Standard

Tailoring Heterometallic Cluster Functional Building Blocks : Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−. / Muravieva, Viktoria K.; Gayfulin, Yakov M.; Prestipino, Carmelo et al.

In: Chemistry - A European Journal, Vol. 25, No. 66, 27.11.2019, p. 15040-15045.

Research output: Contribution to journal › Article › peer-review

Harvard

Muravieva, VK, Gayfulin, YM, Prestipino, C, Lemoine, P, Ryzhikov, MR, Yanshole, VV, Cordier, S & Naumov, NG 2019, 'Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−', Chemistry - A European Journal, vol. 25, no. 66, pp. 15040-15045. https://doi.org/10.1002/chem.201903321

APA

Muravieva, V. K., Gayfulin, Y. M., Prestipino, C., Lemoine, P., Ryzhikov, M. R., Yanshole, V. V., Cordier, S., & Naumov, N. G. (2019). Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−. Chemistry - A European Journal, 25(66), 15040-15045. https://doi.org/10.1002/chem.201903321

Vancouver

Muravieva VK, Gayfulin YM, Prestipino C, Lemoine P, Ryzhikov MR, Yanshole VV et al. Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−. Chemistry - A European Journal. 2019 Nov 27;25(66):15040-15045. Epub 2019 Oct 24. doi: 10.1002/chem.201903321

Author

Muravieva, Viktoria K. ; Gayfulin, Yakov M. ; Prestipino, Carmelo et al. / Tailoring Heterometallic Cluster Functional Building Blocks : Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−. In: Chemistry - A European Journal. 2019 ; Vol. 25, No. 66. pp. 15040-15045.

BibTeX

@article{d65e71d5e332484ea424ed919e030afd,
title = "Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−",
abstract = "Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.",
keywords = "cluster compounds, electronic structure, EXAFS, heterometallic complexes, structure, MOLYBDENUM, OCTAHEDRAL CLUSTERS, X-RAY",
author = "Muravieva, {Viktoria K.} and Gayfulin, {Yakov M.} and Carmelo Prestipino and Pierric Lemoine and Ryzhikov, {Maxim R.} and Yanshole, {Vadim V.} and St{\'e}phane Cordier and Naumov, {Nikolay G.}",
note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
month = nov,
day = "27",
doi = "10.1002/chem.201903321",
language = "English",
volume = "25",
pages = "15040--15045",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "66",

}

RIS

TY - JOUR

T1 - Tailoring Heterometallic Cluster Functional Building Blocks

T2 - Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−

AU - Muravieva, Viktoria K.

AU - Gayfulin, Yakov M.

AU - Prestipino, Carmelo

AU - Lemoine, Pierric

AU - Ryzhikov, Maxim R.

AU - Yanshole, Vadim V.

AU - Cordier, Stéphane

AU - Naumov, Nikolay G.

N1 - Publisher Copyright: © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/11/27

Y1 - 2019/11/27

N2 - Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

AB - Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond-length distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS, and DFT calculations.

KW - cluster compounds

KW - electronic structure

KW - EXAFS

KW - heterometallic complexes

KW - structure

KW - MOLYBDENUM

KW - OCTAHEDRAL CLUSTERS

KW - X-RAY

UR - http://www.scopus.com/inward/record.url?scp=85074595795&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/5ce59b57-cf7b-33b6-8caa-721a3f3de4bc/

U2 - 10.1002/chem.201903321

DO - 10.1002/chem.201903321

M3 - Article

C2 - 31468567

AN - SCOPUS:85074595795

VL - 25

SP - 15040

EP - 15045

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 66

ER -

ID: 22320999