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The effect of the oxophilic Tb(III) cation on C–ON bond homolysis in alkoxyamines. / Audran, Gérard; Bagryanskaya, Elena G.; Bagryanskaya, Irina Yu et al.

In: Inorganic Chemistry Communications, Vol. 91, 01.05.2018, p. 5-7.

Research output: Contribution to journal › Article › peer-review

Harvard

Audran, G, Bagryanskaya, EG, Bagryanskaya, IY, Edeleva, M, Kaletina, P, Marque, SRA, Parkhomenko, D, Tretyakov, EV & Zhivetyeva, SI 2018, 'The effect of the oxophilic Tb(III) cation on C–ON bond homolysis in alkoxyamines', Inorganic Chemistry Communications, vol. 91, pp. 5-7. https://doi.org/10.1016/j.inoche.2018.02.019

APA

Audran, G., Bagryanskaya, E. G., Bagryanskaya, I. Y., Edeleva, M., Kaletina, P., Marque, S. R. A., Parkhomenko, D., Tretyakov, E. V., & Zhivetyeva, S. I. (2018). The effect of the oxophilic Tb(III) cation on C–ON bond homolysis in alkoxyamines. Inorganic Chemistry Communications, 91, 5-7. https://doi.org/10.1016/j.inoche.2018.02.019

Vancouver

Audran G, Bagryanskaya EG, Bagryanskaya IY, Edeleva M, Kaletina P, Marque SRA et al. The effect of the oxophilic Tb(III) cation on C–ON bond homolysis in alkoxyamines. Inorganic Chemistry Communications. 2018 May 1;91:5-7. doi: 10.1016/j.inoche.2018.02.019

Author

Audran, Gérard ; Bagryanskaya, Elena G. ; Bagryanskaya, Irina Yu et al. / The effect of the oxophilic Tb(III) cation on C–ON bond homolysis in alkoxyamines. In: Inorganic Chemistry Communications. 2018 ; Vol. 91. pp. 5-7.

BibTeX

@article{db59172d7ffd4b69899996a5805b4a0e,
title = "The effect of the oxophilic Tb(III) cation on C–ON bond homolysis in alkoxyamines",
abstract = "Recently, we reported on the activation of the C–ON bond homolysis in alkoxyamines R1R2NOR3 using the coordination of the alkyl fragment R3 with metal cations Cu(II) and Zn(II). Here, we report the selective coordination of the diethylphosphoryl group carried by the nitroxyl fragment by the oxophilic metal cation Tb(III). Coordination on the nitroxyl fragment afford a slight 2-fold decrease in the C–ON bond homolysis rate constant kd.",
keywords = "Alkoxyamine-Tb(III) complex, Diethylphosphoryl group-Tb coordination, Homolysis of alkoxyamines, Safe radical polymerization initiator, NITROXIDE MEDIATED POLYMERIZATION, Dlethylphosphoryl group-Tb coordination",
author = "G{\'e}rard Audran and Bagryanskaya, {Elena G.} and Bagryanskaya, {Irina Yu} and Mariya Edeleva and Polina Kaletina and Marque, {Sylvain R.A.} and Dmitriy Parkhomenko and Tretyakov, {Evgeny V.} and Zhivetyeva, {Svetlana I.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = may,
day = "1",
doi = "10.1016/j.inoche.2018.02.019",
language = "English",
volume = "91",
pages = "5--7",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - The effect of the oxophilic Tb(III) cation on C–ON bond homolysis in alkoxyamines

AU - Audran, Gérard

AU - Bagryanskaya, Elena G.

AU - Bagryanskaya, Irina Yu

AU - Edeleva, Mariya

AU - Kaletina, Polina

AU - Marque, Sylvain R.A.

AU - Parkhomenko, Dmitriy

AU - Tretyakov, Evgeny V.

AU - Zhivetyeva, Svetlana I.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - Recently, we reported on the activation of the C–ON bond homolysis in alkoxyamines R1R2NOR3 using the coordination of the alkyl fragment R3 with metal cations Cu(II) and Zn(II). Here, we report the selective coordination of the diethylphosphoryl group carried by the nitroxyl fragment by the oxophilic metal cation Tb(III). Coordination on the nitroxyl fragment afford a slight 2-fold decrease in the C–ON bond homolysis rate constant kd.

AB - Recently, we reported on the activation of the C–ON bond homolysis in alkoxyamines R1R2NOR3 using the coordination of the alkyl fragment R3 with metal cations Cu(II) and Zn(II). Here, we report the selective coordination of the diethylphosphoryl group carried by the nitroxyl fragment by the oxophilic metal cation Tb(III). Coordination on the nitroxyl fragment afford a slight 2-fold decrease in the C–ON bond homolysis rate constant kd.

KW - Alkoxyamine-Tb(III) complex

KW - Diethylphosphoryl group-Tb coordination

KW - Homolysis of alkoxyamines

KW - Safe radical polymerization initiator

KW - NITROXIDE MEDIATED POLYMERIZATION

KW - Dlethylphosphoryl group-Tb coordination

UR - http://www.scopus.com/inward/record.url?scp=85042850285&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2018.02.019

DO - 10.1016/j.inoche.2018.02.019

M3 - Article

AN - SCOPUS:85042850285

VL - 91

SP - 5

EP - 7

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 10420667