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Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]. / Shmakova, A. A.; Gushchin, A. L.; Abramov, P. A. et al.

In: Journal of Structural Chemistry, Vol. 60, No. 6, 01.06.2019, p. 961-966.

Research output: Contribution to journal › Article › peer-review

Harvard

Shmakova, AA, Gushchin, AL, Abramov, PA & Sokolov, MN 2019, 'Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]', Journal of Structural Chemistry, vol. 60, no. 6, pp. 961-966. https://doi.org/10.1134/S0022476619060106

APA

Shmakova, A. A., Gushchin, A. L., Abramov, P. A., & Sokolov, M. N. (2019). Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]. Journal of Structural Chemistry, 60(6), 961-966. https://doi.org/10.1134/S0022476619060106

Vancouver

Shmakova AA, Gushchin AL, Abramov PA, Sokolov MN. Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]. Journal of Structural Chemistry. 2019 Jun 1;60(6):961-966. doi: 10.1134/S0022476619060106

Author

Shmakova, A. A. ; Gushchin, A. L. ; Abramov, P. A. et al. / Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]. In: Journal of Structural Chemistry. 2019 ; Vol. 60, No. 6. pp. 961-966.

BibTeX

@article{4ec409637ad24a2886a29a20467fd4dd,
title = "Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]",
abstract = "The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be used as a source of niobium to incorporate the {NbO}3+ group into a cavity of the monolacunary Dawson-type [α2-P2W17O61]10− anion. The product is isolated from the reaction mixture as dimethylammonium salt (Me2NH2)7[α2-P2W17NbO62]·3H2O (1) and characterized by single crystal XRD, IR and Raman spectroscopy, and elemental analysis. (NBu4)6(Me2NH2)[α2-P2W17NbO62] (2) is obtained by adding Bu4NBr to an aqueous solution of 1. The comparison of the electrochemical properties of complex 2 and (NBu4)6[P2W18O62] shows that the incorporation of niobium atom hinders the anion reduction.",
keywords = "cyclic voltammetric patterns, Dawson anion, niobium, NMR, POLYOXOMETALATE, CATALYST",
author = "Shmakova, {A. A.} and Gushchin, {A. L.} and Abramov, {P. A.} and Sokolov, {M. N.}",
year = "2019",
month = jun,
day = "1",
doi = "10.1134/S0022476619060106",
language = "English",
volume = "60",
pages = "961--966",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Synthesis and Electrochemical Properties of ((CH3)2NH2)7[P2W17NbO62]

AU - Shmakova, A. A.

AU - Gushchin, A. L.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be used as a source of niobium to incorporate the {NbO}3+ group into a cavity of the monolacunary Dawson-type [α2-P2W17O61]10− anion. The product is isolated from the reaction mixture as dimethylammonium salt (Me2NH2)7[α2-P2W17NbO62]·3H2O (1) and characterized by single crystal XRD, IR and Raman spectroscopy, and elemental analysis. (NBu4)6(Me2NH2)[α2-P2W17NbO62] (2) is obtained by adding Bu4NBr to an aqueous solution of 1. The comparison of the electrochemical properties of complex 2 and (NBu4)6[P2W18O62] shows that the incorporation of niobium atom hinders the anion reduction.

AB - The bis(oxalate) complex of niobium (NH4)[NbO(C2O4)2(H2O)2]·3H2O can be used as a source of niobium to incorporate the {NbO}3+ group into a cavity of the monolacunary Dawson-type [α2-P2W17O61]10− anion. The product is isolated from the reaction mixture as dimethylammonium salt (Me2NH2)7[α2-P2W17NbO62]·3H2O (1) and characterized by single crystal XRD, IR and Raman spectroscopy, and elemental analysis. (NBu4)6(Me2NH2)[α2-P2W17NbO62] (2) is obtained by adding Bu4NBr to an aqueous solution of 1. The comparison of the electrochemical properties of complex 2 and (NBu4)6[P2W18O62] shows that the incorporation of niobium atom hinders the anion reduction.

KW - cyclic voltammetric patterns

KW - Dawson anion

KW - niobium

KW - NMR

KW - POLYOXOMETALATE

KW - CATALYST

UR - http://www.scopus.com/inward/record.url?scp=85068793068&partnerID=8YFLogxK

U2 - 10.1134/S0022476619060106

DO - 10.1134/S0022476619060106

M3 - Article

AN - SCOPUS:85068793068

VL - 60

SP - 961

EP - 966

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 20837599