TY - JOUR

T1 - Synthesis and Structure of Heterobinuclear Complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O

AU - Makotchenko, E. V.

AU - Baidina, I. A.

AU - Korol’kov, I. V.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - New binuclear complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O, where Dien* is deprotonated diethylenetriamine, have been prepared and studied by elemental analysis, X-ray diffraction, and IR spectroscopy. The crystal structures are built of binuclear complexes of the composition [AuCl(μ-Dien*)PtCl 3 ] with the average Au⋯Pt intramolecular distance equal to 3.403 Å. Gold and platinum atoms have distorted square coordination; the (AuN 3 Cl) and (PtNCl 3 ) coordination cores are found; the middle Dien nitrogen atom acts as a bridge bonding the Au and Pt coordination squares.

AB - New binuclear complexes [AuCl(μ-Dien*)PtCl 3 ] and [AuCl(μ-Dien*)PtCl 3 ] · 0.5H 2 O, where Dien* is deprotonated diethylenetriamine, have been prepared and studied by elemental analysis, X-ray diffraction, and IR spectroscopy. The crystal structures are built of binuclear complexes of the composition [AuCl(μ-Dien*)PtCl 3 ] with the average Au⋯Pt intramolecular distance equal to 3.403 Å. Gold and platinum atoms have distorted square coordination; the (AuN 3 Cl) and (PtNCl 3 ) coordination cores are found; the middle Dien nitrogen atom acts as a bridge bonding the Au and Pt coordination squares.

KW - diethylenetriamine

KW - gold

KW - platinum

KW - X-ray diffraction

KW - CRYSTAL-STRUCTURE

KW - SALTS

UR - http://www.scopus.com/inward/record.url?scp=85065436292&partnerID=8YFLogxK

U2 - 10.1134/S0036023619010157

DO - 10.1134/S0036023619010157

M3 - Article

AN - SCOPUS:85065436292

VL - 64

SP - 41

EP - 48

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 1

ER -