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Synthesis and electrochemical properties of [RuIV 2O(PhCN)4Cl6]. / Gushchin, Artem L.; Laricheva, Yuliya A.; Abramov, Pavel A. et al.

In: Inorganic Chemistry Communications, Vol. 95, 01.09.2018, p. 163-166.

Research output: Contribution to journal › Article › peer-review

Harvard

Gushchin, AL, Laricheva, YA, Abramov, PA & Sokolov, MN 2018, 'Synthesis and electrochemical properties of [RuIV 2O(PhCN)4Cl6]', Inorganic Chemistry Communications, vol. 95, pp. 163-166. https://doi.org/10.1016/j.inoche.2018.07.033

APA

Gushchin, A. L., Laricheva, Y. A., Abramov, P. A., & Sokolov, M. N. (2018). Synthesis and electrochemical properties of [RuIV 2O(PhCN)4Cl6]. Inorganic Chemistry Communications, 95, 163-166. https://doi.org/10.1016/j.inoche.2018.07.033

Vancouver

Gushchin AL, Laricheva YA, Abramov PA, Sokolov MN. Synthesis and electrochemical properties of [RuIV 2O(PhCN)4Cl6]. Inorganic Chemistry Communications. 2018 Sept 1;95:163-166. doi: 10.1016/j.inoche.2018.07.033

Author

Gushchin, Artem L. ; Laricheva, Yuliya A. ; Abramov, Pavel A. et al. / Synthesis and electrochemical properties of [RuIV 2O(PhCN)4Cl6]. In: Inorganic Chemistry Communications. 2018 ; Vol. 95. pp. 163-166.

BibTeX

@article{a135031781564054b472831a768313a7,
title = "Synthesis and electrochemical properties of [RuIV 2O(PhCN)4Cl6]",
abstract = "Slow evaporation of “RuCl3·xH2O” solution in PhCN under heating in air produces crystals of a new binuclear RuIV complex [Ru2O(PhCN)4Cl6] (1). Crystal structure of 1 was determined. Redox behavior of 1 was studied by cyclic voltammetry. The complex demonstrates three chemically reversible redox processes and two irreversible processes between −0.8 and 1.8 V. The first two reversible events can be assigned to the consecutive one-electron reduction of RuIV-O-RuIV into RuIV-O-RuIII and RuIII-O-RuIII. The anodic reversible oxidation corresponds to the formation of RuIV-O-RuV, which then irreversibly oxidizes. Quantum-chemical calculations show metal-centered nature of the redox processes.",
keywords = "WATER-OXIDATION CATALYST, COUPLED ELECTRON-TRANSFER, IRON ACTIVE-SITES, DIOXYGEN ACTIVATION, PHOTOSYSTEM-II, OXO COMPLEXES, MECHANISMS, ENZYMES, DIMER, LIGANDS",
author = "Gushchin, {Artem L.} and Laricheva, {Yuliya A.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",
year = "2018",
month = sep,
day = "1",
doi = "10.1016/j.inoche.2018.07.033",
language = "English",
volume = "95",
pages = "163--166",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis and electrochemical properties of [RuIV 2O(PhCN)4Cl6]

AU - Gushchin, Artem L.

AU - Laricheva, Yuliya A.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

N1 - Publisher Copyright: © 2018 Elsevier B.V.

PY - 2018/9/1

Y1 - 2018/9/1

N2 - Slow evaporation of “RuCl3·xH2O” solution in PhCN under heating in air produces crystals of a new binuclear RuIV complex [Ru2O(PhCN)4Cl6] (1). Crystal structure of 1 was determined. Redox behavior of 1 was studied by cyclic voltammetry. The complex demonstrates three chemically reversible redox processes and two irreversible processes between −0.8 and 1.8 V. The first two reversible events can be assigned to the consecutive one-electron reduction of RuIV-O-RuIV into RuIV-O-RuIII and RuIII-O-RuIII. The anodic reversible oxidation corresponds to the formation of RuIV-O-RuV, which then irreversibly oxidizes. Quantum-chemical calculations show metal-centered nature of the redox processes.

AB - Slow evaporation of “RuCl3·xH2O” solution in PhCN under heating in air produces crystals of a new binuclear RuIV complex [Ru2O(PhCN)4Cl6] (1). Crystal structure of 1 was determined. Redox behavior of 1 was studied by cyclic voltammetry. The complex demonstrates three chemically reversible redox processes and two irreversible processes between −0.8 and 1.8 V. The first two reversible events can be assigned to the consecutive one-electron reduction of RuIV-O-RuIV into RuIV-O-RuIII and RuIII-O-RuIII. The anodic reversible oxidation corresponds to the formation of RuIV-O-RuV, which then irreversibly oxidizes. Quantum-chemical calculations show metal-centered nature of the redox processes.

KW - WATER-OXIDATION CATALYST

KW - COUPLED ELECTRON-TRANSFER

KW - IRON ACTIVE-SITES

KW - DIOXYGEN ACTIVATION

KW - PHOTOSYSTEM-II

KW - OXO COMPLEXES

KW - MECHANISMS

KW - ENZYMES

KW - DIMER

KW - LIGANDS

UR - http://www.scopus.com/inward/record.url?scp=85050656786&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2018.07.033

DO - 10.1016/j.inoche.2018.07.033

M3 - Article

AN - SCOPUS:85050656786

VL - 95

SP - 163

EP - 166

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 15918910