The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand

Original language	English
Pages (from-to)	1278-1290
Number of pages	13
Journal	Chemistry - A European Journal
Volume	23
Issue number	6
DOIs	https://doi.org/10.1002/chem.201604340
Publication status	Published - 26 Jan 2017

lanthanides, magnetism, quantum chemical calculations, radicals, sulfur diimide, COORDINATION CHEMISTRY, DECAMETHYLYTTERBOCENE COMPLEXES, Z,Z CONFIGURATION, CRYSTAL-STRUCTURE, STRUCTURAL-CHARACTERIZATION, SINGLE-MOLECULE MAGNETS, TRANSITION-METAL, INTERMEDIATE-VALENCE, HETEROCYCLIC RADICAL-ANION, EXCHANGE INTERACTION

ID: 9052625

The First Lanthanide Complexes with a Redox-Active Sulfur Diimide Ligand: Synthesis and Characterization of [LnCp*2(RN=)2S], Ln=Sm, Eu, Yb; R=SiMe3