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Synthesis of samarium oxysulfateSm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties. / Denisenko, Yu G.; Sal'nikova, E. I.; Basova, S. A. et al.

In: Molecules, Vol. 25, No. 6, 1330, 14.03.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Denisenko, YG, Sal'nikova, EI, Basova, SA, Molokeev, MS, Krylov, AS, Aleksandrovsky, AS, Oreshonkov, AS, Atuchin, VV, Volkova, SS, Khritokhin, NA & Andreev, OV 2020, 'Synthesis of samarium oxysulfateSm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties', Molecules, vol. 25, no. 6, 1330. https://doi.org/10.3390/molecules25061330

APA

Denisenko, Y. G., Sal'nikova, E. I., Basova, S. A., Molokeev, M. S., Krylov, A. S., Aleksandrovsky, A. S., Oreshonkov, A. S., Atuchin, V. V., Volkova, S. S., Khritokhin, N. A., & Andreev, O. V. (2020). Synthesis of samarium oxysulfateSm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties. Molecules, 25(6), [1330]. https://doi.org/10.3390/molecules25061330

Vancouver

Denisenko YG, Sal'nikova EI, Basova SA, Molokeev MS, Krylov AS, Aleksandrovsky AS et al. Synthesis of samarium oxysulfateSm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties. Molecules. 2020 Mar 14;25(6):1330. doi: 10.3390/molecules25061330

Author

Denisenko, Yu G. ; Sal'nikova, E. I. ; Basova, S. A. et al. / Synthesis of samarium oxysulfateSm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties. In: Molecules. 2020 ; Vol. 25, No. 6.

BibTeX

@article{a657efcb831c4f41b3ec75719226174a,
title = "Synthesis of samarium oxysulfateSm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties",
abstract = "The oxidation process of samariumoxysulfide was studied in the temperature range of 500-1000 °C. Our DTA investigation allowed for establishing the main thermodynamic (∆Hº exp = -654.6 kJ/mol) and kinetic characteristics of the process (E a = 244 kJ/mol, A = 2 × 10 10). The enthalpy value of samarium oxysulfate (ΔHºf (Sm 2O 2SO 4(monocl)) = -2294.0 kJ/mol) formation was calculated. The calculated process enthalpy value coincides with the value determined in the experiment. It was established that samarium oxysulfate crystallizes in the monoclinic symmetry class and its crystal structure belongs to space group C2/ c with unit cell parameters a = 13.7442 (2), b = 4.20178 (4) and c = 8.16711 (8){\AA}, β = 107.224 (1)°, V = 450.498 (9){\AA} 3, Z = 4. The main elements of the crystalline structure are obtained and the cation coordination environment is analyzed in detail. Vibrational spectroscopy methods confirmed the structural model adequacy. The Sm 2O 2SO 4luminescence spectra exhibit three main bands easily assignable to the transitions from 4G 5/2 state to 6H 5/2, 6H 7/2, and 6H 9/2 multiplets. ",
keywords = "Luminescence, Oxysulfate, Samarium, Structure, Thermochemistry, samarium, LN, PR, SPECTROSCOPIC PROPERTIES, RARE-EARTH SULFATES, DECOMPOSITION, oxysulfate, structure, thermochemistry, OXYGEN-STORAGE, LN(2)O(2)SO(4), luminescence, LA, KINETICS, ND",
author = "Denisenko, {Yu G.} and Sal'nikova, {E. I.} and Basova, {S. A.} and Molokeev, {M. S.} and Krylov, {A. S.} and Aleksandrovsky, {A. S.} and Oreshonkov, {A. S.} and Atuchin, {V. V.} and Volkova, {S. S.} and Khritokhin, {N. A.} and Andreev, {O. V.}",
year = "2020",
month = mar,
day = "14",
doi = "10.3390/molecules25061330",
language = "English",
volume = "25",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "6",

}

RIS

TY - JOUR

T1 - Synthesis of samarium oxysulfateSm2O2SO4 in the high-temperature oxidation reaction and its structural, thermal and luminescent properties

AU - Denisenko, Yu G.

AU - Sal'nikova, E. I.

AU - Basova, S. A.

AU - Molokeev, M. S.

AU - Krylov, A. S.

AU - Aleksandrovsky, A. S.

AU - Oreshonkov, A. S.

AU - Atuchin, V. V.

AU - Volkova, S. S.

AU - Khritokhin, N. A.

AU - Andreev, O. V.

PY - 2020/3/14

Y1 - 2020/3/14

N2 - The oxidation process of samariumoxysulfide was studied in the temperature range of 500-1000 °C. Our DTA investigation allowed for establishing the main thermodynamic (∆Hº exp = -654.6 kJ/mol) and kinetic characteristics of the process (E a = 244 kJ/mol, A = 2 × 10 10). The enthalpy value of samarium oxysulfate (ΔHºf (Sm 2O 2SO 4(monocl)) = -2294.0 kJ/mol) formation was calculated. The calculated process enthalpy value coincides with the value determined in the experiment. It was established that samarium oxysulfate crystallizes in the monoclinic symmetry class and its crystal structure belongs to space group C2/ c with unit cell parameters a = 13.7442 (2), b = 4.20178 (4) and c = 8.16711 (8)Å, β = 107.224 (1)°, V = 450.498 (9)Å 3, Z = 4. The main elements of the crystalline structure are obtained and the cation coordination environment is analyzed in detail. Vibrational spectroscopy methods confirmed the structural model adequacy. The Sm 2O 2SO 4luminescence spectra exhibit three main bands easily assignable to the transitions from 4G 5/2 state to 6H 5/2, 6H 7/2, and 6H 9/2 multiplets.

AB - The oxidation process of samariumoxysulfide was studied in the temperature range of 500-1000 °C. Our DTA investigation allowed for establishing the main thermodynamic (∆Hº exp = -654.6 kJ/mol) and kinetic characteristics of the process (E a = 244 kJ/mol, A = 2 × 10 10). The enthalpy value of samarium oxysulfate (ΔHºf (Sm 2O 2SO 4(monocl)) = -2294.0 kJ/mol) formation was calculated. The calculated process enthalpy value coincides with the value determined in the experiment. It was established that samarium oxysulfate crystallizes in the monoclinic symmetry class and its crystal structure belongs to space group C2/ c with unit cell parameters a = 13.7442 (2), b = 4.20178 (4) and c = 8.16711 (8)Å, β = 107.224 (1)°, V = 450.498 (9)Å 3, Z = 4. The main elements of the crystalline structure are obtained and the cation coordination environment is analyzed in detail. Vibrational spectroscopy methods confirmed the structural model adequacy. The Sm 2O 2SO 4luminescence spectra exhibit three main bands easily assignable to the transitions from 4G 5/2 state to 6H 5/2, 6H 7/2, and 6H 9/2 multiplets.

KW - Luminescence

KW - Oxysulfate

KW - Samarium

KW - Structure

KW - Thermochemistry

KW - samarium

KW - LN

KW - PR

KW - SPECTROSCOPIC PROPERTIES

KW - RARE-EARTH SULFATES

KW - DECOMPOSITION

KW - oxysulfate

KW - structure

KW - thermochemistry

KW - OXYGEN-STORAGE

KW - LN(2)O(2)SO(4)

KW - luminescence

KW - LA

KW - KINETICS

KW - ND

UR - http://www.scopus.com/inward/record.url?scp=85081649606&partnerID=8YFLogxK

U2 - 10.3390/molecules25061330

DO - 10.3390/molecules25061330

M3 - Article

C2 - 32183320

AN - SCOPUS:85081649606

VL - 25

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 6

M1 - 1330

ER -

ID: 23806721