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The features of acetylene pyrolysis in an atmosphere of inert gases in a cyclic compression reactor. / Васильев, Сергей Александрович; Ездин, Борис Семенович; Яньшоле , Л.В. et al.

In: Technical Physics Letters, Vol. 49, No. 2, 2023, p. 65-68.

Research output: Contribution to journal › Article › peer-review

Harvard

Васильев, СА, Ездин, БС, Яньшоле , ЛВ, Пахаруков, ЮВ, Каляда, ВВ & Шабиев, ФК 2023, 'The features of acetylene pyrolysis in an atmosphere of inert gases in a cyclic compression reactor', Technical Physics Letters, vol. 49, no. 2, pp. 65-68. https://doi.org/10.21883/TPL.2023.02.55375.19436

APA

Васильев, С. А., Ездин, Б. С., Яньшоле , Л. В., Пахаруков, Ю. В., Каляда, В. В., & Шабиев, Ф. К. (2023). The features of acetylene pyrolysis in an atmosphere of inert gases in a cyclic compression reactor. Technical Physics Letters, 49(2), 65-68. https://doi.org/10.21883/TPL.2023.02.55375.19436

Vancouver

Васильев СА, Ездин БС, Яньшоле ЛВ, Пахаруков ЮВ, Каляда ВВ, Шабиев ФК. The features of acetylene pyrolysis in an atmosphere of inert gases in a cyclic compression reactor. Technical Physics Letters. 2023;49(2):65-68. doi: 10.21883/TPL.2023.02.55375.19436

Author

Васильев, Сергей Александрович ; Ездин, Борис Семенович ; Яньшоле , Л.В. et al. / The features of acetylene pyrolysis in an atmosphere of inert gases in a cyclic compression reactor. In: Technical Physics Letters. 2023 ; Vol. 49, No. 2. pp. 65-68.

BibTeX

@article{b2cf93cec0bc40e29003bc933de566dd,
title = "The features of acetylene pyrolysis in an atmosphere of inert gases in a cyclic compression reactor",
abstract = "The pyrolysis of acetylene was studied experimentally in a cyclic compression reactor in an atmosphere of buffer inert gases (argon, neon, helium). A significant difference in the thermodynamic conditions for the complete pyrolysis of the precursor for various buffer gases was revealed. The reaction products of acetylene in neon and helium contained up to 20% of the part soluble in organic solvents. The study of the ethanol-soluble part of the product using time-of-flight mass spectrometry with matrix-assisted laser desorption/ionization made it possible to distinguish even and odd branches in the spectrum of substances by the number of carbon atoms. A mechanism is proposed for the formation of larger particles by merging smaller ones. Keywords: cyclic compression reactor, acetylene pyrolysis, buffer inert gas, growth mechanism, carbon nanoparticles.",
author = "Васильев, {Сергей Александрович} and Ездин, {Борис Семенович} and Л.В. Яньшоле and Пахаруков, {Юрий Вавилович} and Каляда, {Валерий Владимирович} and Ф.К. Шабиев",
note = "Experiments on synthesis and examination of the properties of carbon nanomaterials were supported financially by the Ministry of Science and Higher Education of the Russian Federation (project 075-15-2020-797 (13.1902.21.0024)).",
year = "2023",
doi = "10.21883/TPL.2023.02.55375.19436",
language = "English",
volume = "49",
pages = "65--68",
journal = "Technical Physics Letters",
issn = "1063-7850",
publisher = "PLEIADES PUBLISHING INC",
number = "2",

}

RIS

TY - JOUR

T1 - The features of acetylene pyrolysis in an atmosphere of inert gases in a cyclic compression reactor

AU - Васильев, Сергей Александрович

AU - Ездин, Борис Семенович

AU - Яньшоле , Л.В.

AU - Пахаруков, Юрий Вавилович

AU - Каляда, Валерий Владимирович

AU - Шабиев, Ф.К.

N1 - Experiments on synthesis and examination of the properties of carbon nanomaterials were supported financially by the Ministry of Science and Higher Education of the Russian Federation (project 075-15-2020-797 (13.1902.21.0024)).

PY - 2023

Y1 - 2023

N2 - The pyrolysis of acetylene was studied experimentally in a cyclic compression reactor in an atmosphere of buffer inert gases (argon, neon, helium). A significant difference in the thermodynamic conditions for the complete pyrolysis of the precursor for various buffer gases was revealed. The reaction products of acetylene in neon and helium contained up to 20% of the part soluble in organic solvents. The study of the ethanol-soluble part of the product using time-of-flight mass spectrometry with matrix-assisted laser desorption/ionization made it possible to distinguish even and odd branches in the spectrum of substances by the number of carbon atoms. A mechanism is proposed for the formation of larger particles by merging smaller ones. Keywords: cyclic compression reactor, acetylene pyrolysis, buffer inert gas, growth mechanism, carbon nanoparticles.

AB - The pyrolysis of acetylene was studied experimentally in a cyclic compression reactor in an atmosphere of buffer inert gases (argon, neon, helium). A significant difference in the thermodynamic conditions for the complete pyrolysis of the precursor for various buffer gases was revealed. The reaction products of acetylene in neon and helium contained up to 20% of the part soluble in organic solvents. The study of the ethanol-soluble part of the product using time-of-flight mass spectrometry with matrix-assisted laser desorption/ionization made it possible to distinguish even and odd branches in the spectrum of substances by the number of carbon atoms. A mechanism is proposed for the formation of larger particles by merging smaller ones. Keywords: cyclic compression reactor, acetylene pyrolysis, buffer inert gas, growth mechanism, carbon nanoparticles.

UR - https://www.mendeley.com/catalogue/f1f3b690-e8aa-33e7-96a4-e57e9a005903/

U2 - 10.21883/TPL.2023.02.55375.19436

DO - 10.21883/TPL.2023.02.55375.19436

M3 - Article

VL - 49

SP - 65

EP - 68

JO - Technical Physics Letters

JF - Technical Physics Letters

SN - 1063-7850

IS - 2

ER -

ID: 59415822