Synthesis and structure of a new neodymium complex with an unusual type of coordination of the benzyl ligand

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Synthesis and structure of a new neodymium complex with an unusual type of coordination of the benzyl ligand. / Demkin, A. G.; Savkov, B. Yu; Sukhikh, T. S. et al.

In: Journal of Structural Chemistry, Vol. 62, No. 1, 01.2021, p. 116-122.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{0086c082990049699185687ad47ed913,

title = "Synthesis and structure of a new neodymium complex with an unusual type of coordination of the benzyl ligand",

abstract = "A reaction of [Cp'''2NdI](1)(Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) with BzK (Bz = C6H5CH2) in toluene is studied. The result of this reaction was expected to be Bz–substitution for I–, however, it is found that the main reaction product is a new binuclear neodymium complex [(Cp′′′BzNd)2O] (2), containing a bridging oxygen atom. Structures of (1) and (2) are determined by single crystal X-ray diffraction analysis.",

keywords = "benzyl complexes, coordination compounds, crystal structure, lanthanides, neodymium",

author = "Demkin, {A. G.} and Savkov, {B. Yu} and Sukhikh, {T. S.} and Konchenko, {S. N.}",

note = "Funding Information: The work was supported by the Russian Science Foundation (grant No. 16-13-10294). Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = jan,

doi = "10.1134/S0022476621010145",

language = "English",

volume = "62",

pages = "116--122",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "1",

}

RIS

TY - JOUR

T1 - Synthesis and structure of a new neodymium complex with an unusual type of coordination of the benzyl ligand

AU - Demkin, A. G.

AU - Savkov, B. Yu

AU - Sukhikh, T. S.

AU - Konchenko, S. N.

N1 - Funding Information: The work was supported by the Russian Science Foundation (grant No. 16-13-10294). Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1

Y1 - 2021/1

N2 - A reaction of [Cp'''2NdI](1)(Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) with BzK (Bz = C6H5CH2) in toluene is studied. The result of this reaction was expected to be Bz–substitution for I–, however, it is found that the main reaction product is a new binuclear neodymium complex [(Cp′′′BzNd)2O] (2), containing a bridging oxygen atom. Structures of (1) and (2) are determined by single crystal X-ray diffraction analysis.

AB - A reaction of [Cp'''2NdI](1)(Cp′′′ = 1,3,4-tris(tert-butyl)cyclopentadienide) with BzK (Bz = C6H5CH2) in toluene is studied. The result of this reaction was expected to be Bz–substitution for I–, however, it is found that the main reaction product is a new binuclear neodymium complex [(Cp′′′BzNd)2O] (2), containing a bridging oxygen atom. Structures of (1) and (2) are determined by single crystal X-ray diffraction analysis.

KW - benzyl complexes

KW - coordination compounds

KW - crystal structure

KW - lanthanides

KW - neodymium

UR - http://www.scopus.com/inward/record.url?scp=85100919907&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/3ac1bee8-c747-3cf3-bdd3-3cdfa6046c1d/

U2 - 10.1134/S0022476621010145

DO - 10.1134/S0022476621010145

M3 - Article

AN - SCOPUS:85100919907

VL - 62

SP - 116

EP - 122

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -

ID: 27880143