Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes

Standard

Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes. / Marchenko, Roman D.; Lysova, Anna A.; Samsonenko, Denis G. et al.

In: Polyhedron, Vol. 177, 114330, 01.02.2020.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{5d0457746fab4ec9b365620a54e071fe,

title = "Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes",

abstract = "A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.",

keywords = "Benzotriazole, Cadmium, Coordination polymers, Crystal structure, Silver, POLYMERS, SERIES, COMPLEXES, CRYSTAL-STRUCTURES, COPPER, CHAIN, INHIBITORS, LIGAND",

author = "Marchenko, {Roman D.} and Lysova, {Anna A.} and Samsonenko, {Denis G.} and Dybtsev, {Danil N.} and Potapov, {Andrei S.}",

year = "2020",

month = feb,

day = "1",

doi = "10.1016/j.poly.2019.114330",

language = "English",

volume = "177",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes

AU - Marchenko, Roman D.

AU - Lysova, Anna A.

AU - Samsonenko, Denis G.

AU - Dybtsev, Danil N.

AU - Potapov, Andrei S.

PY - 2020/2/1

Y1 - 2020/2/1

N2 - A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.

AB - A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.

KW - Benzotriazole

KW - Cadmium

KW - Coordination polymers

KW - Crystal structure

KW - Silver

KW - POLYMERS

KW - SERIES

KW - COMPLEXES

KW - CRYSTAL-STRUCTURES

KW - COPPER

KW - CHAIN

KW - INHIBITORS

KW - LIGAND

UR - http://www.scopus.com/inward/record.url?scp=85077316469&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2019.114330

DO - 10.1016/j.poly.2019.114330

M3 - Article

AN - SCOPUS:85077316469

VL - 177

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

M1 - 114330

ER -

ID: 22999152