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Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped solid solutions (Y1-xREx)4S3(Si2O7). / Tarasenko, Maria S.; Berezin, Alexey S.; Kiryakov, Alexander S. et al.

In: Journal of Solid State Chemistry, Vol. 265, 01.09.2018, p. 36-41.

Research output: Contribution to journal › Article › peer-review

Harvard

Tarasenko, MS, Berezin, AS, Kiryakov, AS, Piryazev, DA, Filatova, IY & Naumov, NG 2018, 'Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped solid solutions (Y1-xREx)4S3(Si2O7)', Journal of Solid State Chemistry, vol. 265, pp. 36-41. https://doi.org/10.1016/j.jssc.2018.05.016

APA

Tarasenko, M. S., Berezin, A. S., Kiryakov, A. S., Piryazev, D. A., Filatova, I. Y., & Naumov, N. G. (2018). Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped solid solutions (Y1-xREx)4S3(Si2O7). Journal of Solid State Chemistry, 265, 36-41. https://doi.org/10.1016/j.jssc.2018.05.016

Vancouver

Tarasenko MS, Berezin AS, Kiryakov AS, Piryazev DA, Filatova IY, Naumov NG. Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped solid solutions (Y1-xREx)4S3(Si2O7). Journal of Solid State Chemistry. 2018 Sept 1;265:36-41. doi: 10.1016/j.jssc.2018.05.016

Author

Tarasenko, Maria S. ; Berezin, Alexey S. ; Kiryakov, Alexander S. et al. / Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped solid solutions (Y1-xREx)4S3(Si2O7). In: Journal of Solid State Chemistry. 2018 ; Vol. 265. pp. 36-41.

BibTeX

@article{44247ac843fd4c0da5fbd708932eafd7,
title = "Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped solid solutions (Y1-xREx)4S3(Si2O7)",
abstract = "Y4S3(Si2O7) and its solid solutions (Y1-xREx)4S3Si2O7 (RE = Eu x = 0.010–0.085, RE=Tb x = 0.010–0.500) were quantitatively prepared by reaction of starting compounds in molten CsCl. Single crystal X-Ray analysis revealed the difference in preference Eu3+ occupancy for two independent RE-sites coming from volume difference of these sites. This effect is negligible for the Tb-containing solid solution due to smaller difference in radii Tb3+ and Y3+ ions. Tb3+-containing samples are luminescent with typical emission of Tb3+, while Eu3+-containing samples are not luminescent. The 1%Tb3+-containing sample emits in blue or in green color depending on the excitation wavelength. Measured melting points are 1545 ± 15 °С for all investigated samples (Y1-xREx)4S3Si2O7.",
keywords = "Chalcogenide, Crystal structure, Luminescence, Rare earth elements, Silicate, CE, UP-CONVERSION, LANTHANIDES, DISILICATE, WHITE-LIGHT EMISSION, SULFIDE, PHOSPHORS, LUMINESCENCE, SILICATE",
author = "Tarasenko, {Maria S.} and Berezin, {Alexey S.} and Kiryakov, {Alexander S.} and Piryazev, {Dmitry A.} and Filatova, {Irina Yu} and Naumov, {Nikolay G.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Inc.",
year = "2018",
month = sep,
day = "1",
doi = "10.1016/j.jssc.2018.05.016",
language = "English",
volume = "265",
pages = "36--41",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Academic Press Inc.",

}

RIS

TY - JOUR

T1 - Synthesis, crystal structure and photoluminescence of Eu3+ or Tb3+ doped solid solutions (Y1-xREx)4S3(Si2O7)

AU - Tarasenko, Maria S.

AU - Berezin, Alexey S.

AU - Kiryakov, Alexander S.

AU - Piryazev, Dmitry A.

AU - Filatova, Irina Yu

AU - Naumov, Nikolay G.

N1 - Publisher Copyright: © 2018 Elsevier Inc.

PY - 2018/9/1

Y1 - 2018/9/1

N2 - Y4S3(Si2O7) and its solid solutions (Y1-xREx)4S3Si2O7 (RE = Eu x = 0.010–0.085, RE=Tb x = 0.010–0.500) were quantitatively prepared by reaction of starting compounds in molten CsCl. Single crystal X-Ray analysis revealed the difference in preference Eu3+ occupancy for two independent RE-sites coming from volume difference of these sites. This effect is negligible for the Tb-containing solid solution due to smaller difference in radii Tb3+ and Y3+ ions. Tb3+-containing samples are luminescent with typical emission of Tb3+, while Eu3+-containing samples are not luminescent. The 1%Tb3+-containing sample emits in blue or in green color depending on the excitation wavelength. Measured melting points are 1545 ± 15 °С for all investigated samples (Y1-xREx)4S3Si2O7.

AB - Y4S3(Si2O7) and its solid solutions (Y1-xREx)4S3Si2O7 (RE = Eu x = 0.010–0.085, RE=Tb x = 0.010–0.500) were quantitatively prepared by reaction of starting compounds in molten CsCl. Single crystal X-Ray analysis revealed the difference in preference Eu3+ occupancy for two independent RE-sites coming from volume difference of these sites. This effect is negligible for the Tb-containing solid solution due to smaller difference in radii Tb3+ and Y3+ ions. Tb3+-containing samples are luminescent with typical emission of Tb3+, while Eu3+-containing samples are not luminescent. The 1%Tb3+-containing sample emits in blue or in green color depending on the excitation wavelength. Measured melting points are 1545 ± 15 °С for all investigated samples (Y1-xREx)4S3Si2O7.

KW - Chalcogenide

KW - Crystal structure

KW - Luminescence

KW - Rare earth elements

KW - Silicate

KW - CE

KW - UP-CONVERSION

KW - LANTHANIDES

KW - DISILICATE

KW - WHITE-LIGHT EMISSION

KW - SULFIDE

KW - PHOSPHORS

KW - LUMINESCENCE

KW - SILICATE

UR - http://www.scopus.com/inward/record.url?scp=85047318103&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2018.05.016

DO - 10.1016/j.jssc.2018.05.016

M3 - Article

AN - SCOPUS:85047318103

VL - 265

SP - 36

EP - 41

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

ID: 13541544