Standard

Tantalum Dimethyldithiocarbamate Complexes. / Petrov, P. A.; Rogachev, A. V.; Kompan’kov, N. B. et al.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 43, No. 10, 01.10.2017, p. 652-656.

Research output: Contribution to journal › Article › peer-review

Harvard

Petrov, PA, Rogachev, AV, Kompan’kov, NB, Gushchin, AL & Sokolov, MN 2017, 'Tantalum Dimethyldithiocarbamate Complexes', Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 10, pp. 652-656. https://doi.org/10.1134/S1070328417100074

APA

Petrov, P. A., Rogachev, A. V., Kompan’kov, N. B., Gushchin, A. L., & Sokolov, M. N. (2017). Tantalum Dimethyldithiocarbamate Complexes. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 43(10), 652-656. https://doi.org/10.1134/S1070328417100074

Vancouver

Petrov PA, Rogachev AV, Kompan’kov NB, Gushchin AL, Sokolov MN. Tantalum Dimethyldithiocarbamate Complexes. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 Oct 1;43(10):652-656. doi: 10.1134/S1070328417100074

Author

Petrov, P. A. ; Rogachev, A. V. ; Kompan’kov, N. B. et al. / Tantalum Dimethyldithiocarbamate Complexes. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017 ; Vol. 43, No. 10. pp. 652-656.

BibTeX

@article{8e5918cd88c24484ab74ec9f9e6e8cdb,
title = "Tantalum Dimethyldithiocarbamate Complexes",
abstract = "The reaction of Ta(NMe2)5 with CS2 gave the tantalum(V) dimethyldithiocarbamate complex [Ta(MeDtc)4](MeDtc) (I). An ionic structure of the complex with a dodecahedral coordination of the tantalum atom was determined for toluene (I · Tol) and THF (I · THF) solvates by X-ray diffraction (CCDC no. 1544283 and no. 1544284, respectively). The reaction of I with CH2Cl2 leads to exchange of the outersphere anion to give the known complex [Ta(MeDtc)4]Cl (II). The cyclic voltammogram of II in CH3CN exhibits a quasi-reversible transition at E1/2 =–0.735 V corresponding to the TaV/TaIV pair.",
keywords = "amides, cyclic voltammetry, dithiocarbamates, tantalum, X-ray diffraction analysis, NIOBIUM, MOLECULAR-STRUCTURE, CRYSTAL",
author = "Petrov, {P. A.} and Rogachev, {A. V.} and Kompan{\textquoteright}kov, {N. B.} and Gushchin, {A. L.} and Sokolov, {M. N.}",
year = "2017",
month = oct,
day = "1",
doi = "10.1134/S1070328417100074",
language = "English",
volume = "43",
pages = "652--656",
journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",
issn = "1070-3284",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "10",

}

RIS

TY - JOUR

T1 - Tantalum Dimethyldithiocarbamate Complexes

AU - Petrov, P. A.

AU - Rogachev, A. V.

AU - Kompan’kov, N. B.

AU - Gushchin, A. L.

AU - Sokolov, M. N.

PY - 2017/10/1

Y1 - 2017/10/1

N2 - The reaction of Ta(NMe2)5 with CS2 gave the tantalum(V) dimethyldithiocarbamate complex [Ta(MeDtc)4](MeDtc) (I). An ionic structure of the complex with a dodecahedral coordination of the tantalum atom was determined for toluene (I · Tol) and THF (I · THF) solvates by X-ray diffraction (CCDC no. 1544283 and no. 1544284, respectively). The reaction of I with CH2Cl2 leads to exchange of the outersphere anion to give the known complex [Ta(MeDtc)4]Cl (II). The cyclic voltammogram of II in CH3CN exhibits a quasi-reversible transition at E1/2 =–0.735 V corresponding to the TaV/TaIV pair.

AB - The reaction of Ta(NMe2)5 with CS2 gave the tantalum(V) dimethyldithiocarbamate complex [Ta(MeDtc)4](MeDtc) (I). An ionic structure of the complex with a dodecahedral coordination of the tantalum atom was determined for toluene (I · Tol) and THF (I · THF) solvates by X-ray diffraction (CCDC no. 1544283 and no. 1544284, respectively). The reaction of I with CH2Cl2 leads to exchange of the outersphere anion to give the known complex [Ta(MeDtc)4]Cl (II). The cyclic voltammogram of II in CH3CN exhibits a quasi-reversible transition at E1/2 =–0.735 V corresponding to the TaV/TaIV pair.

KW - amides

KW - cyclic voltammetry

KW - dithiocarbamates

KW - tantalum

KW - X-ray diffraction analysis

KW - NIOBIUM

KW - MOLECULAR-STRUCTURE

KW - CRYSTAL

UR - http://www.scopus.com/inward/record.url?scp=85032010881&partnerID=8YFLogxK

U2 - 10.1134/S1070328417100074

DO - 10.1134/S1070328417100074

M3 - Article

AN - SCOPUS:85032010881

VL - 43

SP - 652

EP - 656

JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

SN - 1070-3284

IS - 10

ER -

ID: 9875383