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Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures. / Chanyshev, Artem D.; Litasov, Konstantin D.; Furukawa, Yoshihiro et al.

In: Scientific Reports, Vol. 7, No. 1, 7889, 11.08.2017, p. 7889.

Research output: Contribution to journal › Article › peer-review

Harvard

Chanyshev, AD, Litasov, KD, Furukawa, Y, Kokh, KA & Shatskiy, AF 2017, 'Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures', Scientific Reports, vol. 7, no. 1, 7889, pp. 7889. https://doi.org/10.1038/s41598-017-08529-2

APA

Chanyshev, A. D., Litasov, K. D., Furukawa, Y., Kokh, K. A., & Shatskiy, A. F. (2017). Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures. Scientific Reports, 7(1), 7889. [7889]. https://doi.org/10.1038/s41598-017-08529-2

Vancouver

Chanyshev AD, Litasov KD, Furukawa Y, Kokh KA, Shatskiy AF. Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures. Scientific Reports. 2017 Aug 11;7(1):7889. 7889. doi: 10.1038/s41598-017-08529-2

Author

Chanyshev, Artem D. ; Litasov, Konstantin D. ; Furukawa, Yoshihiro et al. / Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures. In: Scientific Reports. 2017 ; Vol. 7, No. 1. pp. 7889.

BibTeX

@article{5b1ebbd0bdcf45a0b8da3a9e647484e1,
title = "Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures",
abstract = "Temperature-induced oligomerization of polycyclic aromatic hydrocarbons (PAHs) was found at 500–773 K and ambient and high (3.5 GPa) pressures. The most intensive oligomerization at 1 bar and 3.5 GPa occurs at 740–823 K. PAH carbonization at high pressure is the final stage of oligomerization and occurs as a result of sequential oligomerization and polymerization of the starting material, caused by overlapping of π-orbitals, a decrease of intermolecular distances, and finally the dehydrogenation and polycondensation of benzene rings. Being important for building blocks of life, PAHs and their oligomers can be formed in the interior of the terrestrial planets with radii less than 2270 km.",
keywords = "AMINO-ACIDS, ANTHRACENE, BENZENE, CARBONIZATION, CRYSTAL MESOPHASE DEVELOPMENT, EARLY EARTH, GPA, IMPACT-SHOCK, MURCHISON METEORITE, ORGANIC-MOLECULES",
author = "Chanyshev, {Artem D.} and Litasov, {Konstantin D.} and Yoshihiro Furukawa and Kokh, {Konstantin A.} and Shatskiy, {Anton F.}",
year = "2017",
month = aug,
day = "11",
doi = "10.1038/s41598-017-08529-2",
language = "English",
volume = "7",
pages = "7889",
journal = "Scientific Reports",
issn = "2045-2322",
publisher = "Nature Publishing Group",
number = "1",

}

RIS

TY - JOUR

T1 - Temperature-induced oligomerization of polycyclic aromatic hydrocarbons at ambient and high pressures

AU - Chanyshev, Artem D.

AU - Litasov, Konstantin D.

AU - Furukawa, Yoshihiro

AU - Kokh, Konstantin A.

AU - Shatskiy, Anton F.

PY - 2017/8/11

Y1 - 2017/8/11

N2 - Temperature-induced oligomerization of polycyclic aromatic hydrocarbons (PAHs) was found at 500–773 K and ambient and high (3.5 GPa) pressures. The most intensive oligomerization at 1 bar and 3.5 GPa occurs at 740–823 K. PAH carbonization at high pressure is the final stage of oligomerization and occurs as a result of sequential oligomerization and polymerization of the starting material, caused by overlapping of π-orbitals, a decrease of intermolecular distances, and finally the dehydrogenation and polycondensation of benzene rings. Being important for building blocks of life, PAHs and their oligomers can be formed in the interior of the terrestrial planets with radii less than 2270 km.

AB - Temperature-induced oligomerization of polycyclic aromatic hydrocarbons (PAHs) was found at 500–773 K and ambient and high (3.5 GPa) pressures. The most intensive oligomerization at 1 bar and 3.5 GPa occurs at 740–823 K. PAH carbonization at high pressure is the final stage of oligomerization and occurs as a result of sequential oligomerization and polymerization of the starting material, caused by overlapping of π-orbitals, a decrease of intermolecular distances, and finally the dehydrogenation and polycondensation of benzene rings. Being important for building blocks of life, PAHs and their oligomers can be formed in the interior of the terrestrial planets with radii less than 2270 km.

KW - AMINO-ACIDS

KW - ANTHRACENE

KW - BENZENE

KW - CARBONIZATION

KW - CRYSTAL MESOPHASE DEVELOPMENT

KW - EARLY EARTH

KW - GPA

KW - IMPACT-SHOCK

KW - MURCHISON METEORITE

KW - ORGANIC-MOLECULES

UR - http://www.scopus.com/inward/record.url?scp=85046346432&partnerID=8YFLogxK

U2 - 10.1038/s41598-017-08529-2

DO - 10.1038/s41598-017-08529-2

M3 - Article

C2 - 28801612

AN - SCOPUS:85046346432

VL - 7

SP - 7889

JO - Scientific Reports

JF - Scientific Reports

SN - 2045-2322

IS - 1

M1 - 7889

ER -

ID: 16074606