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Synthesis, crystal structure, and luminescent properties of new zinc(II) and cadmium(II) metal-organic frameworks based on flexible bis(imidazol-1-yl)alkane ligands. / Barsukova, Marina; Goncharova, Tatiana; Samsonenko, Denis et al.

In: Crystals, Vol. 6, No. 10, 132, 2016.

Research output: Contribution to journal › Article › peer-review

Harvard

Barsukova, M, Goncharova, T, Samsonenko, D, Dybtsev, D & Potapov, A 2016, 'Synthesis, crystal structure, and luminescent properties of new zinc(II) and cadmium(II) metal-organic frameworks based on flexible bis(imidazol-1-yl)alkane ligands', Crystals, vol. 6, no. 10, 132. https://doi.org/10.3390/cryst6100132

APA

Barsukova, M., Goncharova, T., Samsonenko, D., Dybtsev, D., & Potapov, A. (2016). Synthesis, crystal structure, and luminescent properties of new zinc(II) and cadmium(II) metal-organic frameworks based on flexible bis(imidazol-1-yl)alkane ligands. Crystals, 6(10), [132]. https://doi.org/10.3390/cryst6100132

Vancouver

Barsukova M, Goncharova T, Samsonenko D, Dybtsev D, Potapov A. Synthesis, crystal structure, and luminescent properties of new zinc(II) and cadmium(II) metal-organic frameworks based on flexible bis(imidazol-1-yl)alkane ligands. Crystals. 2016;6(10):132. doi: 10.3390/cryst6100132

Author

Barsukova, Marina ; Goncharova, Tatiana ; Samsonenko, Denis et al. / Synthesis, crystal structure, and luminescent properties of new zinc(II) and cadmium(II) metal-organic frameworks based on flexible bis(imidazol-1-yl)alkane ligands. In: Crystals. 2016 ; Vol. 6, No. 10.

BibTeX

@article{a8f53d71da4045859af4252fde59359c,
title = "Synthesis, crystal structure, and luminescent properties of new zinc(II) and cadmium(II) metal-organic frameworks based on flexible bis(imidazol-1-yl)alkane ligands",
abstract = "New metal-organic frameworks (MOFs) based on zinc and cadmium ions, terephthalic acid, and flexible ligands 1,5-bis(imidazol-1-yl)pentane or 1,6-bis(imidazol-1-yl)hexane were prepared and characterized by X-ray diffraction, thermorgavimetric analysis and IR spectroscopy. The imidazolyl ligands were prepared by a new robust procedure involving the reaction between imidazole and 1,5-dibromopentane or 1,6-dibromohexane in a superbasic medium (KOH in DMSO). MOFs based on 1,5-bis(imidazol-1-yl)pentane had diamond topology (dia) and are triply interpenetrated. Ligands with longer spacer 1,6-bis(imidazol-1-yl)hexane, terephthalate ions and zinc(II) ions formed five-fold interpenetrated metal-organic framework also with dia topology, while cadmium(II) ions with the same ligands formed eight-connected uninodal net with a very rare self-penetrated topological type ilc and a point symbol 424 .5.63. The influence of the chemical composition of MOFs on their photoluminescent properties is investigated and discussed in detail.",
keywords = "Bis(imidazol-1-yl)alkanes, Cadmium, Flexible ligands, Imidazole, Luminescence, Metal-organic frameworks, Zinc",
author = "Marina Barsukova and Tatiana Goncharova and Denis Samsonenko and Danil Dybtsev and Andrei Potapov",
year = "2016",
doi = "10.3390/cryst6100132",
language = "English",
volume = "6",
journal = "Crystals",
issn = "2073-4352",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "10",

}

RIS

TY - JOUR

T1 - Synthesis, crystal structure, and luminescent properties of new zinc(II) and cadmium(II) metal-organic frameworks based on flexible bis(imidazol-1-yl)alkane ligands

AU - Barsukova, Marina

AU - Goncharova, Tatiana

AU - Samsonenko, Denis

AU - Dybtsev, Danil

AU - Potapov, Andrei

PY - 2016

Y1 - 2016

N2 - New metal-organic frameworks (MOFs) based on zinc and cadmium ions, terephthalic acid, and flexible ligands 1,5-bis(imidazol-1-yl)pentane or 1,6-bis(imidazol-1-yl)hexane were prepared and characterized by X-ray diffraction, thermorgavimetric analysis and IR spectroscopy. The imidazolyl ligands were prepared by a new robust procedure involving the reaction between imidazole and 1,5-dibromopentane or 1,6-dibromohexane in a superbasic medium (KOH in DMSO). MOFs based on 1,5-bis(imidazol-1-yl)pentane had diamond topology (dia) and are triply interpenetrated. Ligands with longer spacer 1,6-bis(imidazol-1-yl)hexane, terephthalate ions and zinc(II) ions formed five-fold interpenetrated metal-organic framework also with dia topology, while cadmium(II) ions with the same ligands formed eight-connected uninodal net with a very rare self-penetrated topological type ilc and a point symbol 424 .5.63. The influence of the chemical composition of MOFs on their photoluminescent properties is investigated and discussed in detail.

AB - New metal-organic frameworks (MOFs) based on zinc and cadmium ions, terephthalic acid, and flexible ligands 1,5-bis(imidazol-1-yl)pentane or 1,6-bis(imidazol-1-yl)hexane were prepared and characterized by X-ray diffraction, thermorgavimetric analysis and IR spectroscopy. The imidazolyl ligands were prepared by a new robust procedure involving the reaction between imidazole and 1,5-dibromopentane or 1,6-dibromohexane in a superbasic medium (KOH in DMSO). MOFs based on 1,5-bis(imidazol-1-yl)pentane had diamond topology (dia) and are triply interpenetrated. Ligands with longer spacer 1,6-bis(imidazol-1-yl)hexane, terephthalate ions and zinc(II) ions formed five-fold interpenetrated metal-organic framework also with dia topology, while cadmium(II) ions with the same ligands formed eight-connected uninodal net with a very rare self-penetrated topological type ilc and a point symbol 424 .5.63. The influence of the chemical composition of MOFs on their photoluminescent properties is investigated and discussed in detail.

KW - Bis(imidazol-1-yl)alkanes

KW - Cadmium

KW - Flexible ligands

KW - Imidazole

KW - Luminescence

KW - Metal-organic frameworks

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=84992372067&partnerID=8YFLogxK

U2 - 10.3390/cryst6100132

DO - 10.3390/cryst6100132

M3 - Article

AN - SCOPUS:84992372067

VL - 6

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 10

M1 - 132

ER -

ID: 25398412