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The approach to 4d/4f-polyphosphides. / Arleth, Nicholas; Gamer, Michael T.; Köppe, Ralf et al.

In: Chemical Science, Vol. 6, No. 12, 29.09.2015, p. 7179-7184.

Research output: Contribution to journal › Article › peer-review

Harvard

Arleth, N, Gamer, MT, Köppe, R, Pushkarevsky, NA, Konchenko, SN, Fleischmann, M, Bodensteiner, M, Scheer, M & Roesky, PW 2015, 'The approach to 4d/4f-polyphosphides', Chemical Science, vol. 6, no. 12, pp. 7179-7184. https://doi.org/10.1039/c5sc02252e

APA

Arleth, N., Gamer, M. T., Köppe, R., Pushkarevsky, N. A., Konchenko, S. N., Fleischmann, M., Bodensteiner, M., Scheer, M., & Roesky, P. W. (2015). The approach to 4d/4f-polyphosphides. Chemical Science, 6(12), 7179-7184. https://doi.org/10.1039/c5sc02252e

Vancouver

Arleth N, Gamer MT, Köppe R, Pushkarevsky NA, Konchenko SN, Fleischmann M et al. The approach to 4d/4f-polyphosphides. Chemical Science. 2015 Sept 29;6(12):7179-7184. doi: 10.1039/c5sc02252e

Author

Arleth, Nicholas ; Gamer, Michael T. ; Köppe, Ralf et al. / The approach to 4d/4f-polyphosphides. In: Chemical Science. 2015 ; Vol. 6, No. 12. pp. 7179-7184.

BibTeX

@article{817fcab0ab2a46ce8161fbb1b587ab91,
title = "The approach to 4d/4f-polyphosphides",
abstract = "The first 4d/4f polyphosphides were obtained by reaction of the divalent metallocenes [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] or [Cp∗Mo(CO)2(η3-P3)]. Treatment of [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] gave the 16-membered bicyclic compounds [(Cp2∗Ln)2P2(CpMo(CO)2)4] (Ln = Sm, Yb) as the major products. From the reaction involving samarocene, the cyclic P4 complex [(Cp∗2Sm)2P4(CpMo(CO)2)2] and the cyclic P5 complex [(Cp∗2Sm)3P5(CpMo(CO)2)3] were also obtained as minor products. In each reaction, the P2 unit is reduced and a rearrangement occurred. In dedicated cases, a P-P bond formation takes place, which results in a new aggregation of the central phosphorus scaffold. In the reactions of [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [Cp∗Mo(CO)2P3] a new P-P bond is formed by reductive dimerization and the 4d/4f hexaphosphides [(Cp∗2Ln)2P6(Cp∗Mo(CO)2)2] (Ln = Sm, Yb) were obtained.",
author = "Nicholas Arleth and Gamer, {Michael T.} and Ralf K{\"o}ppe and Pushkarevsky, {Nikolay A.} and Konchenko, {Sergey N.} and Martin Fleischmann and Michael Bodensteiner and Manfred Scheer and Roesky, {Peter W.}",
year = "2015",
month = sep,
day = "29",
doi = "10.1039/c5sc02252e",
language = "English",
volume = "6",
pages = "7179--7184",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "12",

}

RIS

TY - JOUR

T1 - The approach to 4d/4f-polyphosphides

AU - Arleth, Nicholas

AU - Gamer, Michael T.

AU - Köppe, Ralf

AU - Pushkarevsky, Nikolay A.

AU - Konchenko, Sergey N.

AU - Fleischmann, Martin

AU - Bodensteiner, Michael

AU - Scheer, Manfred

AU - Roesky, Peter W.

PY - 2015/9/29

Y1 - 2015/9/29

N2 - The first 4d/4f polyphosphides were obtained by reaction of the divalent metallocenes [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] or [Cp∗Mo(CO)2(η3-P3)]. Treatment of [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] gave the 16-membered bicyclic compounds [(Cp2∗Ln)2P2(CpMo(CO)2)4] (Ln = Sm, Yb) as the major products. From the reaction involving samarocene, the cyclic P4 complex [(Cp∗2Sm)2P4(CpMo(CO)2)2] and the cyclic P5 complex [(Cp∗2Sm)3P5(CpMo(CO)2)3] were also obtained as minor products. In each reaction, the P2 unit is reduced and a rearrangement occurred. In dedicated cases, a P-P bond formation takes place, which results in a new aggregation of the central phosphorus scaffold. In the reactions of [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [Cp∗Mo(CO)2P3] a new P-P bond is formed by reductive dimerization and the 4d/4f hexaphosphides [(Cp∗2Ln)2P6(Cp∗Mo(CO)2)2] (Ln = Sm, Yb) were obtained.

AB - The first 4d/4f polyphosphides were obtained by reaction of the divalent metallocenes [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] or [Cp∗Mo(CO)2(η3-P3)]. Treatment of [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [{CpMo(CO)2}2(μ,η2:2-P2)] gave the 16-membered bicyclic compounds [(Cp2∗Ln)2P2(CpMo(CO)2)4] (Ln = Sm, Yb) as the major products. From the reaction involving samarocene, the cyclic P4 complex [(Cp∗2Sm)2P4(CpMo(CO)2)2] and the cyclic P5 complex [(Cp∗2Sm)3P5(CpMo(CO)2)3] were also obtained as minor products. In each reaction, the P2 unit is reduced and a rearrangement occurred. In dedicated cases, a P-P bond formation takes place, which results in a new aggregation of the central phosphorus scaffold. In the reactions of [Cp∗2Ln(thf)2] (Ln = Sm, Yb) with [Cp∗Mo(CO)2P3] a new P-P bond is formed by reductive dimerization and the 4d/4f hexaphosphides [(Cp∗2Ln)2P6(Cp∗Mo(CO)2)2] (Ln = Sm, Yb) were obtained.

UR - http://www.scopus.com/inward/record.url?scp=84946546726&partnerID=8YFLogxK

U2 - 10.1039/c5sc02252e

DO - 10.1039/c5sc02252e

M3 - Article

AN - SCOPUS:84946546726

VL - 6

SP - 7179

EP - 7184

JO - Chemical Science

JF - Chemical Science

SN - 2041-6520

IS - 12

ER -

ID: 25414830