Research output: Contribution to journal › Article › peer-review
Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2. / Vorobyev, Vasily; Kabin, Evgeniy V.; Emelyanov, Vyacheslav A. et al.
In: Inorganic Chemistry Communications, Vol. 68, 06.2016, p. 1-3.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2
AU - Vorobyev, Vasily
AU - Kabin, Evgeniy V.
AU - Emelyanov, Vyacheslav A.
AU - Baidina, Iraida A.
AU - Korolkov, Ilya V.
PY - 2016/6
Y1 - 2016/6
N2 - The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.
AB - The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.
KW - Aqua complex
KW - Metastable states
KW - Nitro complex
KW - Nitrosyl
KW - Photoactivity
KW - Ruthenium
UR - http://www.scopus.com/inward/record.url?scp=84962848889&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2016.03.019
DO - 10.1016/j.inoche.2016.03.019
M3 - Article
AN - SCOPUS:84962848889
VL - 68
SP - 1
EP - 3
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -
ID: 25403758