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Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2. / Vorobyev, Vasily; Kabin, Evgeniy V.; Emelyanov, Vyacheslav A. et al.

In: Inorganic Chemistry Communications, Vol. 68, 06.2016, p. 1-3.

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Vorobyev V, Kabin EV, Emelyanov VA, Baidina IA, Korolkov IV. Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2. Inorganic Chemistry Communications. 2016 Jun;68:1-3. doi: 10.1016/j.inoche.2016.03.019

Author

Vorobyev, Vasily ; Kabin, Evgeniy V. ; Emelyanov, Vyacheslav A. et al. / Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2. In: Inorganic Chemistry Communications. 2016 ; Vol. 68. pp. 1-3.

BibTeX

@article{c3eedfe17ea2498a87cbd5b39eea4cfe,
title = "Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2",
abstract = "The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.",
keywords = "Aqua complex, Metastable states, Nitro complex, Nitrosyl, Photoactivity, Ruthenium",
author = "Vasily Vorobyev and Kabin, {Evgeniy V.} and Emelyanov, {Vyacheslav A.} and Baidina, {Iraida A.} and Korolkov, {Ilya V.}",
year = "2016",
month = jun,
doi = "10.1016/j.inoche.2016.03.019",
language = "English",
volume = "68",
pages = "1--3",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Synthesis and crystal structure of mer-nitroaquatriamminenitrosylruthenium(II) nitrate [RuNO(NH3)3(NO2)(H2O)](NO3)2

AU - Vorobyev, Vasily

AU - Kabin, Evgeniy V.

AU - Emelyanov, Vyacheslav A.

AU - Baidina, Iraida A.

AU - Korolkov, Ilya V.

PY - 2016/6

Y1 - 2016/6

N2 - The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.

AB - The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4.

KW - Aqua complex

KW - Metastable states

KW - Nitro complex

KW - Nitrosyl

KW - Photoactivity

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=84962848889&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2016.03.019

DO - 10.1016/j.inoche.2016.03.019

M3 - Article

AN - SCOPUS:84962848889

VL - 68

SP - 1

EP - 3

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

ER -

ID: 25403758