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Synthesis and crystal chemistry of octahedral rhodium(III) chloroamines. / Yusenko, Kirill V.; Sukhikh, Aleksandr S.; Kraus, Werner et al.

In: Molecules, Vol. 25, No. 4, 768, 11.02.2020.

Research output: Contribution to journal › Article › peer-review

Harvard

Yusenko, KV, Sukhikh, AS, Kraus, W & Gromilov, SA 2020, 'Synthesis and crystal chemistry of octahedral rhodium(III) chloroamines', Molecules, vol. 25, no. 4, 768. https://doi.org/10.3390/molecules25040768

APA

Yusenko, K. V., Sukhikh, A. S., Kraus, W., & Gromilov, S. A. (2020). Synthesis and crystal chemistry of octahedral rhodium(III) chloroamines. Molecules, 25(4), [768]. https://doi.org/10.3390/molecules25040768

Vancouver

Yusenko KV, Sukhikh AS, Kraus W, Gromilov SA. Synthesis and crystal chemistry of octahedral rhodium(III) chloroamines. Molecules. 2020 Feb 11;25(4):768. doi: 10.3390/molecules25040768

Author

Yusenko, Kirill V. ; Sukhikh, Aleksandr S. ; Kraus, Werner et al. / Synthesis and crystal chemistry of octahedral rhodium(III) chloroamines. In: Molecules. 2020 ; Vol. 25, No. 4.

BibTeX

@article{74af1de574a34c1ab4ee993e4f5549da,
title = "Synthesis and crystal chemistry of octahedral rhodium(III) chloroamines",
abstract = "Rhodium(III) octahedral complexes with amine and chloride ligands are the most common starting compounds for preparing catalytically active rhodium(I) and rhodium(III) species. Despite intensive study during the last 100 years, synthesis and crystal structures of rhodium(III) complexes were described only briefly. Some [RhClx(NH3)6-x] compounds are still unknown. In this study, available information about synthetic protocols and the crystal structures of possible [RhClx(NH3)6−x] octahedral species are summarized and critically analyzed. Unknown crystal structures of (NH4)2[Rh(NH3)Cl5], trans–[Rh(NH3)4Cl2]Cl·H2O, and cis–[Rh(NH3)4Cl2]Cl are reported based on high quality single crystal X-ray diffraction data. The crystal structure of [Rh(NH3)5Cl]Cl2 was redetermined. All available crystal structures with octahedral complexes [RhClx(NH3)6-x] were analyzed in terms of their packings and pseudo-translational sublattices. Pseudo-translation lattices suggest face-centered cubic and hexagonal closed-packed sub-cells, where Rh atoms occupy nearly ideal lattices.",
keywords = "Crystal structure, Ligand substitution, Pseudo-translational sublattices, Rhodium complexes, AMMINE, COMPLEXES, crystal structure, IONS, pseudo-translational sublattices, VIBRATIONAL-SPECTRA, ligand substitution, rhodium complexes",
author = "Yusenko, {Kirill V.} and Sukhikh, {Aleksandr S.} and Werner Kraus and Gromilov, {Sergey A.}",
note = "Publisher Copyright: {\textcopyright} 2020 by the authors. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = feb,
day = "11",
doi = "10.3390/molecules25040768",
language = "English",
volume = "25",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "4",

}

RIS

TY - JOUR

T1 - Synthesis and crystal chemistry of octahedral rhodium(III) chloroamines

AU - Yusenko, Kirill V.

AU - Sukhikh, Aleksandr S.

AU - Kraus, Werner

AU - Gromilov, Sergey A.

N1 - Publisher Copyright: © 2020 by the authors. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/2/11

Y1 - 2020/2/11

N2 - Rhodium(III) octahedral complexes with amine and chloride ligands are the most common starting compounds for preparing catalytically active rhodium(I) and rhodium(III) species. Despite intensive study during the last 100 years, synthesis and crystal structures of rhodium(III) complexes were described only briefly. Some [RhClx(NH3)6-x] compounds are still unknown. In this study, available information about synthetic protocols and the crystal structures of possible [RhClx(NH3)6−x] octahedral species are summarized and critically analyzed. Unknown crystal structures of (NH4)2[Rh(NH3)Cl5], trans–[Rh(NH3)4Cl2]Cl·H2O, and cis–[Rh(NH3)4Cl2]Cl are reported based on high quality single crystal X-ray diffraction data. The crystal structure of [Rh(NH3)5Cl]Cl2 was redetermined. All available crystal structures with octahedral complexes [RhClx(NH3)6-x] were analyzed in terms of their packings and pseudo-translational sublattices. Pseudo-translation lattices suggest face-centered cubic and hexagonal closed-packed sub-cells, where Rh atoms occupy nearly ideal lattices.

AB - Rhodium(III) octahedral complexes with amine and chloride ligands are the most common starting compounds for preparing catalytically active rhodium(I) and rhodium(III) species. Despite intensive study during the last 100 years, synthesis and crystal structures of rhodium(III) complexes were described only briefly. Some [RhClx(NH3)6-x] compounds are still unknown. In this study, available information about synthetic protocols and the crystal structures of possible [RhClx(NH3)6−x] octahedral species are summarized and critically analyzed. Unknown crystal structures of (NH4)2[Rh(NH3)Cl5], trans–[Rh(NH3)4Cl2]Cl·H2O, and cis–[Rh(NH3)4Cl2]Cl are reported based on high quality single crystal X-ray diffraction data. The crystal structure of [Rh(NH3)5Cl]Cl2 was redetermined. All available crystal structures with octahedral complexes [RhClx(NH3)6-x] were analyzed in terms of their packings and pseudo-translational sublattices. Pseudo-translation lattices suggest face-centered cubic and hexagonal closed-packed sub-cells, where Rh atoms occupy nearly ideal lattices.

KW - Crystal structure

KW - Ligand substitution

KW - Pseudo-translational sublattices

KW - Rhodium complexes

KW - AMMINE

KW - COMPLEXES

KW - crystal structure

KW - IONS

KW - pseudo-translational sublattices

KW - VIBRATIONAL-SPECTRA

KW - ligand substitution

KW - rhodium complexes

UR - http://www.scopus.com/inward/record.url?scp=85079336247&partnerID=8YFLogxK

U2 - 10.3390/molecules25040768

DO - 10.3390/molecules25040768

M3 - Article

C2 - 32053922

AN - SCOPUS:85079336247

VL - 25

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 4

M1 - 768

ER -

ID: 23542928