → Fe) or an indirect three-stage reduction with the formation of FeO intermediate phases (Fe 2 O 3 → Fe 3 O 4 → FeO → Fe). The introduction of Al into Fe 2 O 3 leads to a decrease in the rate for all reduction steps. In addition, the introduction of Al stabilizes small Fe 3 O 4 particles and prevents further sintering of the iron oxide. The mechanism of stabilization is associated with the formation of Fe 3-x Al x O 4 solid solution. The addition of copper to the Fe-Al catalyst leads to the formation of highly dispersed CuO particles on the catalyst surface and a mixed oxide with a spinel-type crystalline structure similar to that of CuFe 2 O 4 . The low-temperature reduction of Cu 2+ to Cu 0 accelerates the Fe 2 O 3 → Fe 3 O 4 and FeO → Fe transformations but does not affect the Fe 3 O 4 → FeO/Fe stages. These changes in the reduction properties significantly affect the catalytic performance of the Fe-based nanocomposite catalysts in the low-temperature oxidation of CO.

AB - The reduction of Fe-based nanocomposite catalysts doped with Al and Cu has been studied using in situ X-ray diffraction (XRD), in situ X-ray absorption near-edge structure (XANES), and temperature-programmed reduction (TPR) techniques. The catalysts have been synthesized by melting of iron, aluminum, and copper salts. According to XRD, the catalysts consist mainly of Fe 2 O 3 and Al 2 O 3 phases. Alumina is in an amorphous state, whereas iron oxide forms nanoparticles with the protohematite structure. The Al 3+ cations are partially dissolved in the Fe 2 O 3 lattice. Due to strong alumina-iron oxide interaction, the specific surface area of the catalysts increases significantly. TPR and XANES data indicate that copper forms highly dispersed surface CuO nanoparticles and partially dissolves in iron oxide. It has been shown that the reduction of iron(III) oxide by CO proceeds via two routes: a direct two-stage reduction of iron(III) oxide to metal (Fe 2 O 3 → Fe 3 O 4 → Fe) or an indirect three-stage reduction with the formation of FeO intermediate phases (Fe 2 O 3 → Fe 3 O 4 → FeO → Fe). The introduction of Al into Fe 2 O 3 leads to a decrease in the rate for all reduction steps. In addition, the introduction of Al stabilizes small Fe 3 O 4 particles and prevents further sintering of the iron oxide. The mechanism of stabilization is associated with the formation of Fe 3-x Al x O 4 solid solution. The addition of copper to the Fe-Al catalyst leads to the formation of highly dispersed CuO particles on the catalyst surface and a mixed oxide with a spinel-type crystalline structure similar to that of CuFe 2 O 4 . The low-temperature reduction of Cu 2+ to Cu 0 accelerates the Fe 2 O 3 → Fe 3 O 4 and FeO → Fe transformations but does not affect the Fe 3 O 4 → FeO/Fe stages. These changes in the reduction properties significantly affect the catalytic performance of the Fe-based nanocomposite catalysts in the low-temperature oxidation of CO.

UR - http://www.scopus.com/inward/record.url?scp=85064389525&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.8b03403

DO - 10.1021/acs.inorgchem.8b03403

M3 - Article

C2 - 30946575

AN - SCOPUS:85064350984

VL - 58

SP - 4842

EP - 4850

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 8

ER -