Research output: Contribution to journal › Article › peer-review
Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds. / Pavlov, D. I.; Sukhikh, T. S.; Potapov, A. S.
In: Russian Chemical Bulletin, Vol. 69, No. 10, 01.10.2020, p. 1953-1964.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds
AU - Pavlov, D. I.
AU - Sukhikh, T. S.
AU - Potapov, A. S.
PY - 2020/10/1
Y1 - 2020/10/1
N2 - Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.
AB - Reactions of adamantylazoles with nucleophiles (water, carbon monoxide, acetonitrile) in sulfuric acid were studied. New bifunctional adamantane derivatives containing one heterocyclic substituent and one hydroxyl or acetamide substituent were synthesized. The coordination compounds of copper(II) and zinc(II) with 1-adamantyl-1,2,4-triazole, 4-adamantylpyrazole, and 4-adamantyl-3,5-dimethylpyrazole were synthesized and structurally characterized. These complexes are first examples of coordination compounds of azolyladamantanes.
KW - adamantane
KW - coordination compounds
KW - copper
KW - pyrazole
KW - triazole
KW - X-ray diffraction
KW - zinc
UR - http://www.scopus.com/inward/record.url?scp=85094962271&partnerID=8YFLogxK
U2 - 10.1007/s11172-020-2985-2
DO - 10.1007/s11172-020-2985-2
M3 - Article
AN - SCOPUS:85094962271
VL - 69
SP - 1953
EP - 1964
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 10
ER -
ID: 25861236