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Syntheses, crystal structure and luminescence properties of the novel isostructural KSrR(BO3)2 with R = Y, Yb, Tb. / Kokh, A. E.; Kononova, N. G.; Shevchenko, V. S. et al.

In: Journal of Alloys and Compounds, Vol. 711, 15.07.2017, p. 440-445.

Research output: Contribution to journal › Article › peer-review

Harvard

Kokh, AE, Kononova, NG, Shevchenko, VS, Seryotkin, YV, Bolatov, AK, Abdullin, KA, Uralbekov, BM & Burkitbayev, M 2017, 'Syntheses, crystal structure and luminescence properties of the novel isostructural KSrR(BO3)2 with R = Y, Yb, Tb', Journal of Alloys and Compounds, vol. 711, pp. 440-445. https://doi.org/10.1016/j.jallcom.2017.03.322

APA

Kokh, A. E., Kononova, N. G., Shevchenko, V. S., Seryotkin, Y. V., Bolatov, A. K., Abdullin, K. A., Uralbekov, B. M., & Burkitbayev, M. (2017). Syntheses, crystal structure and luminescence properties of the novel isostructural KSrR(BO3)2 with R = Y, Yb, Tb. Journal of Alloys and Compounds, 711, 440-445. https://doi.org/10.1016/j.jallcom.2017.03.322

Vancouver

Kokh AE, Kononova NG, Shevchenko VS, Seryotkin YV, Bolatov AK, Abdullin KA et al. Syntheses, crystal structure and luminescence properties of the novel isostructural KSrR(BO3)2 with R = Y, Yb, Tb. Journal of Alloys and Compounds. 2017 Jul 15;711:440-445. doi: 10.1016/j.jallcom.2017.03.322

Author

Kokh, A. E. ; Kononova, N. G. ; Shevchenko, V. S. et al. / Syntheses, crystal structure and luminescence properties of the novel isostructural KSrR(BO3)2 with R = Y, Yb, Tb. In: Journal of Alloys and Compounds. 2017 ; Vol. 711. pp. 440-445.

BibTeX

@article{18d4522efe02454081f626ad0c13d835,
title = "Syntheses, crystal structure and luminescence properties of the novel isostructural KSrR(BO3)2 with R = Y, Yb, Tb",
abstract = "Three new rare-earth based orthoborates KSrR(BO3)2, with R = Y, Tb, Yb were synthesized by solid-state reaction method. Single crystals of KSrR(BO3)2 were obtained by spontaneous crystallization using selected flux. Single-crystal X-ray diffraction measurements reveal that KSrY(BO3)2 crystallizes in monoclinic space group P21/m with cell parameters of a = 9.2743(3) {\AA}, b = 5.35919(12) {\AA}, c = 6.5749(2) {\AA}, and β = 117.682(4)°. Distinctive feature of studied borates structure is the close-packed composite of anion-cation (K,Sr)(BO3) layers. The two-layer {Y[KSr(BO3)2]} package is the base building block for this structure, with one package on c-period. The comparison of the structures of Ba2Mg(BO3)2, BaNaY(BO3)2, KBaY(BO3)2 and KSrY(BO3)2 is discussed. The photoluminescence properties of the synthesized borate KSrTb(BO)3 under UV excitation have been investigated in a detail.",
keywords = "Luminescence, Rare-earth borates, Single crystal structure, REFINEMENT, BORATE, PHOSPHOR, ND, ORTHOBORATE, GD",
author = "Kokh, {A. E.} and Kononova, {N. G.} and Shevchenko, {V. S.} and Seryotkin, {Yu V.} and Bolatov, {A. K.} and Abdullin, {Kh A.} and Uralbekov, {B. M.} and M. Burkitbayev",
year = "2017",
month = jul,
day = "15",
doi = "10.1016/j.jallcom.2017.03.322",
language = "English",
volume = "711",
pages = "440--445",
journal = "Journal of Alloys and Compounds",
issn = "0925-8388",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Syntheses, crystal structure and luminescence properties of the novel isostructural KSrR(BO3)2 with R = Y, Yb, Tb

AU - Kokh, A. E.

AU - Kononova, N. G.

AU - Shevchenko, V. S.

AU - Seryotkin, Yu V.

AU - Bolatov, A. K.

AU - Abdullin, Kh A.

AU - Uralbekov, B. M.

AU - Burkitbayev, M.

PY - 2017/7/15

Y1 - 2017/7/15

N2 - Three new rare-earth based orthoborates KSrR(BO3)2, with R = Y, Tb, Yb were synthesized by solid-state reaction method. Single crystals of KSrR(BO3)2 were obtained by spontaneous crystallization using selected flux. Single-crystal X-ray diffraction measurements reveal that KSrY(BO3)2 crystallizes in monoclinic space group P21/m with cell parameters of a = 9.2743(3) Å, b = 5.35919(12) Å, c = 6.5749(2) Å, and β = 117.682(4)°. Distinctive feature of studied borates structure is the close-packed composite of anion-cation (K,Sr)(BO3) layers. The two-layer {Y[KSr(BO3)2]} package is the base building block for this structure, with one package on c-period. The comparison of the structures of Ba2Mg(BO3)2, BaNaY(BO3)2, KBaY(BO3)2 and KSrY(BO3)2 is discussed. The photoluminescence properties of the synthesized borate KSrTb(BO)3 under UV excitation have been investigated in a detail.

AB - Three new rare-earth based orthoborates KSrR(BO3)2, with R = Y, Tb, Yb were synthesized by solid-state reaction method. Single crystals of KSrR(BO3)2 were obtained by spontaneous crystallization using selected flux. Single-crystal X-ray diffraction measurements reveal that KSrY(BO3)2 crystallizes in monoclinic space group P21/m with cell parameters of a = 9.2743(3) Å, b = 5.35919(12) Å, c = 6.5749(2) Å, and β = 117.682(4)°. Distinctive feature of studied borates structure is the close-packed composite of anion-cation (K,Sr)(BO3) layers. The two-layer {Y[KSr(BO3)2]} package is the base building block for this structure, with one package on c-period. The comparison of the structures of Ba2Mg(BO3)2, BaNaY(BO3)2, KBaY(BO3)2 and KSrY(BO3)2 is discussed. The photoluminescence properties of the synthesized borate KSrTb(BO)3 under UV excitation have been investigated in a detail.

KW - Luminescence

KW - Rare-earth borates

KW - Single crystal structure

KW - REFINEMENT

KW - BORATE

KW - PHOSPHOR

KW - ND

KW - ORTHOBORATE

KW - GD

UR - http://www.scopus.com/inward/record.url?scp=85017173044&partnerID=8YFLogxK

U2 - 10.1016/j.jallcom.2017.03.322

DO - 10.1016/j.jallcom.2017.03.322

M3 - Article

AN - SCOPUS:85017173044

VL - 711

SP - 440

EP - 445

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

ER -

ID: 10265238