Standard

Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane. / Semitut, Evgeny Yu; Komarov, Vladislav Yu; Filatov, Evgeny Yu et al.

In: Inorganic Chemistry Communications, Vol. 64, 02.2016, p. 23-26.

Research output: Contribution to journal › Article › peer-review

Harvard

Semitut, EY, Komarov, VY, Filatov, EY, Kuznetsova, AS, Khlebnikov, AI & Potapov, AS 2016, 'Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane', Inorganic Chemistry Communications, vol. 64, pp. 23-26. https://doi.org/10.1016/j.inoche.2015.12.008

APA

Semitut, E. Y., Komarov, V. Y., Filatov, E. Y., Kuznetsova, A. S., Khlebnikov, A. I., & Potapov, A. S. (2016). Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane. Inorganic Chemistry Communications, 64, 23-26. https://doi.org/10.1016/j.inoche.2015.12.008

Vancouver

Semitut EY, Komarov VY, Filatov EY, Kuznetsova AS, Khlebnikov AI, Potapov AS. Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane. Inorganic Chemistry Communications. 2016 Feb;64:23-26. doi: 10.1016/j.inoche.2015.12.008

Author

Semitut, Evgeny Yu ; Komarov, Vladislav Yu ; Filatov, Evgeny Yu et al. / Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane. In: Inorganic Chemistry Communications. 2016 ; Vol. 64. pp. 23-26.

BibTeX

@article{3ef7f197079f4060b5e04a75bc2124fa,
title = "Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane",
abstract = "Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions.",
keywords = "1,1,2,2-tetra(pyrazol-1-yl)ethane, Bis(pyrazol-1-yl)methane, Bitopic ligand, Coordination polymers, Copper(II) nitrate, Crystal structure",
author = "Semitut, {Evgeny Yu} and Komarov, {Vladislav Yu} and Filatov, {Evgeny Yu} and Kuznetsova, {Anastasia S.} and Khlebnikov, {Andrei I.} and Potapov, {Andrei S.}",
year = "2016",
month = feb,
doi = "10.1016/j.inoche.2015.12.008",
language = "English",
volume = "64",
pages = "23--26",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis and structural characterization of copper(II) coordination polymers with 1,1,2,2-tetra(pyrazol-1-yl)ethane

AU - Semitut, Evgeny Yu

AU - Komarov, Vladislav Yu

AU - Filatov, Evgeny Yu

AU - Kuznetsova, Anastasia S.

AU - Khlebnikov, Andrei I.

AU - Potapov, Andrei S.

PY - 2016/2

Y1 - 2016/2

N2 - Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions.

AB - Reaction between 1,1,2,2-tetra(pyrazol-1-yl)ethane (Pz4) and copper(II) nitrate in ethanol at room temperature and in solvothermal conditions (90 °C) lead to coordination polymers of two different structures. A ribbon-like coordination polymer {Cu2(μ2-NO3)2(H2O)4 μ′2-Pz4}n was formed at room temperature in which nitrate ions bind the monomeric units, while Pz4 ligands are responsible for cross-linking of {Cu(μ-NO3)} chains. At 90 °C linear 1D coordination polymer was formed, in which Pz4 ligands bridge copper ions that in addition bear two monodentate nitrate ions.

KW - 1,1,2,2-tetra(pyrazol-1-yl)ethane

KW - Bis(pyrazol-1-yl)methane

KW - Bitopic ligand

KW - Coordination polymers

KW - Copper(II) nitrate

KW - Crystal structure

UR - http://www.scopus.com/inward/record.url?scp=84951141200&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2015.12.008

DO - 10.1016/j.inoche.2015.12.008

M3 - Article

AN - SCOPUS:84951141200

VL - 64

SP - 23

EP - 26

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 25398720