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Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions. / Ivanov, A. A.; Shestopalov, M. A.; Brylev, K. A. et al.

In: Russian Chemical Bulletin, Vol. 66, No. 3, 01.03.2017, p. 426-431.

Research output: Contribution to journal › Article › peer-review

Harvard

Ivanov, AA, Shestopalov, MA, Brylev, KA, Vorotnikov, YA, Plyusnin, PE & Mironov, YV 2017, 'Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions', Russian Chemical Bulletin, vol. 66, no. 3, pp. 426-431. https://doi.org/10.1007/s11172-017-1750-7

APA

Ivanov, A. A., Shestopalov, M. A., Brylev, K. A., Vorotnikov, Y. A., Plyusnin, P. E., & Mironov, Y. V. (2017). Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions. Russian Chemical Bulletin, 66(3), 426-431. https://doi.org/10.1007/s11172-017-1750-7

Vancouver

Ivanov AA, Shestopalov MA, Brylev KA, Vorotnikov YA, Plyusnin PE, Mironov YV. Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions. Russian Chemical Bulletin. 2017 Mar 1;66(3):426-431. doi: 10.1007/s11172-017-1750-7

Author

Ivanov, A. A. ; Shestopalov, M. A. ; Brylev, K. A. et al. / Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions. In: Russian Chemical Bulletin. 2017 ; Vol. 66, No. 3. pp. 426-431.

BibTeX

@article{e526f3ed68864ab59e82ab6d08fb155b,
title = "Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions",
abstract = "The compound [{Re6S8}(3,5-Me2pzH)6]2[{Re6S8}Br6]•9H2O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re6S8}(3,5-Me2pzH)6]Br2•2(3,5-Me2pzH) (pzH is pyrazole) with an aqueous solution of Cs4[{Re6S8}Br6]•2H2O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H5O2 +) and solvate water molecules and is described by the formula (H5O2)2[{Re6S8}(3,5-Me2pzH)6][{Re6S8}Br6]•4H2O.",
keywords = "3,5-dimethylpyrazole, crystal structure, luminescence, octahedral chalcogenide cluster complexes, rhenium, Zundel cation, Zundel catio, CRYSTAL-STRUCTURE, ORGANIC-LIGANDS, COMPLEXES, ENCAPSULATION, LUMINESCENCE PROPERTIES, FAMILY, CHALCOGENIDE CLUSTERS, SE, LIGANDS SYNTHESIS, X-RAY",
author = "Ivanov, {A. A.} and Shestopalov, {M. A.} and Brylev, {K. A.} and Vorotnikov, {Yu A.} and Plyusnin, {P. E.} and Mironov, {Yu V.}",
year = "2017",
month = mar,
day = "1",
doi = "10.1007/s11172-017-1750-7",
language = "English",
volume = "66",
pages = "426--431",
journal = "Russian Chemical Bulletin",
issn = "1066-5285",
publisher = "Springer Nature",
number = "3",

}

RIS

TY - JOUR

T1 - Synthesis, structure, and properties of compounds containing both octahedral rhenium cluster cations and anions

AU - Ivanov, A. A.

AU - Shestopalov, M. A.

AU - Brylev, K. A.

AU - Vorotnikov, Yu A.

AU - Plyusnin, P. E.

AU - Mironov, Yu V.

PY - 2017/3/1

Y1 - 2017/3/1

N2 - The compound [{Re6S8}(3,5-Me2pzH)6]2[{Re6S8}Br6]•9H2O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re6S8}(3,5-Me2pzH)6]Br2•2(3,5-Me2pzH) (pzH is pyrazole) with an aqueous solution of Cs4[{Re6S8}Br6]•2H2O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H5O2 +) and solvate water molecules and is described by the formula (H5O2)2[{Re6S8}(3,5-Me2pzH)6][{Re6S8}Br6]•4H2O.

AB - The compound [{Re6S8}(3,5-Me2pzH)6]2[{Re6S8}Br6]•9H2O•4EtOH containing a cluster cation and a cluster anion in a 2: 1 ratio was synthesized by mixing an ethanol solution of the rhenium cluster complex [{Re6S8}(3,5-Me2pzH)6]Br2•2(3,5-Me2pzH) (pzH is pyrazole) with an aqueous solution of Cs4[{Re6S8}Br6]•2H2O. The resulting compound was characterized by a combination of physicochemical methods. In particular, luminescence properties were studied and compared with those of the parent cluster complexes. A crystal suitable for single-crystal X-ray diffraction was obtained by layering these solutions. According to single-crystal X-ray diffraction analysis, this compound is composed of a cluster cation and a cluster anion (in a ratio of 1: 1) and also of Zundel cations (H5O2 +) and solvate water molecules and is described by the formula (H5O2)2[{Re6S8}(3,5-Me2pzH)6][{Re6S8}Br6]•4H2O.

KW - 3,5-dimethylpyrazole

KW - crystal structure

KW - luminescence

KW - octahedral chalcogenide cluster complexes

KW - rhenium

KW - Zundel cation

KW - Zundel catio

KW - CRYSTAL-STRUCTURE

KW - ORGANIC-LIGANDS

KW - COMPLEXES

KW - ENCAPSULATION

KW - LUMINESCENCE PROPERTIES

KW - FAMILY

KW - CHALCOGENIDE CLUSTERS

KW - SE

KW - LIGANDS SYNTHESIS

KW - X-RAY

UR - http://www.scopus.com/inward/record.url?scp=85029147749&partnerID=8YFLogxK

U2 - 10.1007/s11172-017-1750-7

DO - 10.1007/s11172-017-1750-7

M3 - Article

AN - SCOPUS:85029147749

VL - 66

SP - 426

EP - 431

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 3

ER -

ID: 9912763